An NMR Spectroscopy View on London Dispersion in Catalysis: Detection, Quantification, and Application in Ion Pair and Transition Metal Catalysis

London Dispersion Favors Sterically Hindered Diarylthiourea Conformers in Solution

(2022) Lars Rummel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gauging the Steric Effects of Silyl Groups with a Molecular Balance

(2022) Henrik F. König et al.   JOURNAL OF ORGANIC CHEMISTRY

Tilting the Balance: London Dispersion Systematically Enhances Enantioselectivities in Brønsted Acid Catalyzed Transfer Hydrogenation of Imines

(2022) Johannes Gramüller et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New Ligand Design Based on London Dispersion Empowers Chiral Bismuth–Rhodium Paddlewheel Catalysts

(2021) Santanu Singha et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Noncovalent CH–π and π–π Interactions in Phosphoramidite Palladium(II) Complexes with Strong Conformational Preference

(2021) Matej Žabka et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unveiling the Delicate Balance of Steric and Dispersion Interactions in Organocatalysis Using High-Level Computational Methods

(2020) Diana Yepes et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

London dispersion in alkane solvents

(2020) Marcel A. Strauss et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

London Dispersion Rather than Steric Hindrance Determines the Enantioselectivity of the Corey‐Bakshi‐Shibata Reduction

(2020) Christian Eschmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intramolecular London Dispersion Interactions Do Not Cancel in Solution

(2020) Jan M. Schümann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Origin of the Immiscibility of Alkanes and Perfluoroalkanes

(2019) Robert Pollice et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rotational Signatures of Dispersive Stacking in the Formation of Aromatic Dimers

(2019) Mariyam Fatima et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Retooling Asymmetric Conjugate Additions for Sterically Demanding Substrates with an Iterative Data-Driven Approach

(2019) Alexandre V. Brethomé et al.   ACS Catalysis

Exploring London Dispersion and Solvent Interactions at Alkyl-Alkyl Interfaces Using Azobenzene Switches

(2019) Marcel A. Strauss et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Disulfonimides versus Phosphoric Acids in Brønsted Acid Catalysis: The Effect of Weak Hydrogen Bonds and Multiple Acceptors on Complex Structures and Reactivity

(2019) Kerstin Rothermel et al.   JOURNAL OF ORGANIC CHEMISTRY

The Effect of Dispersion on the Structure of Diphenyl Ether Aggregates

(2018) Fabian Dietrich et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Understanding and Quantifying London Dispersion Effects in Organometallic Complexes

(2018) Markus Bursch et al.   ACCOUNTS OF CHEMICAL RESEARCH

Probing the Delicate Balance between Pauli Repulsion and London Dispersion with Triphenylmethyl Derivatives

(2018) Sören Rösel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

London Dispersion Enables the Shortest Intermolecular Hydrocarbon H···H Contact

(2017) Sören Rösel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Attenuation of London Dispersion in Dichloromethane Solutions

(2017) Robert Pollice et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular London Dispersion Interaction Effects on Gas-Phase and Solid-State Structures of Diamondoid Dimers

(2017) Andrey A. Fokin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Sizing the role of London dispersion in the dissociation of all-meta tert-butyl hexaphenylethane

(2017) Sören Rösel et al.   Chemical Science

Enantioselective Conjugate Addition Catalyzed by a Copper Phosphoramidite Complex: Computational and Experimental Exploration of Asymmetric Induction

(2017) Ruchuta Ardkhean et al.   ACS Catalysis

The Enantioselective Dakin-West Reaction

(2016) Raffael C. Wende et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Uncovering Key Structural Features of an Enantioselective Peptide-Catalyzed Acylation Utilizing Advanced NMR Techniques

(2016) Eliška Procházková et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Brønsted Acid Catalysis—Structural Preferences and Mobility in Imine/Phosphoric Acid Complexes

(2016) Julian Greindl et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

NMR Spectroscopic Characterization of Charge Assisted Strong Hydrogen Bonds in Brønsted Acid Catalysis

(2016) Nils Sorgenfrei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Attraction or Repulsion? London Dispersion Forces Control Azobenzene Switches

(2015) Luca Schweighauser et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

London Dispersion in Molecular Chemistry-Reconsidering Steric Effects

(2015) J. Philipp Wagner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

London Dispersion Decisively Contributes to the Thermodynamic Stability of Bulky NHC-Coordinated Main Group Compounds

(2015) J. Philipp Wagner et al.   Journal of Chemical Theory and Computation

The Supramolecular Balance for Transition-Metal Complexes: Assessment of Noncovalent Interactions in Phosphoramidite Palladium Complexes

(2013) Evelyn Hartmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structures and Interligand Interaction Pattern of Phosphoramidite Pd Complexes by NMR Spectroscopy: Modulations in Extended Interaction Surfaces as Stereoselection Mode of a Privileged Class of Ligands

(2013) Evelyn Hartmann et al.   CHEMISTRY-A EUROPEAN JOURNAL

How much do van der Waals dispersion forces contribute to molecular recognition in solution?

(2013) Lixu Yang et al.   Nature Chemistry

On the Importance of the Dispersion Energy for the Thermodynamic Stability of Molecules

(2011) Stefan Grimme et al.   CHEMPHYSCHEM

Overcoming lability of extremely long alkane carbon–carbon bonds through dispersion forces

(2011) Peter R. Schreiner et al.   NATURE

1H DOSY Spectra of Ligands for Highly Enantioselective Reactions-A Fast and Simple NMR Method to Optimize Catalytic Reaction Conditions

(2010) Katrin Schober et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Practical Synthetic Approach to Chiral Sulfonimides (CSIs) - Chiral Brønsted Acids for Organocatalysis

(2010) Hao He et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

A Powerful Chiral Counteranion Motif for Asymmetric Catalysis

(2009) Pilar García-García et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

BINBAM - A New Motif for Strong and Chiral Brønsted Acids

(2009) Marcel Treskow et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Copper-Catalyzed Conjugate Addition and Allylic Substitution Reactions

(2008) A. Alexakis et al.   CHEMICAL REVIEWS