4.6 Article

Facile synthesis of Ni/Li3Ti4NiCrO12 composites with enhanced cycle performance as lithium ion battery anode

Journal

MATERIALS LETTERS
Volume 169, Issue -, Pages 13-16

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.matlet.2015.12.005

Keywords

Lithium ion battery; Metallic composites; Lithium titanate; Crystal structure; Anode

Funding

  1. [14520503100]
  2. [15ZZ095]
  3. [13PJ1407400]
  4. [201310-JD-B2-009]

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Ni modified spinel Li3Ti4NiCrO12 (Ni/Li3Ti4NiCrO12) anode material was synthesized by a simple high temperature solid-state reaction in a reducing atmosphere. The existence of metallic Ni not only changes the growth manner of the synthesized Ni/Li3Ti4NiCrO12, but also reduces the grain size, which further leads to a significant improvement in electric conductivity. Such Ni modified Li3Ti4NiCrO12 anode material showed excellent electrochemical behavior upon cyclic test, with a high initial capacity of 158.8 mA h/g and high capacity retention (97.2%) after 80 cycles. All the results confirmed the significance of metallic Ni in promoting the electrochemical behaviors of Li3Ti4NiCrO12, suggesting high potential of Ni/Li3Ti4NiCrO12 in future application. (C) 2015 Elsevier B.V. All rights reserved.

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