Article
Chemistry, Physical
Lev Matoh, Bostjan Zener, Tina Skalar, Lavrencic Stangar Urska
Summary: Hydrothermal reactions are a simple and efficient method for preparing nanostructured TiO2 particles with large specific surface area for photocatalytic applications. The effects of different synthesis parameters on morphology and photocatalytic activity were studied, showing that the final calcination temperature significantly affects degradation rates. Initial morphology had little effect on photocatalytic properties, with results comparable to P25 TiO2 nanoparticles.
Article
Engineering, Biomedical
Xinxin Miao, Fen Yu, Kuan Liu, Zhongsheng Lv, Jianjian Deng, Tianlong Wu, Xinyan Cheng, Wei Zhang, Xigao Cheng, Xiaolei Wang
Summary: A new series of zinc oxide with high specific surface area and narrow energy band gap was prepared using a simple microwave-induced method. These zinc oxide materials possess efficient photocatalytic activity and biological safety due to their ability to be excited by long wave temperature light and their removal of pigment on the tooth surface under yellow light irradiation. This research has opened up new opportunities for the biomedical field.
BIOACTIVE MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
Chujun Yao, Jiamin Lin, Li Wu, Lequn Li, Ning Xu, Jian Sun, Jiada Wu
Summary: ZnO-Au nanocomposites with high photocatalytic activity were synthesized via hydrothermal reactions, where the plasmonic sensitizing effect of Au nanoparticles led to higher light absorption capacity and lower carrier recombination rate, resulting in efficient degradation of RhB. The nanocomposites showed good photocatalytic stability and could be reused as catalysts.
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Zeineb A. Thiehmed, Talal M. Altahtamouni
Summary: In this study, the effect of KBr salt on the growth of TiO2 nanorods was investigated. The addition of KBr with different concentrations controlled the growth of TiO2 nanorods, with KBr molecules suppressing lateral growth and allowing for axial growth. This impacted the morphology and internal surface area of the nanorods.
Article
Electrochemistry
Yue Lin, Qun Qian, Zhenhui Chen, Phan Dinh Tuan, Daolun Feng
Summary: In this study, a simple and novel method was presented to fabricate TiO2 nanopowders with coral-like structure surface. Porous titanium was used as an anodic substrate to enhance the reaction rate and promote the shedding of nanotube fragments.
ELECTROCHEMISTRY COMMUNICATIONS
(2022)
Article
Materials Science, Multidisciplinary
Huanhuan Xu, Lan Xu, Adnan Ahmed
Summary: In this work, carbon quantum dots (CQDs)-decorated ZnO heterostructure nanoflowers grown on nanofiber membranes (NFMs) were prepared using a simple three-step method of electrospinning, heat treatment and hydrothermal synthesis. The nanocomposites were characterized and the photocatalytic degradation mechanism was revealed. The results showed that the NFMs with CQDs-decorated ZnO had the best light absorption performance and achieved the highest degradation efficiency on methylene blue under natural sunlight irradiation.
DIAMOND AND RELATED MATERIALS
(2023)
Article
Materials Science, Ceramics
Ningna Bai, Xiangchun Liu, Zhengguang Li, Xinyu Ke, Kai Zhang, Qi Wu
Summary: TiO2/ZnO nanocomposites with different Ti/Zn ratios were successfully synthesized by sol-gel and hydrothermal methods, exhibiting excellent photocatalytic performance. The degradation rate of methylene blue by TiO2/ZnO nanocomposites with a Ti/Zn ratio of 2:1 was close to 100%, outperforming other samples. The improved catalytic performance was attributed to the ability to separate holes and electrons.
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
(2021)
Article
Chemistry, Physical
Shui-Shu Hsiao, Thi-Minh-Phuong Nguyen, Li-Pang Wang, Gui-Bing Hong, Yu-Chen Cheng, Pei-Hua Wang, Cong-Chinh Duong, Chia-Jui Yang
Summary: The number of kidney dialysis patients, particularly in Taiwan, is increasing every year. The high antibiotic content in kidney dialysis wastewater can pose an environmental burden if not properly treated. This study presents a new design for a flower-like ZnO catalyst, which effectively treats norfloxacin (NF) in dialysis wastewater. The study investigates the NF treatment efficiency under different operating parameters. An evaluation of the ZnO sample shows the presence of flower-like nanostructures with specific characteristics. The study also observes the impact of initial pH values on the removal efficiency of NF.
Article
Chemistry, Physical
Adam Kubiak, Sonia Zoltowska, Aleksandra Bartkowiak, Elzbieta Gabala, Natalia Sacharczuk, Maciej Zalas, Katarzyna Siwinska-Ciesielczyk, Teofil Jesionowski
Summary: The study focused on the hydrothermal-assisted synthesis of TiO2-ZnO systems and their application in photoactive processes, with a method proposed to control crystallinity and morphology through ZnO nanowire growth. Addition of small amounts of ZnO inhibited ZnO crystallization and formed ZnO nanowires, with no significant changes in band gap energy observed. The synthesized binary systems exhibited efficient photodegradation processes and also had potential applications in dye-sensitized solar cells.
Article
Chemistry, Multidisciplinary
Xiaoqian Ai, Shun Yan, Ligang Ma
Summary: In this study, a hierarchical ZnO microsphere precursor was prepared using a hydrothermal method, and a controllable morphology ZnO catalyst was produced through annealing at different temperatures. The catalyst annealed at 400 degrees C showed the best photocatalytic activity for the degradation of dye molecules, and its structure was confirmed to be a 2D cellular network composed of two-dimensional nanosheets through electron microscopy measurements.
Article
Electrochemistry
Qun Qian, Yue Lin, Zhongliang Xiong, Penghao Su, Dexiang Liao, Qizhou Dai, Lisu Chen, Daolun Feng
Summary: In this study, immobilized TiO2 nanotubes with a high specific surface area were successfully fabricated through internal anodization. The anodized porous Ti exhibited a significant increase in BET specific surface area, which not only benefits the designing of highly active TiO2-based photocatalysts, but also shows great potential for applications in adsorption and electrocatalysis.
ELECTROCHEMISTRY COMMUNICATIONS
(2022)
Article
Chemistry, Physical
Huizhong Ma, Baofei Hao, Wentao Song, Jinpeng Guo, Mingyuan Li, Lan Zhang
Summary: The TiO2/ZnO heterojunction thin films combined with surface oxygen vacancies prepared through magnetron sputtering showed enhanced photocatalytic performance in degrading organic pollutants in water. By controlling the O-2/Ar ratio, the morphology, thickness, chemical composition, and crystal structure of the films can be regulated to improve photocatalytic efficiency. The heterojunction thin film exhibited superior photocatalytic properties due to the heterojunction interface and surface oxygen vacancies, accelerating the separation of electron-hole pairs.
Article
Energy & Fuels
Umer Younas, Awais Ahmad, Aftab Islam, Faisal Ali, Muhammad Pervaiz, Aimon Saleem, Muhammad Waseem, Ahmed Muteb Aljuwayid, Mohamed A. Habila, Salman Raza Naqvi
Summary: In this study, a WO3/TiO2/V2O5 catalyst was synthesized and characterized for the degradation of O-NP, MB, and MO pollutants. The results showed that the synthesized nanocomposite exhibited excellent photocatalytic potential, with degradation rates of up to 76%, 86%, and 86% for MB, MO, and O-NP, respectively.
Article
Chemistry, Physical
Shimpei Naniwa, Kosaku Kato, Akira Yamakata, Akira Yamamoto, Hisao Yoshida
Summary: Heterogeneous photocatalysis is a promising technology for green and sustainable chemical processes. This study investigates the relationship between the structure, properties, and activity of photocatalysts in order to improve their design. The authors propose a simple rate equation that relates the specific surface area (S-BET) and the lifetime of photoexcited carriers (tau) to the photocatalytic activity. Their findings suggest that both S-BET and tau are important factors affecting the activity of photocatalysts.
Article
Materials Science, Ceramics
N. K. A. Hamed, M. K. Ahmad, N. H. H. Hairom, A. B. Faridah, M. H. Mamat, A. Mohamed, A. B. Suriani, C. F. Soon, F. I. M. Fazli, S. M. Mokhtar, M. Shimomura
Summary: This study investigates the photocatalytic degradation of methylene blue using flowerlike rutile-phase TiO2 films synthesized by a hydrothermal method. The research reveals that various parameters such as catalyst morphology, oxygen vacancy/Ti3+ surface defects, pH of the methylene blue solution, and initial concentration of the dye influence the photocatalytic activity of the TiO2 film. The presence of oxygen vacancy/Ti3+ surface defects is found to enhance the photocatalytic activity by acting as an electron trap.
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
(2022)
Article
Chemistry, Applied
Xiaoguang Wang, Yang Yang, Heng Zhong, Runtian He, Jiong Cheng, Fangming Jin
Article
Chemistry, Multidisciplinary
Yamei Li, Yoo Kyung Go, Hideshi Ooka, Daoping He, Fangming Jin, Sun Hee Kim, Ryuhei Nakamura
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2020)
Article
Chemistry, Analytical
Hongtao Wang, Linsheng Zhou, Yueying Liu, Fengmin Liu, Xishuang Liang, Fangmeng Liu, Yuan Gao, Xu Yan, Geyu Lu
SENSORS AND ACTUATORS B-CHEMICAL
(2020)
Article
Chemistry, Analytical
Xuejiao Sun, Fangmeng Liu, Caileng Wang, Xinxin Liu, Juan Jian, Decheng Zeng, Liujun Liu, Hongming Yuan, Geyu Lu
SENSORS AND ACTUATORS B-CHEMICAL
(2020)
Article
Chemistry, Analytical
Man Yang, Jingyuan Lu, Xi Wang, Hong Zhang, Fang Chen, Jianbo Sun, Jiaqi Yang, Yanfeng Sun, Geyu Lu
SENSORS AND ACTUATORS B-CHEMICAL
(2020)
Article
Engineering, Electrical & Electronic
Lishuang Wu, Rudan Xu, Guangping Yao, Dasheng Su, Zisheng Su, Huishan Yang
Summary: Organic photodetectors utilizing lead phthalocyanine and C(60) as the donor and acceptor, with a mixed active layer structure, demonstrate enhanced near-infrared responses compared to planar heterojunction devices. The mixed structure increases carrier transport paths, leading to improved exciton dissociation efficiency and carrier collection efficiency, ultimately enhancing device response.
MICROWAVE AND OPTICAL TECHNOLOGY LETTERS
(2021)
Article
Chemistry, Analytical
Pengfei Cheng, Fan Dang, Yinglin Wang, Jianning Gao, Luping Xu, Chen Wang, Li Lv, Xu Li, Bao Zhang, Baijun Liu
Summary: In this study, hierarchical flower-like Ni-doped Co3O4 was successfully synthesized using a facile method, and the effect of ethanol/water ratio on samples was investigated. Gas sensors based on the prepared materials showed excellent performance, with the sensor using 5.3 mol% Ni-doped Co3O4 microflowers exhibiting the highest response towards n-butanol, as well as outstanding anti-humidity properties and long-term stability. The improved gas sensing properties were attributed to the unique hierarchical flower-like microstructure and optimized parameters resulting from the Ni doping.
SENSORS AND ACTUATORS B-CHEMICAL
(2021)
Article
Chemistry, Analytical
Rui Jin, Fanyu Wang, Qingyun Li, Xu Yan, Mengqi Liu, Yue Chen, Weirong Zhou, Hao Gao, Peng Sun, Geyu Lu
Summary: A multi-enzyme cascade system-based hydrogel kit integrated with a smartphone detector was proposed for in-field screening of pesticide, achieving accurate and sensitive detection within 65 minutes. The results obtained were consistent with those of traditional laboratory microplate reader, demonstrating high reliability and ease of operation for real-time measurement of pesticide.
SENSORS AND ACTUATORS B-CHEMICAL
(2021)
Article
Chemistry, Analytical
Tong Liu, Haifei Guan, Tong Wang, Xishuang Liang, Fengmin Liu, Fangmeng Liu, Chuan Zhang, Geyu Lu
Summary: Breath analysis is crucial for early diagnosis of diabetic ketoacidosis. Gas sensors with Bi1-xSrxFeO3 materials were used to fabricate sensors, showing potential in clinical tests for diabetes and healthy individuals.
SENSORS AND ACTUATORS B-CHEMICAL
(2021)
Article
Nanoscience & Nanotechnology
Pengfei Cheng, Chen Wang, Yinglin Wang, Luping Xu, Fan Dang, Li Lv, Xu Li
Summary: Large-scale and well-aligned SnO2 nanotube arrays were synthesized on the surface of Al2O3 ceramic tubes using a cost-effective template self-etching method. The sensor exhibited excellent response and selectivity to acetone gas, showing promising potential in monitoring and detecting acetone. The unique hollow structure and controllable growth strategy contribute to the high sensing performance of the sensor.
Article
Nanoscience & Nanotechnology
Pengfei Cheng, Yinglin Wang, Chen Wang, Jian Ma, Luping Xu, Chao Lv, Yanfeng Sun
Summary: This study investigated the sensitization effects of different noble metals (Au, Ag, Pt, Pd) on In2O3 for improving ethanol sensing performance. Pd doping showed the best sensing performance, with the highest response and shortest response and recovery times. The gas sensing mechanism of noble metal-doped materials involves a synergistic effect of 'catalysis' and 'electronic and chemical sensitization' of noble metals, with the chemical state of the noble metal playing a significant role.
Article
Chemistry, Analytical
Jiaqi Yang, Wenjiang Han, Jian Ma, Chong Wang, Kengo Shimanoe, Sumei Zhang, Yanfeng Sun, Pengfei Cheng, Yinglin Wang, Hong Zhang, Geyu Lu
Summary: A series of high stable gas sensors were prepared by doping Sn into NiO nanofibers, showing enhanced gas response and reduced crystal size. Sn doping altered the resistance of the sensors differently under variable relative humidity conditions, with the sensor exhibiting the highest response to triethylamine at 6% Sn doping content.
SENSORS AND ACTUATORS B-CHEMICAL
(2021)
Article
Chemistry, Analytical
Xu Li, Yinglin Wang, Pengfei Cheng, Yanming Liu, Yue Zhang, Jian Ma, Chao Lv
Summary: Research on the influence of different precursors and Sb concentrations on the gas sensing performance of In2O3 was conducted, with the chemical and structural properties of the material verified through various analysis methods and gas sensing tests carried out. The results show that, with appropriate molar ratios of Sb doping, In(NO3)3 as the precursor can achieve better sensing performance, holding potential application value for ethanol detection.
SENSORS AND ACTUATORS B-CHEMICAL
(2021)
Article
Chemistry, Multidisciplinary
Xu Li, Yinglin Wang, Pengfei Cheng, Yanming Liu, Zhaohui Lei, Mengge Liu, Xue Yao, Haobo Yan, Zhi Weng
Summary: In2O3 doped with Ce element was synthesized via a spray pyrolysis method to produce multi-core-shell structure samples, with the sensor doped with 5 mol% Ce showing the best oxygen adsorption capability and the highest response to acetone. The introduction of Ce ions decreased the operating temperature of the device, improved its selectivity, and enhanced its ability to detect acetone. The article also discusses the formation mechanism of the sample and the gas mechanism in detail.
MATERIALS CHEMISTRY FRONTIERS
(2022)
Article
Materials Science, Ceramics
Xidong Hao, Yinglin Wang, Pengfei Cheng, Shanfu Sun, Luping Xu, Yintang Yang, Yue Hao
Summary: For real-time and in-situ NOx monitoring, a high-performance NO2 mixed potential sensor based on yttria-stabilized zirconia (YSZ) with an MMn2O4 sensing electrode(SE) (M = Co, Cd and Zn) was successfully fabricated. Among the three sensing electrodes, the ZnMn2O4 showed the smallest interface resistance to 100 ppm NO2 and exhibited the highest response. By optimizing the sintering temperature, the ZnMn2O4 sensor sintered at 1000 degrees C achieved the highest response of 23 mV to 10 ppm NO2. The sensor also demonstrated a wide detection range of 1-1000 ppm, with excellent sensitivities and long-term stability.
CERAMICS INTERNATIONAL
(2023)
Article
Materials Science, Multidisciplinary
Deyong Zheng, Huihui Jin, Yucong Liao, Pengxia Ji
Summary: In this study, a highly stable and efficient catalyst, fluorine-doped Co3O4 (F-Co3O4), was developed for hydrogen production by water electrolysis. The F-Co3O4 catalyst exhibited a remarkable reduction in overpotential and demonstrated excellent stability for over 100 hours.
Article
Materials Science, Multidisciplinary
Ziwen Lv, Jintao Wang, Fengyi Wang, Jianqiang Wang, Fuquan Li, Hongtao Chen
Summary: Adding Cu6Sn5 nano particles can effectively inhibit the overgrowth of intermetallic compounds at the interfaces of solder joints in electronic devices, providing a solution to this issue. A new growth mechanism of intermetallic compounds at the interfaces was identified.
Article
Materials Science, Multidisciplinary
Jun Wang, Jiawei Chen, Wanru Liao, Fangyang Liu, Min Liu, Liangxing Jiang
Summary: A BiOI/AgI/Ag plasmonic heterostructure photocathode was successfully designed through electrodeposition, ion-exchange, and illumination methods. This photocathode exhibits superior performance in photoelectrochemical water splitting.
Article
Materials Science, Multidisciplinary
Xiaoxiao Liu, Xianxian Zhou, Xiaotao Ma, Qinbo Yuan, Shibin Liu
Summary: In this study, the authors propose a method to accelerate the reaction of polysulfides in lithium-sulfur batteries using a Ni@OC Mott-Schottky heterojunction as a catalyst. The experimental results demonstrate that the charge redistribution at the Ni@OC interface accelerates electron transfer and enhances catalytic activity, leading to improved reaction kinetics and battery performance.
Article
Materials Science, Multidisciplinary
Dayou Ma, Mohammad Rezasefat, Joziel Aparecido da Cruz, Sandro Campos Amico, Marco Giglio, Andrea Manes
Summary: The matrix has a significant effect on the impact resistance of composite materials. Replacing a brittle polymer with a more flexible one can improve impact resistance, but it poses challenges to standard testing methods. This study designs a new fixture for testing the low-velocity impact of soft composites and investigates the effect of the fixture on the mechanical performance.
Article
Materials Science, Multidisciplinary
Lingchang Wang, Qihang Yang, Huzhen Li, Ming Wei, Qian Wang, Zhenzhong Hu, Mengmeng Zhen
Summary: Bronze titanium dioxide (TiO2(B)) is a promising anode material for lithium-ion batteries due to its high specific capacity. However, its practical applications are hindered by poor conductivity and limited electrochemical kinetics. In this study, TiO2(B)-carbon nanosheets heterostructures are synthesized to enhance the cycling performance and rate capability of TiO2(B).
Article
Materials Science, Multidisciplinary
Atul Thakur, Ritesh Verma, Ankush Chauhan, Fayu Wan, Preeti Thakur
Summary: In this study, BaFe12O19 and BaFe12O19: Epoxy (50:50) nanocomposites were synthesized using the co-precipitation method. The structural information and material properties, such as crystallite size and electrical conductivity, were characterized by XRD, FESEM, EDX, and TEM techniques.
Article
Materials Science, Multidisciplinary
Jingyu Wu, Xinyan Ma, Yong Yang
Summary: A well-defined CoS2@NC(CS-500) hierarchical binder-free catalyst cathode is constructed through in-situ grown of ZIF-67 on carbon cloth and high-temperature carbonization. The cathode shows excellent reaction kinetics and electrochemical performance, providing inspiration for developing advanced Li-CO2 battery catalysts.
Article
Materials Science, Multidisciplinary
Svetlana M. Posokhova, Vladimir A. Morozov, Kirill N. Boldyrev, Dina Deyneko, Erzhena T. Pavlova, Bogdan I. Lazoryak
Summary: This study explores the impact of synthesis method and composition on the structure and luminescence properties of K5Eu1-xHox(MoO4)4 with the palmierite-type matrix. The co-doping of Eu3+ and Ho3+ ions plays a critical role in manipulating charge transfer and luminescence efficiency in the visible and infrared regions.
Article
Materials Science, Multidisciplinary
Jian Wang, Yeting Tao, Jingsheng Wang, Youtian Tao
Summary: A new electron-transport material iTPyBI-CN is developed through non-catalytic C-N coupling reaction. It exhibits better electroluminescence efficiency in organic light-emitting diodes compared to the commercial material TPBI, due to its twisted geometry and higher energy levels.
Article
Materials Science, Multidisciplinary
Tao Zhu, Feng Huang, Shuo Li, Yang Zhou
Summary: This article combines XRD analysis and microscopic structural observation to investigate the changes in limestone after high-temperature treatment. It finds that 500 degrees C is the critical temperature for crystalline and spatial arrangement changes in limestone, and the thermal conductivity, specific heat capacity, and heat storage coefficient gradually decrease after thermal treatment.
Article
Materials Science, Multidisciplinary
Muhammad Haekal Habibie, Fransiska Sri Herwahyu Krismastuti, Abdi Wira Septama, Faiza Maryani, Vivi Fauzia
Summary: This study focuses on the synthesis of zinc oxide nanostructure from zinc recovered from galvanization ash and highlights its potential as a sustainable source of zinc and as an antibacterial agent.
Article
Materials Science, Multidisciplinary
Jingyi Li, Yixin Xing, Wei Gu, Shousi Lu
Summary: In this study, PC@CaP microparticles were fabricated using biomimetic mineralization. The results showed that under environmental stress, PC@CaP exhibited improved stability and antioxidative activity, indicating its potential use in high-added value fields.
Article
Materials Science, Multidisciplinary
Yan Liu, Shunyou Chen
Summary: In this study, TNTs were used as a drug carrier and modified with ZIF-8 and silk fibroin to obtain a new drug loading platform. The results showed that this drug-loaded platform had a good drug release effect in vitro and could promote cell proliferation and osteogenic differentiation.
Article
Materials Science, Multidisciplinary
Chunhui Zhu, Wentao Wang, Qing Zhen, Xinning Huang, Shixin Li, Shaochang Wang, Xiaoping Ma, Xiaoxia Liu, Yalong Jiao, Kai Sun, Zhuangzhi Li, Huaixin Yang, Jianqi Li
Summary: A type of stacking fault is revealed in e-InSe crystal, which is associated with a small stacking-fault energy and shows exceptional plasticity.