Article
Chemistry, Analytical
Nor Ernie Fatriyah Kari, Marhaina Ismail, Aqeel Ahmad, Khaliesah Kamal, Thiam Leng Chew, Mohamad Azmi Bustam
Summary: The discovery of Metal-Organic Frameworks M-CPO-27 as revolutionary for CO2 adsorption, with Ni-CPO-27 showing the best performance among magnesium, zinc, and cobalt metal centers, has been confirmed through simulation and experimental methods. The CO2 adsorption capacity of synthesized Ni-CPO-27 is almost 20% higher than other MOFs.
Article
Biochemistry & Molecular Biology
Anton I. Kudelin, Konstantinos Papathanasiou, Vera Isaeva, Juergen Caro, Tapio Salmi, Leonid M. Kustov
Summary: CPO-27-Mg, a coordination polymer, was rapidly synthesized under microwave irradiation and exhibited high drug loading towards aspirin and paracetamol. The binding of these molecules with the inner surface of the material remained stable, but desorption energies decreased under solvent conditions.
Article
Chemistry, Physical
Agustin A. Godoy, Dimar Villarroel-Rocha, Jose Joaquin Arroyo-Gomez, Celeste Bernini, Griselda Narda, Karim Sapag
Summary: This study investigated the influence of degassing temperature and urea functionalization on the CO2 adsorption performance of CPO-27-Mg. Four samples with different degrees of urea functionalization were obtained through post-synthesis modification treatments. The influence of degassing temperature on the non-functionalized MOF was also evaluated. The resulting compounds were characterized and the thermally treated and functionalized CPO-27-Mg was evaluated for CO2 capture.
Article
Chemistry, Physical
Yusuf Pradesar, Afandi Yusuf, Daniel Manaye Kabtamu, Hsin-Chih Huang, Chen-Hao Wang
Summary: This study synthesizes the nickel-cobalt supported by the metal-organic framework CPO-27 and g-C3N4, demonstrating outstanding catalytic activity and stability for oxygen reduction reaction in alkaline media. The AEMFC using NiCo2-CPO-27/PCN-HT in the cathode shows excellent performance with a maximum power density of 224.4 mW cm(-2), which is 20% higher than AEMFC using Pt/C under the same condition.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Nanoscience & Nanotechnology
Andrew P. Justl, Susan M. Kauzlarich
Summary: Yb14MSb11 (M = Mg, Mn, Zn) are p-type Zintl phases with high thermoelectric efficiencies at 1000 degrees C and melting points above 1200 degrees C under vacuum and/or inert atmosphere. Oxidation behavior of Yb14MSb11 in dry air has been studied, showing different oxidation reactions in the outer layer, inner layer, and core of the material. Yb14ZnSb11 exhibits the best resistance to oxidation and holds promise for further passivation optimization.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Multidisciplinary
H. J. Gao, S. F. Wang, L. M. Fang, G. A. Sun, X. P. Chen, S. N. Tang, H. Yang, G. Z. Sun, D. F. Li
Summary: Nanostructured spinel-type M(M = Mg, Co, Zn)Cr2O4 oxides with novel adsorbents showed excellent adsorption performance for aqueous Congo red removal. Among them, ZnCr2O4 oxide exhibited higher adsorption capacity than MgCr2O4 and CoCr2O4 oxides. The adsorption process was best described by pseudo-second-order kinetics.
MATERIALS TODAY CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Matthew J. Evans, George H. Iliffe, Samuel E. Neale, Claire L. McMullin, J. Robin Fulton, Mathew D. Anker, Martyn P. Coles
Summary: The corresponding Al(mu-O)M complexes were isolated by the reaction of compounds containing Al-Mg and Al-Zn bonds with N2O. Electronic structure analysis revealed mainly ionic Al-O and O-M bonds in these complexes, featuring an anionic mu-oxo centre. The reaction with CO2 confirmed that these species correspond to the proposed intermediates in the formation of mu-carbonate compounds.
CHEMICAL COMMUNICATIONS
(2022)
Article
Chemistry, Inorganic & Nuclear
A. L. Buzlukov, N. Medvedeva, D. Suetin, A. Serdtsev, Y. Baklanova, S. F. Solodovnikov, A. P. Tyutyunnik, T. A. Denisova, O. A. Gulyaeva
Summary: The type and concentration of M element in alluaudite-type compounds play a crucial role in the sodium diffusion process, with higher concentration and charge of M element enhancing sodium mobility. Additionally, sodium dynamics increase with the size of M ion.
JOURNAL OF SOLID STATE CHEMISTRY
(2021)
Article
Engineering, Chemical
Che-Ming Yang, Minh Viet Huynh, Teng-Yun Liang, Tien Khoa Le, Thi Kieu Xuan Huynh, Shih-Yuan Lu, De-Hao Tsai
Summary: Controlled synthesis of metal-organic framework (MOF)-derived Mg-Zn hybrid nanostructure has been demonstrated for the development of high-performance catalysts in biodiesel production, achieving high cycle stability and yield.
ADVANCED POWDER TECHNOLOGY
(2022)
Article
Chemistry, Inorganic & Nuclear
Sachin Pal, Dileep Kumar Yadav, Sitharaman Uma
Summary: The present study focuses on the design of new honeycomb layered oxides, Li3(MnM)SbO6 and Li3(CoM')SbO6, and investigates their structural and magnetic properties. The presence of different metal ions and impurities affects the properties of these compounds. These oxides exhibit antiferromagnetic behavior at low temperatures and show competing ferromagnetic interactions.
SOLID STATE SCIENCES
(2022)
Article
Chemistry, Multidisciplinary
Bodo Felsner, Volodymyr Bon, Jack D. Evans, Friedrich Schwotzer, Ronny Grunker, Irena Senkovska, Stefan Kaskel
Summary: The switching mechanism of the flexible framework Zn4O(benztb)(1.5) (benztb=N,N,N',N'-benzidine tetrabenzoate), also known as DUT-13, was studied using advanced powder X-ray diffraction (PXRD) and gas physisorption techniques. In situ synchrotron PXRD experiments revealed guest-induced breathing in the MOF, which is based on the conformationally labile benztb ligand and results in a reduction in specific pore volume. The high temperature limit for adsorption-induced contraction of 170 K indicates that the DUT-13 framework is softer than other mesoporous MOFs, such as DUT-49, and does not support the formation of overloaded metastable states.
CHEMISTRY-A EUROPEAN JOURNAL
(2021)
Article
Chemistry, Physical
Anastasia Kalashnova, Georgyi Sh Shekhtman
Summary: The glycine-nitrate method was used to synthesize samples in the Li6-2xMxZr2O7 (M = Mg, Ca, Zn) systems, and the synthesized solid solutions exhibited significantly higher conductivity than undoped Li6Zr2O7. The study also investigated the influence of M dopants' electronegativity on the transport properties of the solid electrolytes.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Engineering, Electrical & Electronic
Asif Ali, Amir Salam, Amir Khesro, Muhammad Naeem Khan
Summary: Lead-free Bi(M2/3Nb1/3)O-3 (M = Mg, Zn, Ni) ceramics were successfully prepared and their structure, microstructure, and dielectric properties were investigated. The samples showed differences in crystal structure, microstructure, and dielectric properties, with Bi(Zn2/3Nb1/3)O-3 exhibiting good temperature stability.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2022)
Article
Engineering, Electrical & Electronic
Puneet Kaur, Atul Khanna
Summary: Alkaline earth and zinc vanadate samples prepared by solid state reaction method exhibit distinct crystal structures, good electrical properties, and intense photoluminescence, which are significant for the development of novel luminescent materials.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2021)
Article
Chemistry, Multidisciplinary
Simon M. Vornholt, Caroline G. Elliott, Cameron M. Rice, Samantha E. Russell, Peter J. Kerr, Daniel N. Rainer, Michal Mazur, Mark R. Warren, Paul S. Wheatley, Russell E. Morris
Summary: The size of single crystals of the metal-organic framework CPO-27-Ni was increased using a novel linker modulated synthesis, resulting in high crystallinity and phase purity. Additionally, the materials exhibited high BET surface areas and nitric oxide (NO) release efficiencies.
CHEMISTRY-A EUROPEAN JOURNAL
(2021)
Article
Chemistry, Multidisciplinary
Vinicius Martins, Jun Xu, Ivan Hung, Zhehong Gan, Christel Gervais, Christian Bonhomme, Yining Huang
Summary: In this study, the use of O-17 isotopic enrichment and O-17 SSNMR experiments at an ultrahigh magnetic field of 35.2 T allowed for the complete resolution of all chemically and crystallographically inequivalent oxygen sites in two representative MIL-53(Al) phases. This advancement enhances the potential for using NMR crystallography approach to determine crystal structures of new MOFs and verify existing MOF structures.
MAGNETIC RESONANCE IN CHEMISTRY
(2021)
Article
Chemistry, Physical
Shuo Wang, Dongxue Guo, MengYa Zong, CunZheng Fan, Xu Jun, Dan-Hong Wang
Summary: This study investigated the impact of strong metal-support interaction between Ru quantum dots and g-C3N4 nanosheets on the photocatalytic nitrogen fixation performance, showing that SMSI can enhance the activity and stability of catalysts. The research provides a promising and sustainable strategy for photocatalytic nitrogen fixation.
APPLIED CATALYSIS A-GENERAL
(2021)
Article
Chemistry, Physical
Zongjing Feng, Dong Xiao, Zhengmao Liu, Guangjin Hou, Jun Xu
Summary: The structure and anion exchange behaviors of LYH-X are strongly influenced by X-, resulting in different structures and conversion between them; foreign anions interact specifically with host layers. These characteristics should be taken into consideration in future studies and applications.
JOURNAL OF PHYSICAL CHEMISTRY C
(2021)
Article
Chemistry, Physical
Jun Xu, Yanxin Liu, Yining Huang
Summary: The ultrafast crystallization of AlPO4-5 molecular sieve in a deep eutectic solvent was observed, with fluoride ions accelerating the process and influencing the crystal symmetry. This study provides a new approach to control the crystal structure of molecular sieves.
JOURNAL OF PHYSICAL CHEMISTRY C
(2021)
Article
Chemistry, Physical
Shuo Wang, Xu Zhang, Xue Chang, Meng-Ya Zong, Cun-Zheng Fan, Dong-Xue Guo, Jun Xu, Dan-Hong Wang, Xian-He Bu
Summary: By adjusting the valence state of metal units, this study successfully generated active species within ionic metal-organic frameworks, which is crucial for the rational design of efficient ionic MOFs.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2021)
Article
Chemistry, Multidisciplinary
Kai Li, Zhi-Gang Li, Jun Xu, Yan Qin, Wei Li, Alessandro Stroppa, Keith T. Butler, Christopher J. Howard, Martin T. Dove, Anthony K. Cheetham, Xian-He Bu
Summary: In this study, the nature of ferroelectric phase transitions in hybrid organic-inorganic perovskite ferroelectrics was investigated through structural analysis and lattice dynamics calculations. It was found that the vibrational entropy change of the lattice, along with the rotational entropy change, plays a crucial role in the ferroelectric transition, suggesting that both local and extended lattice fluctuations can be manipulated to create ferroelectricity.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Review
Chemistry, Applied
Dongxue Guo, Shuo Wang, Jun Xu, Wenjun Zheng, Danhong Wang
Summary: e-NRR is an emerging strategy for reducing energy-intensive operations in industrial ammonia synthesis. Defect and interface engineering can enhance the performance of electrocatalysts, but there are challenges and unresolved issues that need further exploration.
JOURNAL OF ENERGY CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Zongsu Han, Kunyu Wang, Hui Min, Jun Xu, Wei Shi, Peng Cheng
Summary: This study develops a general strategy to introduce chirality into metal-organic frameworks and constructs IRMOF-74 analogs with different pore sizes. To enhance detection accuracy, a second luminescent center is introduced for ratiometric sensing. The compounds exhibit pore-size-dependent sensing performance, revealing the importance of pores in MOF-based luminescent sensors.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Physical
Shuo Wang, Ji-Jie Zhang, Meng-Ya Zong, Jun Xu, Dan-Hong Wang, Xian-He Bu
Summary: Energy level engineering through defect level control and single-site heterojunction construction offers opportunities for photocatalytic nitrogen fixation. Ru@Mo-MOF-tri exhibited higher activity due to the presence of more active sites and interface bending. The structure-activity relationship provides clues for designing biomimetic photocatalysts.
Article
Chemistry, Multidisciplinary
Hui Min, Zhonghang Chen, Zongsu Han, Kunyu Wang, Jun Xu, Wei Shi, Peng Cheng
Summary: A series of bilanthanide metalorganic frameworks functionalised with a borono group are shown to detect TMAO with high sensitivity and selectivity by exploiting the inverse emission intensity changes of the two lanthanide centres. The detection of TMAO is crucial for early intervention of cardiovascular disease.
COMMUNICATIONS CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Zhonghang Chen, Yi-Lin Lu, Liang Wang, Jun Xu, Jing Zhang, Xiufang Xu, Peng Cheng, Sihai Yang, Wei Shi
Summary: A molecular nanocage has been studied as an efficient sensing and sorbent material for POPs. The strong host-guest interactions between the nanocage and PFOS contribute to a highly sensitive and unusual turn-on fluorescence response within 10 seconds and a 97% total removal of PFOS from water in 20 minutes.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Multidisciplinary Sciences
Jun Xu, Xingwu Liu, Xingchen Liu, Tao Yan, Hongliu Wan, Zhi Cao, Jeffrey A. Reimer
Summary: This study reports a general method to decipher the apportionment of metal ions in bulk metal-organic frameworks (MOFs) using solid-state nuclear magnetic resonance spectroscopy. The researchers successfully applied this method to Mg1-xNix-MOF-74 and identified all eight possible Mg/Ni arrangements. The results reveal that only two specific Mg/Ni structural arrangements are preferred in Ni-incorporated MOFs.
Article
Chemistry, Physical
Yanxin Liu, Xinyue Sheng, Kongying Zhu, Xia Li, Xinlong Yao, Guangjin Hou, Jun Xu
Summary: A new method is reported here to achieve high-resolution characterization of hydrogen in hydrous materials using 1D and 2D 1H solid-state NMR experiments. By combining MAS NMR, moderate 2H substitution, and high magnetic fields, chemically similar but crystallographically distinct hydrogen sites in a prototypical hydrous material LYH-Br were successfully identified. This advance provides a powerful tool for studying multiple hydrous species in hydrous materials and obtaining previously inaccessible fine structural information.
JOURNAL OF PHYSICAL CHEMISTRY C
(2023)
Article
Chemistry, Multidisciplinary
Zongsu Han, Runhao Zhang, Jialong Jiang, Zhonghang Chen, Youxuan Ni, Weiwei Xie, Jun Xu, Zhen Zhou, Jun Chen, Peng Cheng, Wei Shi
Summary: We report a porous coordination chain-based hydrogen-bonded framework (NKU-1000) for Li+ transport, which exhibits a superior Li+ conductivity, a high Li+ transfer number, and a wide electrochemical window. The assembled solid-state battery with NKU-1000-based SSE shows high discharge capacity with excellent cyclic stability and can work over a wide temperature range without forming lithium dendrites.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Review
Materials Science, Multidisciplinary
Shijia Jiang, Yanxin Liu, Jun Xu
Summary: Rare earth oxynitrides with a perovskite-type structure have shown promise as visible-light-driven photocatalysts for water splitting. Their unique properties, including narrow band gaps, high water stability, and the ability for fine-tuning, present opportunities for addressing the global energy crisis through photocatalysis.
MATERIALS ADVANCES
(2021)