Single-Atom MnN5 Catalytic Sites Enable Efficient Peroxymonosulfate Activation by Forming Highly Reactive Mn(IV)–Oxo Species

Aqueous Iron(IV)–Oxo Complex: An Emerging Powerful Reactive Oxidant Formed by Iron(II)-Based Advanced Oxidation Processes for Oxidative Water Treatment

(2022) Zhen Wang et al.   ENVIRONMENTAL SCIENCE & TECHNOLOGY

Superoxide radical mediated Mn(III) formation is the key process in the activation of peroxymonosulfate (PMS) by Mn-incorporated bacterial-derived biochar

(2022) Bixia Gao et al.   JOURNAL OF HAZARDOUS MATERIALS

Identification of Fenton-like active Cu sites by heteroatom modulation of electronic density

(2022) Xiao Zhou et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Cobalt Single Atoms Anchored on Oxygen‐Doped Tubular Carbon Nitride for Efficient Peroxymonosulfate Activation: Simultaneous Coordination Structure and Morphology Modulation

(2022) Ziwei Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Origin of the Excellent Activity and Selectivity of a Single-Atom Copper Catalyst with Unsaturated Cu-N2 Sites via Peroxydisulfate Activation: Cu(III) as a Dominant Oxidizing Species

(2022) Fan Li et al.   ENVIRONMENTAL SCIENCE & TECHNOLOGY

Mn2O3 as an Electron Shuttle between Peroxymonosulfate and Organic Pollutants: The Dominant Role of Surface Reactive Mn(IV) Species

(2022) Hongchao Li et al.   ENVIRONMENTAL SCIENCE & TECHNOLOGY

Ultrahigh Peroxymonosulfate Utilization Efficiency over CuO Nanosheets via Heterogeneous Cu(III) Formation and Preferential Electron Transfer during Degradation of Phenols

(2022) Yan Wei et al.   ENVIRONMENTAL SCIENCE & TECHNOLOGY

Simultaneous nanocatalytic surface activation of pollutants and oxidants for highly efficient water decontamination

(2022) Ying-Jie Zhang et al.   Nature Communications

Coordination Number Dependent Catalytic Activity of Single‐Atom Cobalt Catalysts for Fenton‐Like Reaction

(2022) Xiaoying Liang et al.   ADVANCED FUNCTIONAL MATERIALS

ABTS as Both Activator and Electron Shuttle to Activate Persulfate for Diclofenac Degradation: Formation and Contributions of ABTS•+, SO4•–, and •OH

(2022) Yixin Huang et al.   ENVIRONMENTAL SCIENCE & TECHNOLOGY

Selective degradation of sulfamethoxazole by N-doped iron-based carbon activated peroxymonosulfate: Collaboration of singlet oxygen and high-valent iron-oxo species

(2022) Jian Wei et al.   SEPARATION AND PURIFICATION TECHNOLOGY

Two-step pyrolysis to anchor ultrahigh-density single-atom FeN5 sites on carbon nitride for efficient Fenton-like catalysis near 0 °C

(2022) Changqing Zhu et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

Axial N Ligand‐Modulated Ultrahigh Activity and Selectivity Hyperoxide Activation over Single‐Atoms Nanozymes

(2022) Han‐Chao Zhang et al.   Advanced Science

Single-Atom Fe Catalyst Outperforms Its Homogeneous Counterpart for Activating Peroxymonosulfate to Achieve Effective Degradation of Organic Contaminants

(2021) Kun Qian et al.   ENVIRONMENTAL SCIENCE & TECHNOLOGY

Interface-Promoted Direct Oxidation of p-Arsanilic Acid and Removal of Total Arsenic by the Coupling of Peroxymonosulfate and Mn-Fe-Mixed Oxide

(2021) Ming-Kun Ke et al.   ENVIRONMENTAL SCIENCE & TECHNOLOGY

Carbon Nitride Supported High‐Loading Fe Single‐Atom Catalyst for Activation of Peroxymonosulfate to Generate 1 O 2 with 100 % Selectivity

(2021) Long‐Shuai Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activity Trends and Mechanisms in Peroxymonosulfate‐Assisted Catalytic Production of Singlet Oxygen over Atomic Metal‐N‐C Catalysts

(2021) Yun Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Novel Nonradical Oxidation of Sulfonamide Antibiotics with Co(II)-Doped g-C3N4-Activated Peracetic Acid: Role of High-Valent Cobalt–Oxo Species

(2021) Banghai Liu et al.   ENVIRONMENTAL SCIENCE & TECHNOLOGY

Density Functional Theory Calculations for Insight into the Heterocatalyst Reactivity and Mechanism in Persulfate-Based Advanced Oxidation Reactions

(2021) Panpan Zhang et al.   ACS Catalysis

Spin-State-Dependent Peroxymonosulfate Activation of Single-Atom M–N Moieties via a Radical-Free Pathway

(2021) Jie Miao et al.   ACS Catalysis

Engineering the Coordination Sphere of Isolated Active Sites to Explore the Intrinsic Activity in Single-Atom Catalysts

(2021) Xin Wu et al.   Nano-Micro Letters

Elucidating the Mechanistic Origin of a Spin State-Dependent FeNx–C Catalyst toward Organic Contaminant Oxidation via Peroxymonosulfate Activation

(2021) Bofan Zhang et al.   ENVIRONMENTAL SCIENCE & TECHNOLOGY

Enthalpy–Entropy Compensation Effect in Oxidation Reactions by Manganese(IV)-Oxo Porphyrins and Nonheme Iron(IV)-Oxo Models

(2021) Mian Guo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Coordination tailoring of Cu single sites on C3N4 realizes selective CO2 hydrogenation at low temperature

(2021) Tang Yang et al.   Nature Communications

Persulfate-Based Advanced Oxidation: Critical Assessment of Opportunities and Roadblocks

(2020) Jaesang Lee et al.   ENVIRONMENTAL SCIENCE & TECHNOLOGY

Trace Cupric Species Triggered Decomposition of Peroxymonosulfate and Degradation of Organic Pollutants: Cu(III) Being the Primary and Selective Intermediate Oxidant

(2020) Li-Hong Wang et al.   ENVIRONMENTAL SCIENCE & TECHNOLOGY

Iron and manganese oxo complexes, oxo wall and beyond

(2020) Virginia A. Larson et al.   Nature Reviews Chemistry

Mn‐O Covalency Governs the Intrinsic Activity of Co‐Mn Spinel Oxides for Boosted Peroxymonosulfate Activation

(2020) Zhi-Yan Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Spectroscopic capture of a low-spin Mn(IV)-oxo species in Ni–Mn3O4 nanoparticles during water oxidation catalysis

(2020) Sunghak Park et al.   Nature Communications

Unraveling the Overlooked Involvement of High-Valent Cobalt-Oxo Species Generated from the Cobalt(II)-Activated Peroxymonosulfate Process

(2020) Yang Zong et al.   ENVIRONMENTAL SCIENCE & TECHNOLOGY

Novel 3D Pd-Cu(OH)2/CF cathode for rapid reduction of nitrate-N and simultaneous total nitrogen removal from wastewater

(2020) Changhui Zhou et al.   JOURNAL OF HAZARDOUS MATERIALS

Confining Free Radicals in Close Vicinity to Contaminants Enables Ultrafast Fenton-like Processes in the Interspacing of MoS2 Membranes

(2019) Yu Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Single-Atom Mn–N4 Site-Catalyzed Peroxone Reaction for the Efficient Production of Hydroxyl Radicals in an Acidic Solution

(2019) Zhuang Guo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Reactive Manganese(IV)-Oxo Porphyrins Showing Temperature-Dependent Reversed Electronic Effect in C–H Bond Activation Reactions

(2019) Mian Guo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Boosting Oxygen Evolution Kinetics by Mn–N–C Motifs with Tunable Spin State for Highly Efficient Solar‐Driven Water Splitting

(2019) Shangcong Sun et al.   Advanced Energy Materials

Further understanding the involvement of Fe(IV) in peroxydisulfate and peroxymonosulfate activation by Fe(II) for oxidative water treatment

(2019) Zhen Wang et al.   CHEMICAL ENGINEERING JOURNAL

NH4Cl-induced low-temperature formation of nitrogen-rich g-C3N4 nanosheets with improved photocatalytic hydrogen evolution

(2019) Xinhe Wu et al.   CARBON

High-Spin Mn(V)-Oxo Intermediate in Nonheme Manganese Complex-Catalyzed Alkane Hydroxylation Reaction: Experimental and Theoretical Approach

(2019) Xiao-Xi Li et al.   INORGANIC CHEMISTRY

Mn-based catalysts for sulfate radical-based advanced oxidation processes: A review

(2019) Jianzhi Huang et al.   ENVIRONMENT INTERNATIONAL

Manganese oxide integrated catalytic ceramic membrane for degradation of organic pollutants using sulfate radicals

(2019) Hong Wu et al.   WATER RESEARCH

Oxidation of Organic Compounds in Water by Unactivated Peroxymonosulfate

(2018) Yi Yang et al.   ENVIRONMENTAL SCIENCE & TECHNOLOGY

Long-Lived Photoexcited State of a Mn(IV)-Oxo Complex Binding Scandium Ions That is Capable of Hydroxylating Benzene

(2018) Namita Sharma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Is Sulfate Radical Really Generated from Peroxydisulfate Activated by Iron(II) for Environmental Decontamination?

(2018) Zhen Wang et al.   ENVIRONMENTAL SCIENCE & TECHNOLOGY

Enhanced peroxymonosulfate activation for phenol degradation over MnO2 at pH 3.5–9.0 via Cu(II) substitution

(2018) Yulin Huang et al.   JOURNAL OF HAZARDOUS MATERIALS

Emerging opportunities for nanotechnology to enhance water security

(2018) Pedro J. J. Alvarez et al.   Nature Nanotechnology

Mechanistic Investigation of Water Oxidation Catalyzed by Uniform, Assembled MnO Nanoparticles

(2017) Kyoungsuk Jin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Generation of sulfate radical through heterogeneous catalysis for organic contaminants removal: Current development, challenges and prospects

(2016) Wen-Da Oh et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

Insights into the generation of high-valent copper-oxo species in ligand-modulated catalytic system for oxidizing organic pollutants

(2016) Yanyan Wang et al.   CHEMICAL ENGINEERING JOURNAL

A Balancing Act: Stability versus Reactivity of Mn(O) Complexes

(2015) Heather M. Neu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Facile Synthesis of Hierarchically Structured Magnetic MnO2/ZnFe2O4 Hybrid Materials and Their Performance in Heterogeneous Activation of Peroxymonosulfate

(2014) Yuxian Wang et al.   ACS Applied Materials & Interfaces

MnxOy/NC and CoxOy/NC Nanoparticles Embedded in a Nitrogen-Doped Carbon Matrix for High-Performance Bifunctional Oxygen Electrodes

(2014) Justus Masa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Understanding the Oxidative Relationships of the Metal Oxo, Hydroxo, and Hydroperoxide Intermediates with Manganese(IV) Complexes Having Bridged Cyclams: Correlation of the Physicochemical Properties with Reactivity

(2012) Guochuan Yin   ACCOUNTS OF CHEMICAL RESEARCH