Cyclic Amide-Anchored NHC-Based Cp*Ir Catalysts for Bidirectional Hydrogenation–Dehydrogenation with CO2/HCO2H Couple

Process intensification for generating and decomposing formic acid, a liquid hydrogen carrier

(2022) Jonathan D. Egbert et al.   IET Renewable Power Generation

Reversible hydrogenation of carbon dioxide to formic acid using a Mn-pincer complex in the presence of lysine

(2022) Duo Wei et al.   Nature Energy

Reusable Single Homogeneous Ir(III)–NHC Catalysts for Bidirectional Hydrogenation–Dehydrogenation of N-Heteroarenes in Water

(2022) Babulal Maji et al.   ORGANOMETALLICS

Engineering of iridium complexes for the efficient hydrogen evolution of formic acid without additives

(2022) Sihang Cheng et al.   JOURNAL OF CATALYSIS

A Low-Coordinate Iridium Complex with a Donor-Flexible O,N-Ligand for Highly Efficient Formic Acid Dehydrogenation

(2022) Nicolas Lentz et al.   ACS Catalysis

Highly efficient additive-free dehydrogenation of neat formic acid

(2021) Sayan Kar et al.   Nature Catalysis

A Proton‐Responsive Pyridyl(benzamide)‐Functionalized NHC Ligand on Ir Complex for Alkylation of Ketones and Secondary Alcohols

(2021) Mandeep Kaur et al.   CHEMISTRY-A EUROPEAN JOURNAL

Formic acid as a potential on‐board hydrogen storage method‐development of  homogeneous noble‐metalcatalysts for the dehydrogenation reactions

(2021) Jian Guo et al.   ChemSusChem

Formic Acid Dehydrogenation for Hydrogen Production Promoted by Grubbs and Hoveyda‐Grubbs Catalysts †

(2021) Qian Wang et al.   CHINESE JOURNAL OF CHEMISTRY

Carbon Dioxide Hydrogenation to Formate Catalyzed by a Bench-Stable, Non-Pincer-Type Mn(I) Alkylcarbonyl Complex

(2021) Sylwia Kostera et al.   ORGANOMETALLICS

Distinct Mechanisms and Hydricities of Cp*Ir-Based CO2 Hydrogenation Catalysts in Basic Water

(2021) A. Nijamudheen et al.   ACS Catalysis

Role of Ligand-Bound CO2 in the Hydrogenation of CO2 to Formate with a (PNP)Mn Catalyst

(2021) Kevin Schlenker et al.   ACS Catalysis

Dehydrogenation of Formic Acid by a Ru II Half Sandwich Catalyst

(2021) Aditi Vatsa et al.   ChemistrySelect

Metal–Ligand Cooperation in Cp*Ir-Pyridylpyrrole Complexes: Rational Design and Catalytic Activity in Formic Acid Dehydrogenation and CO2 Hydrogenation under Ambient Conditions

(2021) Xiu-Fang Mo et al.   INORGANIC CHEMISTRY

“On–Off” Control for On-Demand Hydrogen Production from the Dehydrogenation of Formic Acid

(2021) Fuhua Xu et al.   ACS Catalysis

Picolinamide‐Based Iridium Catalysts for Aqueous Formic Acid Dehydrogenation: Increase in Electron Density of Amide N through Substituents

(2021) Jian Guo et al.   Asian Journal of Organic Chemistry

An Update on Formic Acid Dehydrogenation by Homogeneous Catalysis

(2020) Chao Guan et al.   Chemistry-An Asian Journal

Ligand Design for Catalytic Dehydrogenation of Formic Acid to Produce High-pressure Hydrogen Gas under Base-free Conditions

(2020) Hajime Kawanami et al.   INORGANIC CHEMISTRY

CO2 Hydrogenation and Formic Acid Dehydrogenation Using Ir Catalysts with Amide-Based Ligands

(2020) Ryoichi Kanega et al.   ORGANOMETALLICS

A Proton-Responsive Annulated Mesoionic Carbene (MIC) Scaffold on Ir Complex for Proton/Hydride Shuttle: An Experimental and Computational Investigation on Reductive Amination of Aldehyde

(2020) Pragati Pandey et al.   ORGANOMETALLICS

Understanding the Deactivation Pathways of Iridium(III) Pyridine‐Carboxiamide Catalysts for Formic Acid Dehydrogenation

(2020) Gabriel Menendez Rodriguez et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iridium(I) NHC-phosphine complex-catalyzed hydrogen generation and storage in aqueous formate/bicarbonate solutions using a flow reactor - Effective response to changes in hydrogen demand

(2019) Henrietta Horváth et al.   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

Manganese Mediated Formic Acid Dehydrogenation

(2019) Nickolas H. Anderson et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hydrogen energy, economy and storage: Review and recommendation

(2019) J.O. Abe et al.   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

Exceptional hydrogen storage achieved by screening nearly half a million metal-organic frameworks

(2019) Alauddin Ahmed et al.   Nature Communications

Towards Hydrogen Storage through an Efficient Ruthenium-Catalyzed Dehydrogenation of Formic Acid

(2018) Zhuo Xin et al.   ChemSusChem

Hydrogen Liberation from Formic Acid Mediated by Efficient Iridium(III) Catalysts Bearing Pyridine-Carboxamide Ligands

(2018) Gabriel Menendez Rodriguez et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Hydrogen generation from formic acid decomposition on a highly efficient iridium catalyst bearing a diaminoglyoxime ligand

(2018) Sheng-Mei Lu et al.   GREEN CHEMISTRY

A Rechargeable Hydrogen Battery

(2018) Neethu Christudas Dargily et al.   Journal of Physical Chemistry Letters

Formic Acid Manufacture: Carbon Dioxide Utilization Alternatives

(2018) Marta Rumayor et al.   Applied Sciences-Basel

Carbon Dioxide Hydrogenation and Formic Acid Dehydrogenation Catalyzed by Iridium Complexes Bearing Pyridyl-pyrazole Ligands: Effect of an Electron-donating Substituent on the Pyrazole Ring on the Catalytic Activity and Durability

(2018) Naoya Onishi et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic Formic Acid Dehydrogenation and CO2 Hydrogenation Using Iron PNRP Pincer Complexes with Isonitrile Ligands

(2018) Julia B. Curley et al.   ORGANOMETALLICS

Carbon dioxide hydrogenation catalysed by well-defined Mn(i) PNP pincer hydride complexes

(2017) Federica Bertini et al.   Chemical Science

A Bifunctional Iridium Catalyst Modified for Persistent Hydrogen Generation from Formic Acid: Understanding Deactivation via Cyclometalation of a 1,2-Diphenylethylenediamine Motif

(2017) Asuka Matsunami et al.   ACS Catalysis

Bio-Inspired Mn(I) Complexes for the Hydrogenation of CO2 to Formate and Formamide

(2017) Abhishek Dubey et al.   ACS Catalysis

Nitrogen-Containing Liquid Organic Hydrogen Carriers: Progress and Prospects

(2017) Robert H. Crabtree   ACS Sustainable Chemistry & Engineering

Selective Hydrogen Generation from Formic Acid with Well-Defined Complexes of Ruthenium and Phosphorus-Nitrogen PN3 -Pincer Ligand

(2016) Yupeng Pan et al.   Chemistry-An Asian Journal

Hydrogen Production and Storage on a Formic Acid/Bicarbonate Platform using Water-Soluble N -Heterocyclic Carbene Complexes of Late Transition Metals

(2016) Dominik Jantke et al.   ChemSusChem

Efficient Hydrogen Storage and Production Using a Catalyst with an Imidazoline-Based, Proton-Responsive Ligand

(2016) Lin Wang et al.   ChemSusChem

Highly efficient dehydrogenation of formic acid in aqueous solution catalysed by an easily available water-soluble iridium(iii) dihydride

(2016) G. Papp et al.   DALTON TRANSACTIONS

Base-free hydrogenation of CO2 to formic acid in water with an iridium complex bearing a N,N′-diimine ligand

(2016) Sheng-Mei Lu et al.   GREEN CHEMISTRY

Selective Formic Acid Dehydrogenation Catalyzed by Fe-PNP Pincer Complexes Based on the 2,6-Diaminopyridine Scaffold

(2016) Irene Mellone et al.   ORGANOMETALLICS

1,2-Addition of Formic or Oxalic Acid to –N{CH2CH2(PiPr2)}2-Supported Mn(I) Dicarbonyl Complexes and the Manganese-Mediated Decomposition of Formic Acid

(2016) Aaron M. Tondreau et al.   ORGANOMETALLICS

Efficient and Mild Carbon Dioxide Hydrogenation to Formate Catalyzed by Fe(II) Hydrido Carbonyl Complexes Bearing 2,6-(Diaminopyridyl)diphosphine Pincer Ligands

(2016) Federica Bertini et al.   ACS Catalysis

Hydrogenation of CO2 to formic acid with iridiumIII(bisMETAMORPhos)(hydride): the role of a dormant fac-IrIII(trihydride) and an active trans-IrIII(dihydride) species

(2016) S. Oldenhof et al.   Catalysis Science & Technology

Metal-Ligand Cooperation

(2015) Julia R. Khusnutdinova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Viable Hydrogen Storage and Release System Based on Cesium Formate and Bicarbonate Salts: Mechanistic Insights into the Hydrogen Release Step

(2015) Katerina Sordakis et al.   ChemCatChem

Simple Continuous High-Pressure Hydrogen Production and Separation System from Formic Acid under Mild Temperatures

(2015) Masayuki Iguchi et al.   ChemCatChem

Unprecedentedly High Formic Acid Dehydrogenation Activity on an Iridium Complex with anN,N′-Diimine Ligand in Water

(2015) Zhijun Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Water-Soluble Iridium-NHC-Phosphine Complexes as Catalysts for Chemical Hydrogen Batteries Based on Formate

(2015) Henrietta Horváth et al.   ChemSusChem

Amine-Free Reversible Hydrogen Storage in Formate Salts Catalyzed by Ruthenium Pincer Complex without pH Control or Solvent Change

(2015) Jotheeswari Kothandaraman et al.   ChemSusChem

Dehydrogenation of formic acid by Ir–bisMETAMORPhos complexes: experimental and computational insight into the role of a cooperative ligand

(2015) Sander Oldenhof et al.   Chemical Science

Highly Robust Hydrogen Generation by Bioinspired Ir Complexes for Dehydrogenation of Formic Acid in Water: Experimental and Theoretical Mechanistic Investigations at Different pH

(2015) Wan-Hui Wang et al.   ACS Catalysis

Interconversion of Formic Acid and Carbon Dioxide by Proton-Responsive, Half-Sandwich Cp*IrIII Complexes: A Computational Mechanistic Investigation

(2015) Mehmed Z. Ertem et al.   ACS Catalysis

Liquid organic hydrogen carriers

(2015) Teng He et al.   Journal of Energy Chemistry

A Rechargeable Hydrogen Battery Based on Ru Catalysis

(2014) Shih-Fan Hsu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Efficient Reversible Hydrogenation of Carbon Dioxide to Formates Using a Ruthenium PNP-Pincer Catalyst

(2014) Georgy A. Filonenko et al.   ChemCatChem

Exploring the Reactivity of Nickel Pincer Complexes in the Decomposition of Formic Acid to CO2/H2and the Hydrogenation of NaHCO3to HCOONa

(2014) Stephan Enthaler et al.   ChemCatChem

Formic Acid Dehydrogenation with Bioinspired Iridium Complexes: A Kinetic Isotope Effect Study and Mechanistic Insight

(2014) Wan-Hui Wang et al.   ChemSusChem

Current situation and prospect of hydrogen storage technology with new organic liquid

(2014) Zhao Jiang et al.   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

Lewis Acid-Assisted Formic Acid Dehydrogenation Using a Pincer-Supported Iron Catalyst

(2014) Elizabeth A. Bielinski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Hydrogen Liberation from Formic Acid Catalyzed by a Well-Defined Iron Pincer Complex under Mild Conditions

(2013) Thomas Zell et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Cobalt-Based Catalyst for the Hydrogenation of CO2 under Ambient Conditions

(2013) Matthew S. Jeletic et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Insight through Factors Controlling Effective Hydrogenation of CO2 Catalyzed by Bioinspired Proton-Responsive Iridium(III) Complexes

(2013) Wan-Hui Wang et al.   ACS Catalysis

Catalytic CO2 Hydrogenation to Formate by a Ruthenium Pincer Complex

(2013) Chelsea A. Huff et al.   ACS Catalysis

Catalytic interconversion between hydrogen and formic acid at ambient temperature and pressure

(2012) Yuta Maenaka et al.   Energy & Environmental Science

Towards the development of a hydrogen battery

(2012) Albert Boddien et al.   Energy & Environmental Science

Reversible hydrogen storage using CO2 and a proton-switchable iridium catalyst in aqueous media under mild temperatures and pressures

(2012) Jonathan F. Hull et al.   Nature Chemistry

Long-range metal–ligand bifunctional catalysis: cyclometallated iridium catalysts for the mild and rapid dehydrogenation of formic acid

(2012) Jonathan H. Barnard et al.   Chemical Science

CO2-“Neutral” Hydrogen Storage Based on Bicarbonates and Formates

(2011) Albert Boddien et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Low-Pressure Hydrogenation of Carbon Dioxide Catalyzed by an Iron Pincer Complex Exhibiting Noble Metal Activity

(2011) Robert Langer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Charge/Discharge Device for Chemical Hydrogen Storage and Generation

(2011) Gábor Papp et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogen Storage in Metal–Organic Frameworks

(2011) Myunghyun Paik Suh et al.   CHEMICAL REVIEWS

Secondary Coordination Sphere Interactions Facilitate the Insertion Step in an Iridium(III) CO2Reduction Catalyst

(2011) Timothy J. Schmeier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Studies on the Reversible Hydrogenation of Carbon Dioxide Catalyzed by an Ir-PNP Complex

(2011) Ryo Tanaka et al.   ORGANOMETALLICS

‘(η6-arene)Ru(bis-NHC)’ complexes for the reduction of CO2 to formate with hydrogen and by transfer hydrogenation with iPrOH

(2010) Sergio Sanz et al.   DALTON TRANSACTIONS

Highly efficient hydrogen evolution by decomposition of formic acid using an iridium catalyst with 4,4′-dihydroxy-2,2′-bipyridine

(2009) Yuichiro Himeda   GREEN CHEMISTRY

Catalytic Hydrogenation of Carbon Dioxide Using Ir(III)−Pincer Complexes

(2009) Ryo Tanaka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New Approach to the Reduction of Carbon Dioxide: CO2Reduction to Formate by Transfer Hydrogenation iniPrOH

(2009) Sergio Sanz et al.   ORGANOMETALLICS

Controlled Generation of Hydrogen from Formic Acid Amine Adducts at Room Temperature and Application in H2/O2Fuel Cells

(2008) Björn Loges et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Viable Hydrogen-Storage System Based On Selective Formic Acid Decomposition with a Ruthenium Catalyst

(2008) Céline Fellay et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION