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Title
Photoactive Copper Complexes: Properties and Applications
Authors
Keywords
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Journal
Chemical Reviews
Volume 122, Issue 22, Pages 16365-16609
Publisher
American Chemical Society (ACS)
Online
2022-11-09
DOI
10.1021/acs.chemrev.2c00033
References
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- The Different Faces of Photoredox Catalysts: Visible-Light-Mediated Atom Transfer Radical Addition (ATRA) Reactions of Perfluoroalkyl Iodides with Styrenes and Phenylacetylenes
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- Thermochromic Solid-State Emission of Dipyridyl Sulfoxide Cu(I) Complexes
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- Visible-light induced copper(i)-catalysed denitrogenative oxidative coupling of hydrazinylpyridines with terminal alkynes
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- Cyclic Hypervalent Iodine Reagents for Azidation: Safer Reagents and Photoredox-Catalyzed Ring Expansion
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- Aqueous Benzylic C–H Trifluoromethylation for Late-Stage Functionalization
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- Cu(i) vs. Ru(ii) photosensitizers: elucidation of electron transfer processes within a series of structurally related complexes containing an extended π-system
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- Synthesis, Spectral Characterization, Redox Properties of [Cu(4-ampc)2]BPh4 and [Cu(4-ampc)(PPh3)2]BPh4: Crystal Structure of [Cu(4-ampc)2]BPh4
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- Copper catalyzed photoredox synthesis of α-keto esters, quinoxaline, and naphthoquinone: controlled oxidation of terminal alkynes to glyoxals
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- [Cu(P^P)(N^N)][PF6] compounds with bis(phosphane) and 6-alkoxy, 6-alkylthio, 6-phenyloxy and 6-phenylthio-substituted 2,2′-bipyridine ligands for light-emitting electrochemical cells
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- Bisubstituted-biquinoline Cu(i) complexes: synthesis, mesomorphism and photophysical studies in solution and condensed states
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- Visible-Light-Driven, Copper-Catalyzed Decarboxylative C(sp3 )−H Alkylation of Glycine and Peptides
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- Photocatalyic Appel reaction enabled by copper-based complexes in continuous flow
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- Heteroleptic Copper(I) Complexes Prepared from Phenanthroline and Bis-Phosphine Ligands: Rationalization of the Photophysical and Electrochemical Properties
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- Photoactive Complexes with Earth-Abundant Metals
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- Highly Efficient and Robust Photocatalytic Systems for CO2 Reduction Consisting of a Cu(I) Photosensitizer and Mn(I) Catalysts
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- Copper(II)-Catalyzed Asymmetric Photoredox Reactions: Enantioselective Alkylation of Imines Driven by Visible Light
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- Visible-Light-Mediated Photoredox-Catalyzed Regio- and Stereoselective Chlorosulfonylation of Alkynes
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- Cu Photoredox Catalysts Supported by a 4,6-Disubstituted 2,2′-Bipyridine Ligand: Application in Chlorotrifluoromethylation of Alkenes
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- Synthesis, structures, luminescence and terahertz time-domain spectroscopy of nine Cu(I) complexes with P^P ligands and 1,10-phenanthroline derivatives
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- Spectroscopic Characterization and Mechanistic Studies on Visible Light Photoredox Carbon–Carbon Bond Formation by Bis(arylimino)acenaphthene Copper Photosensitizers
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- Visible-Light-Induced, Copper-Catalyzed Three-Component Coupling of Alkyl Halides, Olefins, and Trifluoromethylthiolate To Generate Trifluoromethyl Thioethers
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- Visible-Light-Mediated Regioselective Chlorosulfonylation of Alkenes and Alkynes: Introducing the Cu(II) Complex [Cu(dap)Cl2] to Photochemical ATRA Reactions
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- Engineering Luminescence Lifetimes of Cu(I) Complexes for Optical Multiplexing
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- Atom‐Transfer Radical Addition Photocatalysis Using a Heteroleptic Copper Complex
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- Heteroleptic copper(I) photosensitizers with carbazole-substituted phenanthroline ligands: Synthesis, photophysical properties and application to photocatalytic H2 generation
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- Coordination Behavior of N ,N′ -Bis(diisopropylphosphinoacetyl)-o -phenylenediamide with NiII and CuI Ions
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- Earth-abundant photocatalytic systems for the visible-light-driven reduction of CO2 to CO
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- Synthesis, Structures, and Photophysical Properties of a Series of Rare Near-IR Emitting Copper(I) Complexes
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- Syntheses, Photoluminescence, and Electroluminescence of a Series of Sublimable Bipolar Cationic Cuprous Complexes with Thermally Activated Delayed Fluorescence
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- Heteroleptic Cu(I) complexes containing polypyridyl ligands and triphenylphosphine: Synthesis, structure, photophysical properties, DFT studies and applications in co-sensitized solar cells
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- Synthesis, characterization, luminescence and catalytic properties of copper(I) complexes with N-(2-pyridylmethylene)-1,5-dimethyl-2-pyrazole-3-(2H)-one and triphenylphosphine as ligands
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- Visible Light Copper Photoredox-Catalyzed Aerobic Oxidative Coupling of Phenols and Terminal Alkynes: Regioselective Synthesis of Functionalized Ketones via C≡C Triple Bond Cleavage
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- Copper-Catalyzed Alkylation of Aliphatic Amines Induced by Visible Light
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- Photoinduced, Copper-Catalyzed Decarboxylative C–N Coupling to Generate Protected Amines: An Alternative to the Curtius Rearrangement
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- Design of a Photoredox Catalyst that Enables the Direct Synthesis of Carbamate-Protected Primary Amines via Photoinduced, Copper-Catalyzed N-Alkylation Reactions of Unactivated Secondary Halides
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- Photoinduced, Copper-Catalyzed Alkylation of Amines: A Mechanistic Study of the Cross-Coupling of Carbazole with Alkyl Bromides
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- Copper (Photo)redox Catalyst for Radical Photopolymerization in Shadowed Areas and Access to Thick and Filled Samples
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- A General Copper Catalyst for Photoredox Transformations of Organic Halides
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- Photoinduced, Copper-Promoted Regio- and Stereoselective Decarboxylative Alkylation of α,β-Unsaturated Acids with Alkyl Iodides
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- Syntheses, structural characterizations and terahertz spectra of Ag(I)/Cu(I) complexes with bis[2-(diphenylphosphino)phenyl]ether and N^N ligands
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- Synthesis, structures and photophysical properties of Cu(I) phosphine complexes with various diimine ligands
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- Reduction of aryl halides by consecutive visible light-induced electron transfer processes
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- A green emitting phosphorescent copper(I) complex with tetrazole derived ligand for electroluminescence application
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- Ambient-Light-Mediated Copper-Catalyzed CC and CN Bond Formation
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- Highly efficient blue-green delayed fluorescence from copper(i) thiolate complexes: luminescence color alteration by orientation change of the aryl ring
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- Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis
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- Rational Design of Strongly Blue-Emitting Cuprous Complexes with Thermally Activated Delayed Fluorescence and Application in Solution-Processed OLEDs
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- A Noble-Metal-Free System for Photocatalytic Hydrogen Production from Water
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- Synthesis, Crystal Structure and Photophysical Properties of Pyrene-Helicene Hybrids
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- Aryl Radical Formation by Copper(I) Photocatalyzed Reduction of Diaryliodonium Salts: NMR Evidence for a CuII/CuIMechanism
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- First application of the HETPHEN concept to new heteroleptic bis(diimine) copper(i) complexes as sensitizers in dye sensitized solar cells
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- Improving the photoresponse of copper(i) dyes in dye-sensitized solar cells by tuning ancillary and anchoring ligand modules
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- Highly efficient thermally activated fluorescence of a new rigid Cu(i) complex [Cu(dmp)(phanephos)]+
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- Synthesis, Characterization, and Photophysics of Oxadiazole- and Diphenylaniline-Substituted Re(I) and Cu(I) Complexes
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- Synthesis, characterization and striking photoluminescence variation of a series of copper(I) complexes containing oxadiazole ligand
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- Copper quantum dots on TiO2: A high-performance, low-cost, and nontoxic photovoltaic material
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- A New Family of Nucleophiles for Photoinduced, Copper-Catalyzed Cross-Couplings via Single-Electron Transfer: Reactions of Thiols with Aryl Halides Under Mild Conditions (O °C)
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- A Versatile Approach to Ullmann C–N Couplings at Room Temperature: New Families of Nucleophiles and Electrophiles for Photoinduced, Copper-Catalyzed Processes
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- Robust Cuprous Phenanthroline Sensitizer for Solar Hydrogen Photocatalysis
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- Catalytic Ketyl-Olefin Cyclizations Enabled by Proton-Coupled Electron Transfer
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- Copper(II)/Tertiary Amine Synergy in Photoinduced Living Radical Polymerization: Accelerated Synthesis of ω-Functional and α,ω-Heterofunctional Poly(acrylates)
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- Photoinitiated ATRP in Inverse Microemulsion
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- Oxyarylation and Aminoarylation of Styrenes Using Photoredox Catalysis
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- Visible-light-induced, copper(i)-catalysed C–N coupling between o-phenylenediamine and terminal alkynes: one-pot synthesis of 3-phenyl-2-hydroxy-quinoxalines
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- Copper(I) complexes bases on a new indazol-4,7-dione ligand
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- Evaluation and development of novel photoinitiator complexes for photoinitiating the copper-catalyzed azide–alkyne cycloaddition reaction
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- Synthesis, crystal structure and photoluminescence of phosphorescent copper (I) complexes containing hole-transporting carbazoly moiety
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- Visible-Light-Induced Intermolecular Atom-Transfer Radical Addition of Benzyl Halides to Olefins: Facile Synthesis of Tetrahydroquinolines
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- Investigation of a copper(i) biquinoline complex for application in dye-sensitized solar cells
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- Photo-Induced Sonogashira CC Coupling Reaction Catalyzed by Simple Copper(I) Chloride Salt at Room Temperature
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- The Reaction of Tertiary Anilines with Maleimides under Visible Light Redox Catalysis
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- Metal-Free, Visible Light-Induced Borylation of Aryldiazonium Salts: A Simple and Green Synthetic Route to Arylboronates
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- Three-component Oxytrifluoromethylation of Alkenes: Highly Efficient and Regioselective Difunctionalization of CC Bonds Mediated by Photoredox Catalysts
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- Photocatalytic Water Reduction with Copper-Based Photosensitizers: A Noble-Metal-Free System
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- External Regulation of Controlled Polymerizations
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- Highly Efficient Ultrafast Electron Injection from the Singlet MLCT Excited State of Copper(I) Diimine Complexes to TiO2Nanoparticles
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- Efficient luminescence from a copper(i) complex doped in organic light-emitting diodes by suppressing C–H vibrational quenching
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- [Cu(dap)2Cl] As an Efficient Visible-Light-Driven Photoredox Catalyst in Carbon-Carbon Bond-Forming Reactions
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- Synthesis and characterisation of neutral mononuclear cuprous complexes based on dipyrrin derivatives and phosphine mixed-ligands
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- Exploring copper(i)-based dye-sensitized solar cells: a complementary experimental and TD-DFT investigation
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- Copper(i) complexes with bipyridyl and phosphine ligands: a systematic study
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- A copper(i) dye-sensitised TiO2-based system for efficient light harvesting and photoconversion of CO2 into hydrocarbon fuel
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- Capturing the geometry of the emissive state of a Cu(i) red emitter through strong intramolecular stacking forces
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- New tetrazole-based Cu(i) homo- and heteroleptic complexes with various P^P ligands: synthesis, characterization, redox and photophysical properties
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- Solvated-Ion-Pairing-Sensitive Molecular Bistability Based on Copper(I)-Coordinated Pyrimidine Ring Rotation
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- Synthesis, crystal structure, and conjugation properties of phenanthroline copper phosphine complexes
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- Synthesis, crystal structure, photoluminescence and theoretical studies of a series of copper(I) compounds based on imidazole derivatives
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- A series of copper complexes with carbazole and oxadiazole moieties: Synthesis, characterization and luminescence performance
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- Improved O2 sensing performance by modifying P–P ligand in [Cu(N–N)(P–P)] complex
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- Strong Steric Hindrance Effect on Excited State Structural Dynamics of Cu(I) Diimine Complexes
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- Photoinduced Multistep Charge Separation in a Heteroleptic Cu(I) Bis(phenanthroline)-Based Donor–Chromophore–Acceptor Triad
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- Reversible Copper(II)/(I) Electrochemical Potential Switching Driven by Visible Light-Induced Coordinated Ring Rotation
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- Exceptionally Long-Lived Luminescence from [Cu(I)(isocyanide)2(phen)]+ Complexes in Nanoporous Crystals Enables Remarkable Oxygen Gas Sensing
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- Photochemically Mediated Atom Transfer Radical Polymerization of Methyl Methacrylate Using ppm Amounts of Catalyst
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- Engaging unactivated alkyl, alkenyl and aryl iodides in visible-light-mediated free radical reactions
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- Toward a Visible Light Mediated Photocyclization: Cu-Based Sensitizers for the Synthesis of [5]Helicene
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- Structural and Photophysical Studies of Phosphorescent Three-Coordinate Copper(I) Complexes Supported by an N-Heterocyclic Carbene Ligand
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- Steric-influenced fluxionality in monomeric two and three coordinate copper(I) complexes with a trans-chelating bis-pyrazole ligand
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- Syntheses, structures and photophysical properties of a series of luminescent copper(I) mixed-ligand complexes
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- Structural, electronic and computational studies of heteroleptic Cu(I) complexes of 6,6′-dimesityl-2,2′-bipyridine with sulfur-substituted dipyridophenazine ligands
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- Photoinduced Ullmann C-N Coupling: Demonstrating the Viability of a Radical Pathway
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- Study on the synthesis, characterization, photophysical performance and oxygen-sensing behavior of a luminescent Cu(I) complex with large conjugation plane
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- Addressing the terawatt challenge: scalability in the supply of chemical elements for renewable energy
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- Visible Light and Sunlight Photoinduced ATRP with ppm of Cu Catalyst
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- Highly efficient green organic light-emitting diodes containing luminescent tetrahedral copper(i) complexes
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- Restricting the geometrical relaxation in four-coordinate copper(i) complexes using face-to-face and edge-to-face π-interactions
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- Synthesis, structural characterization and luminescent properties of a series of Cu(i) complexes based on polyphosphine ligands
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- Photoluminescent Copper(I) Complexes with Amido-Triazolato Ligands
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- New Heteroleptic Bis-Phenanthroline Copper(I) Complexes with Dipyridophenazine or Imidazole Fused Phenanthroline Ligands: Spectral, Electrochemical, and Quantum Chemical Studies
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- Synthesis and Characterization of Neutral Luminescent Diphosphine Pyrrole- and Indole-Aldimine Copper(I) Complexes
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- Luminescent mononuclear copper(I) heteroleptic complexes with 6-cyano-2,2′-bipyridine
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- Synthesis, crystal structure and photoluminescence of phosphorescent copper (I) complexes containing hole-transporting carbazolyl group
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- Fabrication and performances of an optical sensor system constructed by a novel Cu(I) complex embedded on silica matrix
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- Copper(i) complexes for sustainable light-emitting electrochemical cells
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- Synthesis and structural characterization of heteroleptic Cu(I) perchlorate complexes with diimines derived from pyridinyliminobenzoic acids
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- Can Polypyridyl Cu(I)-based Complexes Provide Promising Sensitizers for Dye-Sensitized Solar Cells? A Theoretical Insight into Cu(I) versus Ru(II) Sensitizers
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- Coherent Nuclear Dynamics in Ultrafast Photoinduced Structural Change of Bis(diimine)copper(I) Complex
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- Systematic Investigation of the Metal-Structure–Photophysics Relationship of Emissive d10-Complexes of Group 11 Elements: The Prospect of Application in Organic Light Emitting Devices
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- Highly Efficient Green Organic Light-Emitting Diodes Containing Luminescent Three-Coordinate Copper(I) Complexes
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- Visible-light-mediated conversion of alcohols to halides
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- Synthesis, characterization and theoretical analysis on a oxygen-sensing phosphorescent copper(I) complex
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- A phosphorescent copper(I) complex: Synthesis, characterization, photophysical property, and sensing performance towards molecular oxygen
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- Diamine ligands with multiple coplanar conjugation rings and their phosphorescent copper complexes: Synthesis, characterization, crystal structures, and photophysical property
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- Nanostructures of tetranuclear copper(i) complexes with short Cu(i)⋯Cu(i) contacts: crystallization-induced emission enhancement
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- Efficient luminescence from easily prepared three-coordinate copper(i) arylamidophosphines
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- Synthesis and characterization of phosphorescent three-coordinate Cu(i)–NHC complexes
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- Visible light photoredox catalysis: applications in organic synthesis
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- Temperature-dependent Emission of Copper(I) Phenanthroline Complexes with Bulky Substituents: Estimation of an Energy Gap between the Singlet and Triplet MLCT States
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- Synthesis, characterization, spectroscopic and electrochemical properties of new mono- and binuclear copper(I) complexes with substituted 2,2′-bipyridine
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- Sticky complexes: carboxylic acid-functionalized N-phenylpyridin-2-ylmethanimine ligands as anchoring domains for copper and ruthenium dye-sensitized solar cells
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- Intramolecular π-stacking in copper(i) diketiminate phenanthroline complexes
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- Copper-complexed catenanes and rotaxanes in motion: 15 years of molecular machines
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- Substituted [Cu(i)(POP)(bipyridyl)] and related complexes: Synthesis, structure, properties and applications to dye-sensitised solar cells
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- Neutral copper(i) phosphorescent complexes from their ionic counterparts with 2-(2′-quinolyl)benzimidazole and phosphine mixed ligands
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- Comparison of the Structure and Stability of New α-Diimine Complexes of Copper(I) and Silver(I): Density Functional Theory versus Experimental
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- Synthesis, characterization, crystal structures, and photophysical properties of a series of room-temperature phosphorescent copper(I) complexes with oxadiazole-derived diimine ligand
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- Spectroscopic and electrochemical properties of heteroleptic cationic copper complexes bis-(diphenylphosphino)alkane-(2,2′-biquinoline)copper(I). Crystal structure of bis(diphenylphosphino)ethane-(2,2′-biquinoline)copper(I) perchlorate
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- Impact of substituents in the N∧N ligand on the emission wavelength of Cu(I) complexes: Insight from experimental and theoretical approach
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- Novel green-emitting copper(I) complexes with electron donors incorporated ligands: Synthesis, photophysical properties, and electroluminescence performances
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- A series of copper(I) complexes with electron donor/acceptor embedded ligands: Synthesis, photophysical and electroluminescent properties
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- Influence of Ligand Substitution on Excited State Structural Dynamics in Cu(I) Bisphenanthroline Complexes†
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- Estimation of Standard Reduction Potentials of Halogen Atoms and Alkyl Halides
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- Dual Emission Caused by Ring Inversion Isomerization of a 4-Methyl-2-pyridyl-pyrimidine Copper(I) Complex
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- Asymmetric Suzuki Cross-Couplings of Activated Secondary Alkyl Electrophiles: Arylations of Racemic α-Chloroamides
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- Oxygen Gas Sensing by Luminescence Quenching in Crystals of Cu(xantphos)(phen)+Complexes
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- Photoinduced Controlled Radical Polymerization
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- Photoinitiated Polymerization: Advances, Challenges, and Opportunities
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- Light-induced copper(I)-catalyzed click chemistry
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- Photoluminescence studies of iodobis-(tricyclohexylphosphine)copper(I) and iodobis-(tricyclohexylphosphine)copper(I) benzene solvate
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- Synthesis, characterization and oxygen-sensing properties of a novel luminescent Cu(I) complex
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- A facile iodide-controlled fluorescent switch based on the interconversion between two- and three-coordinate copper(i) complexes
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- Void Space Containing Crystalline Cu(I) Phenanthroline Complexes As Molecular Oxygen Sensors
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- Towards Sustainable Dyes for Dye-Sensitized Solar Cells
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- Copper(i) complexes of 6,6′-disubstituted 2,2′-bipyridine dicarboxylic acids: new complexes for incorporation into copper-based dye sensitized solar cells (DSCs)
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- 2,11-Dialkylated 1,12-Diazaperylene Copper(I) Complexes: First Supramolecular Column Assemblies by π-π Stacking between Homoleptic Tetrahedral Metal Complexes, Exhibiting Low-Energy MLCT Transitions
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- Synthesis, structure and electronic spectra of new three-coordinated copper(I) complexes with tricyclohexylphosphine and diimine ligands
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- Synthesis, characterization, and structures of copper(I) complexes withN,N′-bis[1-(4-chlorophenyl)ethylidene]ethane-1,2-diamine andN,N′-bis[1-(4-nitrophenyl)ethylidene]ethane-1,2-diamine
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- Realization of High-Energy Emission from [Cu(N−N)(P−P)]+ Complexes for Organic Light-Emitting Diode Applications
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- What determines the performance of metal phthalocyanines (MPc, M=Zn, Cu, Ni, Fe) in organic heterojunction solar cells? A combined experimental and theoretical investigation
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- A Synthetic, Structural, Spectroscopic and DFT study of ReI, CuI, RuII and IrIII Complexes Containing Functionalised Dipyrido[3,2-a:2′,3′-c]phenazine (dppz)
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- Efficient Visible Light Photocatalysis of [2+2] Enone Cycloadditions
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- Synthesis and Photovoltaic Application of Copper(I) Sulfide Nanocrystals
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- Synthesis, spectroscopic and electrochemical characterization of copper(I) complexes with functionalized pyrazino[2,3-f]-1,10-phenanthroline
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- Synthesis, crystal structures and spectroscopic properties of copper(I) complexes containing β-dialdiminato supporting ligands
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