Journal
ORGANIC LETTERS
Volume 23, Issue 9, Pages 3663-3668Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.1c01050
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Funding
- Natural Science Foundation of of Shandong Province [ZR2020JQ07, ZR2016JL012]
- National Natural Science Foundation of China [21302110, 21801007]
- Taishan Scholars Construction Projects [tsqn201812075]
- Youth Innovation Science and Technology Plan of Colleges and University in Shandong Province [2019KJC003]
- Scientific Research Foundation of Qingdao University of Science and Technology
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An efficient visible-light-assisted, copper-catalyzed sulfonylation of aryl halides with sulfinates is reported, using a single ligand Cu-I photocatalyst formed in situ for the transformation. Diverse organosulfones were obtained in moderate to good yields, demonstrating a promising approach toward the synthesis of diverse and useful organosulfones.
An efficient visible-light-assisted, copper-catalyzed sulfonylation of aryl halides with sulfinates is reported. In our protocol, a single ligand Cu-I photocatalyst formed in situ was used in the photocatalytic transformation. Diverse organosulfones were obtained in moderate to good yields. This strategy demonstrates a promising approach toward the synthesis of diverse and useful organosulfones.
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