Transition-Metal-Catalyzed Directing-Group-Assisted C4-H Carbon–Carbon Bond Formation of Indole

Directed C–H Functionalization of C3-Aldehyde, Ketone, and Acid/Ester-Substituted Free (NH) Indoles with Iodoarenes via a Palladium Catalyst System

(2022) Yunus Taskesenligil et al.   JOURNAL OF ORGANIC CHEMISTRY

Directing Group Guided Site-Selective Diversification of Indoles by Aziridine: Synthesis of β-Indolylethylamines

(2022) Ashfaq Ahmad et al.   ORGANIC LETTERS

Cascade Reaction to Selectively Synthesize Multifunctional Indole Derivatives by Ir III ‐Catalyzed C−H Activation

(2021) Xin‐Yue Chai et al.   CHEMISTRY-A EUROPEAN JOURNAL

Breaking the Trend: Insight into Unforeseen Reactivity of Alkynes in Cobalt-Catalyzed Weak Chelation-Assisted Regioselective C(4)–H Functionalization of 3-Pivaloyl Indole

(2021) Shyam Kumar Banjare et al.   ACS Catalysis

Rhodium(III)‐Catalyzed Regioselective C−H Allylation and Prenylation of Indoles at C4‐Position

(2021) Shang‐Shi Zhang et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium-Catalyzed 2-fold C–H Activation/C–C Coupling for C4-Arylation of Indoles Using Weak Chelation

(2021) Shubhajit Basak et al.   ORGANIC LETTERS

Weak Coordination Enabled Switchable C4-Alkenylation and Alkylation of Indoles with Allyl Alcohols

(2020) Sourav Pradhan et al.   ORGANIC LETTERS

Thioether-Directed C4-Selective C–H Acylmethylation of Indoles Using α-Carbonyl Sulfoxonium Ylides

(2020) Chandrababu Naidu Kona et al.   ORGANIC LETTERS

Dual-Functional Enone-Directing Group/Electrophile for Sequential C–C Bond Formation with α-Diazomalonates: A Short Synthesis of Chiral 3,4-Fused Tricyclic Indoles

(2020) Shingo Harada et al.   ACS Catalysis

Palladium Catalyzed Site-Selective C4-Arylation and Olefination of Indoles and Azaindoles

(2019) Thrimurtulu Neetipalli et al.   ADVANCED SYNTHESIS & CATALYSIS

Cobalt-Catalyzed Regioselective Direct C-4 Alkenylation of 3-Acetylindole with Michael Acceptors Using a Weakly Coordinating Functional Group

(2019) Shyam Kumar Banjare et al.   ORGANIC LETTERS

Weak Coordination-Guided Regioselective Direct Redox-Neutral C4 Allylation of Indoles with Morita–Baylis–Hillman Adducts

(2019) Sourav Pradhan et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Regioselective Direct C4-Alkylation and C2-Annulation of Indoles: Straightforward Access to Indolopyridone

(2018) Aniruddha Biswas et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Weak Directing Group Steered Formal Oxidative [2+2+2]-Cyclization for Selective Benzannulation of Indoles

(2018) Kiran R. Bettadapur et al.   JOURNAL OF ORGANIC CHEMISTRY

C4–H indole functionalisation: precedent and prospects

(2018) Jagadeesh Kalepu et al.   Chemical Science

Rhodium(iii)-catalyzed C–H activation at the C4-position of indole: switchable hydroarylation and oxidative Heck-type reactions of maleimides

(2018) Mahadev Sharanappa Sherikar et al.   CHEMICAL COMMUNICATIONS

Synthesis and evaluation of selenium-containing indole chalcone and diarylketone derivatives as tubulin polymerization inhibition agents

(2017) Shun Zhang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhodium-Catalyzed Site-Selective Coupling of Indoles with Diazo Esters: C4-Alkylation versus C2-Annulation

(2017) Xiaohong Chen et al.   ORGANIC LETTERS

One-pot synthesis of fluorescent 2,4-dialkenylindoles by rhodium-catalyzed dual C–H functionalization

(2017) Hui Chen et al.   Organic Chemistry Frontiers

Ruthenium-Catalyzed C−H Arylation of Benzoic Acids and Indole Carboxylic Acids with Aryl Halides

(2016) Marco Simonetti et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rh(III)-Catalyzed Aryl and Alkenyl C–H Bond Addition to Diverse Nitroalkenes

(2016) Tyler J. Potter et al.   ACS Catalysis

Unexpected regioselective carbon–hydrogen bond activation/cyclization of indolyl aldehydes or ketones with alkynes to benzo-fused oxindoles

(2014) Xingyan Liu et al.   Nature Communications