4.7 Article

Effects of Nb addition on the properties and microstructure of Cu-Ni-Si-Mg alloy

Journal

MATERIALS CHARACTERIZATION
Volume 194, Issue -, Pages -

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.matchar.2022.112451

Keywords

Cu-Ni-Si-Mg-Nb alloy; Aging; Precipitates; Precipitation kinetics

Funding

  1. Regional Development Project of Fujian Province [2021-113]
  2. Key Project of Science and Technology Innovation of Fujian Province [2021H4026]
  3. Joint Research Fund for Industry and University of Fujian Province [2017H6016]
  4. Qimai Science and Technology Innovation Project of Shanghang County [2017SQM044]

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In this study, the effects of Nb addition on the Cu-Ni-Si-Mg alloy were investigated. The results showed that the alloy with 0.2 wt% Nb exhibited the best comprehensive properties after secondary aging, and the addition of Nb promoted the precipitation of Ni2Si phase and influenced the grain boundary structure.
In this paper, the effects of Nb addition on the mechanical properties, electrical conductivity and microstructure of the Cu-Ni-Si-Mg alloy were investigated. The results show that, after the secondary aging at 460 degrees C for 120 min, the alloy with 0.2 wt% Nb exhibits the best comprehensive properties with a hardness of 245.9 HV, a tensile strength of 747.28 MPa, a breaking elongation of 8.6%, and an electrical conductivity of 47.74 %IACS. The addition of Nb element can promote the precipitation of Ni2Si phase. The Nb-doped alloy has a higher quantity of precipitates and a smaller size of precipitates. The Nb element promotes the transition of the Ni2Si phase from a coherent to an incoherent relationship with the matrix in the Cu-Ni-Si-Mg alloy. In the initial stage of precipi-tation, the precipitation activation energy of the alloy with 0.2 wt% Nb is 46.86% lower than that of the alloy without Nb. The addition of Nb increases the proportion of sigma 3n (n = 1, 2, 3) grain boundary in the Cu-Ni-Si-Mg alloy. Furthermore, after the secondary aging, the Nb addition increases the recrystallized texture and recrys-tallized grains and decreases the cold-rolled texture and defects in the alloy.

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