Structure–Reactivity Relationships of Buchwald-Type Phosphines in Nickel-Catalyzed Cross-Couplings

A Comprehensive Discovery Platform for Organophosphorus Ligands for Catalysis

(2022) Tobias Gensch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Identification of a Nitrenoid Reductive Elimination Pathway in Nickel-Catalyzed C–N Cross-Coupling

(2022) Connor M. Simon et al.   ACS Catalysis

16-Electron Nickel(0)-Olefin Complexes in Low-Temperature C(sp2)–C(sp3) Kumada Cross-Couplings

(2021) Sigrid Lutz et al.   ORGANOMETALLICS

Ni(II) Precatalysts Enable Thioetherification of (Hetero)Aryl Halides and Tosylates and Tandem C−S/C−N Couplings

(2021) M. Trinidad Martín et al.   CHEMISTRY-A EUROPEAN JOURNAL

Selective Synthesis of Z-Silyl Enol Ethers via Ni-Catalyzed Remote Functionalization of Ketones

(2021) Sinem Guven et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Univariate classification of phosphine ligation state and reactivity in cross-coupling catalysis

(2021) Samuel H. Newman-Stonebraker et al.   SCIENCE

Ni(COD)(DQ): An Air-Stable 18-Electron Ni(0)-Olefin Precatalyst

(2020) Van Tran et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Quest for the Ideal Base: Rational Design of a Nickel Precatalyst Enables Mild, Homogeneous C–N Cross-Coupling

(2020) Richard Y. Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Investigation of the Nickel-Catalyzed Carbonylation of Alcohols

(2020) Sara Sabater et al.   ORGANOMETALLICS

Nickel-Catalyzed Decarbonylative Amination of Carboxylic Acid Esters

(2020) Christian A. Malapit et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trends in the Usage of Bidentate Phosphines as Ligands in Nickel Catalysis

(2020) Andrew L. Clevenger et al.   CHEMICAL REVIEWS

Pd- and Ni-Based Systems for the Catalytic Borylation of Aryl (Pseudo)halides with B2(OH)4

(2020) Charissa Munteanu et al.   JOURNAL OF ORGANIC CHEMISTRY

A Mechanistic Analysis of Metallaphotoredox C–N Coupling: Photocatalysis Initiates and Perpetuates Ni(I)/Ni(III) Coupling Activity

(2020) Nicholas A. Till et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni-Catalyzed Intermolecular Carboacylation of Internal Alkynes via Amide C–N Bond Activation

(2020) Mason T. Koeritz et al.   ORGANIC LETTERS

Experimental and computational studies towards chemoselective C‐F over C‐Cl functionalisation: reversible oxidative addition is the key

(2020) Emily Jacobs et al.   ChemCatChem

Effect of Aryl Ligand Identity on Catalytic Performance of Trineopentylphosphine Arylpalladium Complexes in N-Arylation Reactions

(2020) Huaiyuan Hu et al.   ORGANOMETALLICS

Ranking Ligands by Their Ability to Ease (C6F5)2NiIIL → Ni0L + (C6F5)2 Coupling versus Hydrolysis: Outstanding Activity of PEWO Ligands

(2020) Jaime Ponce-de-León et al.   INORGANIC CHEMISTRY

C–H Nickelation of Aryl Phosphinites: Mechanistic Aspects

(2019) Loïc P. Mangin et al.   ORGANOMETALLICS

PAd2-DalPhos Enables the Nickel-Catalyzed C-N Cross-Coupling of Primary Heteroarylamines and (Hetero)aryl Chlorides

(2019) Jillian Clark et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Towards the online computer-aided design of catalytic pockets

(2019) Laura Falivene et al.   Nature Chemistry

C–H Nickelation of Naphthyl Phosphinites: Electronic and Steric Limitations, Regioselectivity, and Tandem C–P Functionalization

(2019) Loïc P. Mangin et al.   ORGANOMETALLICS

An air-stable binary Ni(0)–olefin catalyst

(2019) Lukas Nattmann et al.   Nature Catalysis

Taming Nickel-Catalyzed Suzuki-Miyaura Coupling: A Mechanistic Focus on Boron-to-Nickel Transmetalation

(2018) Pierre-Adrien Payard et al.   ACS Catalysis

Bisphosphines: A Prominent Ancillary Ligand Class for Application in Nickel-Catalyzed C–N Cross-Coupling

(2018) Christopher M. Lavoie et al.   ACS Catalysis

Advances in Base-Metal Catalysis: Development of a Screening Platform for Nickel-Catalyzed Borylations of Aryl (Pseudo)halides with B2(OH)4

(2018) John R. Coombs et al.   ORGANOMETALLICS

Synthesis, Structure and Nickel Carbonyl Complexes of Dialkylterphenyl Phosphines

(2018) Mario Marín et al.   CHEMISTRY-A EUROPEAN JOURNAL

Probing the Influence of PAd-DalPhos Ancillary Ligand Structure on Nickel-Catalyzed Ammonia Cross-Coupling

(2018) Christopher M. Lavoie et al.   ORGANOMETALLICS

Structural, Kinetic, and Computational Characterization of the Elusive Arylpalladium(II)boronate Complexes in the Suzuki–Miyaura Reaction

(2017) Andy A. Thomas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidatively Induced C–H Activation at High Valent Nickel

(2017) Eugene Chong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Preparation of Quaternary Centers via Nickel-Catalyzed Suzuki–Miyaura Cross-Coupling of Tertiary Sulfones

(2017) Zachary T. Ariki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidative Addition of Aryl Electrophiles to a Prototypical Nickel(0) Complex: Mechanism and Structure/Reactivity Relationships

(2017) Sonia Bajo et al.   ORGANOMETALLICS

Well-defined nickel and palladium precatalysts for cross-coupling

(2017) Nilay Hazari et al.   Nature Reviews Chemistry

Applications of Palladium-Catalyzed C–N Cross-Coupling Reactions

(2016) Paula Ruiz-Castillo et al.   CHEMICAL REVIEWS

Arene C(sp2)-H Metalation at NiII Modeled with a Reactive PONCPh Ligand

(2016) Linda S. Jongbloed et al.   INORGANIC CHEMISTRY

Stereospecific Cross Couplings To Set Benzylic, All-Carbon Quaternary Stereocenters in High Enantiopurity

(2016) Qi Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Parameterization of phosphine ligands reveals mechanistic pathways and predicts reaction outcomes

(2016) Zachary L. Niemeyer et al.   Nature Chemistry

Pre-transmetalation intermediates in the Suzuki-Miyaura reaction revealed: The missing link

(2016) A. A. Thomas et al.   SCIENCE

Challenging nickel-catalysed amine arylations enabled by tailored ancillary ligand design

(2016) Christopher M. Lavoie et al.   Nature Communications

Selective amination of aryl chlorides catalysed by Ni(PMe3)4

(2015) Shumiao Zhang et al.   DALTON TRANSACTIONS

Analysis of Past and Present Synthetic Methodologies on Medicinal Chemistry: Where Have All the New Reactions Gone?

(2015) Dean G. Brown et al.   JOURNAL OF MEDICINAL CHEMISTRY

Dinuclear Nickel Complexes in Five States of Oxidation Using a Redox-Active Ligand

(2014) You-Yun Zhou et al.   INORGANIC CHEMISTRY

Ortho Derivatization of Phenols through C–H Nickelation: Synthesis, Characterization, and Reactivities of Ortho-Nickelated Phosphinite Complexes

(2014) Boris Vabre et al.   ORGANOMETALLICS

Nickel Hydroxo Complexes as Intermediates in Nickel-Catalyzed Suzuki–Miyaura Cross-Coupling

(2014) Alec H. Christian et al.   ORGANOMETALLICS

A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes

(2014) Eric A. Standley et al.   ORGANOMETALLICS

Arene CH Amination at Nickel in Terphenyl-Diphosphine Complexes with Labile Metal-Arene Interactions

(2013) David E. Herbert et al.   CHEMISTRY-A EUROPEAN JOURNAL

Suzuki-Miyaura Cross-Coupling of Unprotected, Nitrogen-Rich Heterocycles: Substrate Scope and Mechanistic Investigation

(2013) M. Alexander Düfert et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Reactive, Single-Component Nickel Catalyst Precursor for Suzuki-Miyuara Cross-Coupling of Heteroaryl Boronic Acids with Heteroaryl Halides

(2012) Shaozhong Ge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Cross-Coupling: A Historical Contextual Perspective to the 2010 Nobel Prize

(2012) Carin C. C. Johansson Seechurn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickelation of PCP- and POCOP-Type Pincer Ligands: Kinetics and Mechanism

(2012) Boris Vabre et al.   ORGANOMETALLICS

Nickel-Catalyzed Cross-Coupling of Styrenyl Epoxides with Boronic Acids

(2011) Daniel K. Nielsen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Percent buried volume for phosphine and N-heterocyclic carbene ligands: steric properties in organometallic chemistry

(2010) Hervé Clavier et al.   CHEMICAL COMMUNICATIONS

Synthesis and C−C Coupling Reactivity of a Dinuclear NiI−NiIComplex Supported by a Terphenyl Diphosphine

(2010) Alexandra Velian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dialkylbiaryl phosphines in Pd-catalyzed amination: a user's guide

(2010) David S. Surry et al.   Chemical Science

Nickel/AlMe2Cl-catalysed carbocyanation of alkynes using arylacetonitriles

(2009) Akira Yada et al.   CHEMICAL COMMUNICATIONS

SambVca: A Web Application for the Calculation of the Buried Volume of N-Heterocyclic Carbene Ligands

(2009) Albert Poater et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Palladium-Catalyzed Suzuki−Miyaura Cross-Coupling Reactions Employing Dialkylbiaryl Phosphine Ligands

(2008) Ruben Martin et al.   ACCOUNTS OF CHEMICAL RESEARCH

A New Class of Easily Activated Palladium Precatalysts for Facile C−N Cross-Coupling Reactions and the Low Temperature Oxidative Addition of Aryl Chlorides

(2008) Mark R. Biscoe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY