Nickel-Catalyzed Enantioselective Coupling of Aldehydes and Electron-Deficient 1,3-Dienes Following an Inverse Regiochemical Course

Enantioselective Synthesis of Secondary β-Trifluoromethyl Alcohols via Catalytic Asymmetric Reductive Trifluoroalkylation and Diastereoselective Reduction

(2022) Bing-Bing Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Allenes and Dienes as Chiral Allylmetal Pronucleophiles in Catalytic Enantioselective C=X Addition: Historical Perspective and State‐of‐The‐Art Survey

(2021) Ming Xiang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nickel-Catalyzed Enantioselective Synthesis of Pre-Differentiated Homoallylic syn- or anti-1,2-Diols from Aldehydes and Dienol Ethers

(2021) Thomas Q. Davies et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Fluorination of Copper Carbene Complexes: Preparative Advances and a Mechanistic Rationale

(2020) Michael Buchsteiner et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chagosensine: A Riddle Wrapped in a Mystery Inside an Enigma

(2020) Marc Heinrich et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni(4-tBustb)3: A Robust 16-Electron Ni(0) Olefin Complex for Catalysis

(2020) Lukas Nattmann et al.   ORGANOMETALLICS

CuH-Catalyzed Enantioselective Ketone Allylation with 1,3-Dienes: Scope, Mechanism, and Applications

(2019) Chengxi Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed β-Arylation and -Alkenylation of α-Trifluoromethylacrylic Acid

(2019) Risa Yoshimoto et al.   CHEMISTRY LETTERS

Acyl Fluorides in Late Transition-Metal Catalysis

(2019) Yohei Ogiwara et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Formic Acid Mediated Z -Selective Reductive Coupling of Dienes and Aldehydes

(2019) Christopher Cooze et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Engaging Aldehydes in CuH-Catalyzed Reductive Coupling Reactions: Stereoselective Allylation with Unactivated 1,3-Diene Pronucleophiles

(2019) Chengxi Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Relative and Absolute Structure Assignments of Alkenes Using Crystalline Osmate Derivatives for X-ray Analysis

(2019) Alexander S. Burns et al.   ORGANIC LETTERS

Intermolecular Metal-Catalyzed Reductive Coupling of Dienes, Allenes, and Enynes with Carbonyl Compounds and Imines

(2018) Michael Holmes et al.   CHEMICAL REVIEWS

Exploiting non-covalent π interactions for catalyst design

(2017) Andrew J. Neel et al.   NATURE

Enantioselective Formation of All-Carbon Quaternary Centers via C–H Functionalization of Methanol: Iridium-Catalyzed Diene Hydrohydroxymethylation

(2016) Khoa D. Nguyen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Basis for Regioselection and Regiodivergence in Nickel-Catalyzed Reductive Couplings

(2015) Evan P. Jackson et al.   ACCOUNTS OF CHEMICAL RESEARCH

Nickel Catalysis: Synergy between Method Development and Total Synthesis

(2015) Eric A. Standley et al.   ACCOUNTS OF CHEMICAL RESEARCH

Ruthenium Catalyzed Diastereo- and Enantioselective Coupling of Propargyl Ethers with Alcohols: Siloxy-Crotylation via Hydride Shift Enabled Conversion of Alkynes to π-Allyls

(2015) Tao Liang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalysis-Based Total Synthesis of Putative Mandelalide A

(2014) Jens Willwacher et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Advances in Catalytic Enantioselective Fluorination, Mono-, Di-, and Trifluoromethylation, and Trifluoromethylthiolation Reactions

(2014) Xiaoyu Yang et al.   CHEMICAL REVIEWS

Introduction of Fluorine and Fluorine-Containing Functional Groups

(2013) Theresa Liang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regiodivergent reductive coupling of 2-substituted dienes to formaldehyde employing ruthenium or nickel catalyst: hydrohydroxymethylation via transfer hydrogenation

(2013) Alexander Köpfer et al.   Chemical Science

Chiral-Anion-Dependent Inversion of Diastereo- and Enantioselectivity in Carbonyl Crotylation via Ruthenium-Catalyzed Butadiene Hydrohydroxyalkylation

(2012) Emma L. McInturff et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective C-H Crotylation of Primary Alcohols via Hydrohydroxyalkylation of Butadiene

(2012) J. R. Zbieg et al.   SCIENCE

Nickel-Catalyzed Enantio- and Diastereoselective Three-Component Coupling of 1,3-Dienes, Aldehydes, and a Silylborane Leading to α-Chiral Allylsilanes

(2011) Nozomi Saito et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diastereo- and Enantioselective Ruthenium-Catalyzed Hydrohydroxyalkylation of 2-Silyl-butadienes: Carbonylsyn-Crotylation from the Alcohol Oxidation Level

(2011) Jason R. Zbieg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Construction of Stereogenic Carbon Centers Featuring a Trifluoromethyl Group from Prochiral Trifluoromethylated Substrates

(2010) Jing Nie et al.   CHEMICAL REVIEWS

Ni-Catalyzed Borylative Diene−Aldehyde Coupling: The Remarkable Effect of P(SiMe3)3

(2010) Hee Yeon Cho et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism and Transition-State Structures for Nickel-Catalyzed Reductive Alkyne−Aldehyde Coupling Reactions

(2009) P. R. McCarren et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diastereoselective Construction of Functionalized Homoallylic Alcohols by Ni-Catalyzed Diboron-Promoted Coupling of Dienes and Aldehydes

(2008) Hee Yeon Cho et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Chiral Phosphoramidite beyond Monodentate Coordination: Secondary π-Interactions Turn a Dangling Aryl into a Two-, Four-, or Six-Electron Donor in d6and d8Complexes

(2008) Igor S. Mikhel et al.   ORGANOMETALLICS

Nickel(0)-catalyzed diastereoselective three-component coupling of 1,3-dienes, aldehydes, and organometallic reagents: influence of organometallic reagents on diastereoselectivity

(2008) Nozomi Saito et al.   TETRAHEDRON LETTERS