Mechanistic Insights into Nitrogenase FeMo-Cofactor Catalysis through a Steady-State Kinetic Model

The E2 state of FeMoco: hydride formation vs. Fe reduction and a mechanism for H2 evolution

(2021) Albert Th. Thorhallsson et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reduction of Substrates by Nitrogenases

(2020) Lance C. Seefeldt et al.   CHEMICAL REVIEWS

Catalytic N2-to-NH3 (or -N2H4) Conversion by Well-Defined Molecular Coordination Complexes

(2020) Matthew J. Chalkley et al.   CHEMICAL REVIEWS

Mo-, V-, and Fe-Nitrogenases Use a Universal Eight-Electron Reductive-Elimination Mechanism To Achieve N2 Reduction

(2019) Derek F. Harris et al.   BIOCHEMISTRY

Beyond fossil fuel–driven nitrogen transformations

(2018) Jingguang G. Chen et al.   SCIENCE

A Review of Electrocatalytic Reduction of Dinitrogen to Ammonia under Ambient Conditions

(2018) Xiaoyang Cui et al.   Advanced Energy Materials

Kinetic Understanding of N2 Reduction versus H2 Evolution at the E4(4H) Janus State in the Three Nitrogenases

(2018) Derek F. Harris et al.   BIOCHEMISTRY

Critical computational analysis illuminates the reductive-elimination mechanism that activates nitrogenase for N2reduction

(2018) Simone Raugei et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Evidence That the Pi Release Event Is the Rate-Limiting Step in the Nitrogenase Catalytic Cycle

(2016) Zhi-Yong Yang et al.   BIOCHEMISTRY

Reductive Elimination of H2 Activates Nitrogenase to Reduce the N≡N Triple Bond: Characterization of the E4(4H) Janus Intermediate in Wild-Type Enzyme

(2016) Dmitriy Lukoyanov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrochemical Ammonia Synthesis—The Selectivity Challenge

(2016) Aayush R. Singh et al.   ACS Catalysis

Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage

(2014) Brian M. Hoffman et al.   CHEMICAL REVIEWS

Mechanistic aspects of dinitrogen cleavage and hydrogenation to produce ammonia in catalysis and organometallic chemistry: relevance of metal hydride bonds and dihydrogen

(2013) Hong-Peng Jia et al.   CHEMICAL SOCIETY REVIEWS

On reversible H2 loss upon N2 binding to FeMo-cofactor of nitrogenase

(2013) Z.-Y. Yang et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Extending the Carbon Chain: Hydrocarbon Formation Catalyzed by Vanadium/Molybdenum Nitrogenases

(2011) Y. Hu et al.   SCIENCE

An Earth-system perspective of the global nitrogen cycle

(2008) Nicolas Gruber et al.   NATURE