4.6 Article

Energy transfer in a type-I van der Waals heterostructure of WSe2/PtSe2

Journal

2D MATERIALS
Volume 9, Issue 3, Pages -

Publisher

IOP Publishing Ltd
DOI: 10.1088/2053-1583/ac75f2

Keywords

PtSe2; van der Waals heterostructure; energy transfer; transient absorption spectroscopy

Funding

  1. Beijing Natural Science Foundation [4222073]
  2. National Natural Science Foundation of China [61905010, 11974088, 61875236, 61975007]
  3. Fundamental Research Funds for the Central Universities [buctrc202003]
  4. Beijing Natural Science Foundation of China [Z190006]
  5. U.S. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering [DE-SC0020995]

Ask authors/readers for more resources

In this study, energy transfer in a van der Waals heterostructure formed by WSe2 and PtSe2 monolayers was investigated using steady-state photoluminescence and time-resolved transient absorption spectroscopy. The results showed that excitation can be transferred from WSe2 to PtSe2, but not vice versa. These findings reveal the band alignment of WSe2 and PtSe2 monolayers.
Energy transfer of a van der Waals heterostructure formed by monolayers of WSe2 and PtSe2 is studied by steady-state photoluminescence (PL) and time-resolved transient absorption spectroscopy. The heterostructure sample is fabricated by transferring a mechanically exfoliated WSe2 monolayer onto a PtSe2 monolayer film obtained by chemical vapor deposition. The sample is thermally annealed to improve the interface quality. PL of the heterostructure is quenched by four times compared to the individual WSe2 monolayer, indicating excitation transfer from WSe2 to PtSe2. Femtosecond transient absorption measurements with two configurations show that both the electrons and the holes can transfer from WSe2 to PtSe2 on a sub-picosecond time scale, while neither can transfer from PtSe2 to WSe2. These results indicate that WSe2 and PtSe2 monolayers form a type-I band alignment with both the conduction band minimum and the valence band maximum in the PtSe2 layer.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.6
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Physics, Multidisciplinary

Achieving highly-efficient H2S gas sensor by flower-like SnO2-SnO/porous GaN heterojunction

Zeng Liu, Ling Du, Shao-Hui Zhang, Ang Bian, Jun-Peng Fang, Chen-Yang Xing, Shan Li, Jin-Cheng Tang, Yu-Feng Guo, Wei-Hua Tang

Summary: A flower-like SnO2-SnO/porous GaN (FSS/PGaN) heterojunction was fabricated for the first time, involving a spraying process, hydrothermal preparation of FSS, and electrochemical wet etching of GaN. The loaded SnO2-SnO composites with p-n junctions on the PGaN surface exhibited excellent transport capability, achieving a short response time and release time for H2S sensing. The obtained sensor showed high stability and potential for various applications.

CHINESE PHYSICS B (2023)

Article Psychology

The Importance of the Positional Probability of Word Final (but Not Word Initial) Characters for Word Segmentation and Identification in Children and Adults' Natural Chinese Reading

Feifei Liang, Qi Gao, Xin Li, Yongsheng Wang, Xuejun Bai, Simon P. Liversedge

Summary: This study investigates the influence of positional probabilities of characters on word segmentation and identification in Chinese reading. The results from eye-tracking experiments show that the positional probability of the final character has an effect on word segmentation, as evidenced by reading times and refixations.

JOURNAL OF EXPERIMENTAL PSYCHOLOGY-LEARNING MEMORY AND COGNITION (2023)

Article Materials Science, Multidisciplinary

Fabrication of Diverse Microparticles in a Unified Microfluidic Configuration

Shuai Zhang, Bo Wang, Chenmu Xue, Xiaodong Chen

Summary: This paper presents a reusable and adjustable microfluidic device composed of glass capillaries and polydimethylsiloxane, which allows for the generation of compound microdroplets with different morphologies. The device can be used for rapid prototyping and high-throughput generation of droplets or particles.

ADVANCED MATERIALS TECHNOLOGIES (2023)

Article Chemistry, Multidisciplinary

Synergetic Excess PbI2 and Reduced Pb Leakage Management Strategy for 24.28% Efficient, Stable and Eco-Friendly Perovskite Solar Cells

Yuhong Zhang, Lin Xu, Yanjie Wu, Huan Zhang, Fancong Zeng, Jiahe Xing, Bin Liu, Yu Qi, Biao Dong, Xue Bai, Hongwei Song

Summary: By introducing vertical graded PbI2 distribution and capping a cis-Ru(H(2)dcbpy)(dnbpy)(NCS)(2) (Z907) internal encapsulation layer, the photoinstability, hysteresis, and humidity-related degradation issues caused by excess PbI2 in perovskite solar cells (PSCs) can be improved.

ADVANCED FUNCTIONAL MATERIALS (2023)

Article Engineering, Environmental

Recycle waste washcloth to design Fe3O4/FeS2/C heterojunction membrane as high-area capacity freestanding anode for sodium-ion batteries

Qing Lin, Shaocheng Zhang, Li-Juan Yu, Baoxiu Hou, Shuaihua Zhang, Zheng Wang, Jianjun Song, Xiaoxian Zhao

Summary: In this study, a freestanding anode material for rechargeable sodium-ion batteries was designed by encapsulating Fe3O4/FeS2 heterojunction in a carbon membrane. The material exhibited high specific capacity, low cost, and was suitable for large-scale energy storage. It provided a fast electron transfer pathway and alleviated volume expansion during charging/discharging process. The direct contact between the heterojunction and electrolyte shortened the diffusion path of Na+, resulting in improved performance.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Chemistry, Multidisciplinary

Nanoscale Periodic Trapping Sites for Interlayer Excitons Built by Deformable Molecular Crystal on 2D Crystal

Kushal Rijal, Stephanie Amos, Pavel Valencia-Acuna, Fatimah Rudayni, Neno Fuller, Hui Zhao, Hartwin Peelaers, Wai-Lun Chan

Summary: Periodic nanoscale potentials can trap interlayer excitons by utilizing the structure deformability of a 2D molecular crystal as a degree of freedom. The PTCDI lattice on MoS2 creates a spatial variation of molecular orbital energy, providing effective trapping sites for IXs.

ACS NANO (2023)

Article Chemistry, Analytical

Integrated dual-channel electrochemical immunosensor for early diagnosis and monitoring of periodontitis by detecting multiple biomarkers in saliva

Wei Zhang, Juanrui Du, Kun Wang, Yige Li, Cong Chen, Long Yang, Zitong Kan, Biao Dong, Lin Wang, Lin Xu

Summary: Periodontitis, a prevalent chronic inflammation, has inconspicuous symptoms at early stage, leading to permanent damage. Timely diagnosis and monitoring are crucial for clinical treatment. A dual-channel electrochemical immunosensor was developed for simultaneous detection of periodontitis-related biomarkers in saliva. The sensor showed excellent sensitivity, low limits of detection, and high correlation coefficients, with potential for point-of-care diagnosis and monitoring of periodontitis.

ANALYTICA CHIMICA ACTA (2023)

Article Engineering, Environmental

Allosteric synthetic antibody (Allo-SyAb) for improved cancer immunotherapy

Jiajing Chen, Mengchen Xu, Yongxin Zhang, Linlin Xu, Shuyue Zhao, Yingli An, Rujiang Ma, Yang Liu, Feihe Ma, Linqi Shi

Summary: A novel allosteric synthetic antibody (Allo-SyAb) was constructed using mixed-shell polymeric micelle, which can spatiotemporally activate in response to tumor microenvironment for cancer immunotherapy.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Biochemistry & Molecular Biology

CDK5RAP3, a key defender of udder, modulates NLRP3 inflammasome activation by regulating autophagolysosome degradation in S. agalactiae-infected mastitis

Hongchen Yan, Tianci Zhou, Yongsheng Wang, Zhengcheng Liu, Ilyas Ali, Le Sheng, Qiang Jiang, Tao Li, Minghui Xiang, Ping Li, Wei Zhang, Yong Teng, Honglin Li, Yang Liu, Yafei Cai

Summary: Streptococcus agalactiae is a major pathogen causing mastitis in animals, but its specific pathogenic mechanisms and regulatory factors are largely unknown. Our study revealed that the downregulation of CDK5RAP3 in mastitis caused by S. agalactiae triggers inflammasome activation and inhibits autophagolysosome degradation, leading to inflammation and cell death. This study sheds light on the interaction between autophagy and immune responses and provides new insights for the development of clinical drugs to cure S. agalactiae mastitis.

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES (2023)

Article Chemistry, Physical

Unveiling the role of Ni doping in the electrochemical performance improvement of the LiMn2O4 cathodes

Wangqiong Xu, Qiling Li, Fengrui Sui, Shimei Guo, Ruijuan Qi, Cuiqiong Yan, Lijuan Chen, Shubiao Xia, Junming Guo, Zhe Li, Rong Huang, Feixiang Cheng

Summary: Ni doping is a common strategy for enhancing the performance of LiMn2O4. Understanding the atomic-level structural changes of Ni-doped LiMn2O4 during electrochemical cycling is crucial in elucidating the relationship between Ni doping and performance improvement. By investigating the chemical and structural evolutions with atomic resolution, it was found that Ni2+ ions doping into the Mn 16d sites formed a more stable LiNixMn2-xO4 phase, effectively stabilizing the spinel structure. Moreover, Ni doping suppressed the formation of unexpected phases on the surface and subsurface of LiMn2O4, resulting in splendid long cycling stability.

APPLIED SURFACE SCIENCE (2023)

Article Immunology

Fucoxanthin alleviated atherosclerosis by regulating PI3K/AKT and TLR4/NF kappa B mediated pyroptosis in endothelial cells

Shengyu Cui, Haoliang Wu, Qing He, Lina Wang, Xin Yi, Gaoke Feng, Qingqing Wu, Bo Tao, Danxiang Han, Qiang Hu, Hao Xia, Lin Xu

Summary: In this study, it was found that the plaque area of mice treated with fucoxanthin was significantly reduced compared to the group that did not receive fucoxanthin. Bioinformatics analysis suggested that PI3K/AKT signaling might be involved in the protective effect of fucoxanthin, and this hypothesis was verified in vitro endothelial cell experiments. Moreover, it was revealed that fucoxanthin improved the pyroptosis level of endothelial cells and TLR4/NF kappa B signaling were also participated in the protection of fucoxanthin on endothelial pyroptosis.

INTERNATIONAL IMMUNOPHARMACOLOGY (2023)

Article Materials Science, Multidisciplinary

A new strategy to improve the mechanical properties of CoCrNi medium-entropy alloys based self-lubricating composite in a wide temperature range

Rui Yang, Lijun Yang, Tingmei Wang, Qihua Wang

Summary: This study successfully introduces a solid-lubricant h-BN@Ag to CoCrNi medium entropy alloys, which significantly improves the fracture toughness and tribological behavior of the composites. The composite containing h-BN@Ag exhibits obvious plasticity characteristics and a low, stable coefficient of friction in a wide temperature range (RT-600 degrees C). Adding h-BN@Ag is an effective way to enhance the fracture toughness and tribological behaviors of the CoCrNi matrix composites.

MATERIALS LETTERS (2023)

Article Endocrinology & Metabolism

Prediction for recurrence following antithyroid drug therapy for Graves' hyperthyroidism

Huan Weng, Wen Bo Tian, Zi Dong Xiao, Lin Xu

Summary: This study found that in southern China, insomnia, larger goiter size, higher thyrotrophin receptor antibody (TRAb) titer, and higher maintenance dose of methimazole (MMI) were significant risk factors for the recurrence of Graves' disease (GD) after withdrawing from antithyroid drugs (ATD). Further clinical trials are needed to investigate the potential benefit of improving sleep quality on the prognosis of GD.

ARCHIVES OF ENDOCRINOLOGY METABOLISM (2023)

Article Chemistry, Inorganic & Nuclear

Structural, magnetic and phase transition properties in S=1/2 radical solid solutions of [FxCl1-x-BzPy][Ni(mnt)2] (x=0.07-0.87)

Wan-Wan Yao, Bin-Bin Ma, Lei Xu, Dong-Sheng Shao, Yin Qian, Wen-Long Liu, Xiao-Ming Ren

Summary: Solid solutions provide an opportunity to modulate the structural and physical properties of materials and enhance our understanding of physical phenomena. In this study, two salts and their solid solutions were prepared and characterized. Magnetic phase transitions were observed in the salts, with the solid solutions showing regular antiferromagnetism or uniform ferromagnetic chain behavior depending on the fluorine content. It was found that the solid solutions exhibited higher transition temperatures compared to the parent salts and the magnetic coupling behavior in the high temperature phase showed anomalous changes with fluorine content.

INORGANIC CHEMISTRY FRONTIERS (2023)

Article Medicine, Research & Experimental

Association between P2Y12 inhibitor reloading and in-hospital outcomes for patients with non-ST-segment elevation acute coronary syndrome already on chronic P2Y12 receptor inhibitors therapy in China: findings from the CCC-ACS (improving care for cardiovascular disease in China-acute coronary syndrome) project

Yintang Wang, Yu Geng, Ou Zhang, Qin Xu, Yajun Xue, Boda Zhou, Ping Zhang, Aihua Li, Bao Li, Biao Xu, Guangshu Han, Bin Li, Bin Liu, Bin Wang, Bing Fu, Bo Yu, Bosong Yang, Caidong Luo, Changqian Wang, Changyong Liu, Chuanliang Liang, Chuanyu Gao, Chunlin Lai, Chuntong Wang, Chunyan Zhang, Chunyang Wu, Congliang Zhang, Cui Bin, Lan Huang, Daoquan Peng, Dawen Xu, Di Wu, Dongmei Zhu, Dongsheng Chai, Dongyan Li, Fakuan Tang, Jun Xiao, Fang Zhao, Fangfang Huang, Fanju Meng, Fengwei Li, Fudong Gan, Gang Xu, Gengsheng Sang, Genshan Ma, Guixia Zhang, Guizhou Tao, Guo Li, Guoduo Chen, Guoqin Xin, Guoqing Li, Guosheng Fu, Guoxiong Chen, Hailong Lin, Haiping Guo, Haiyun Lin, Hong Jiang, Hong Liu, Hong Luan, Hong Zhang, Honghua Deng, Hongwei Li, Honhju Wang, Hualing Liu, Hui Dong, Hui Liu, Huifang Zhang, Huifeng Wang, Huimin Chu, Jiabin Xi, Jian Yang, Jianfeng Ye, Jianhao Li, Jianhong Tao, Jianwen Liu, JiaoMei Yang, Jiawang Ding, Jiayi Tong, Jie Chen, Jie Jiang, Jie Yang, Jifu Li, Jinchuan Yan, Jing Hu, Jing Xu, Jingfeng Wang, Jinglan Diao, Jingshan Zhao, Jinru Wei, Jinxing Yi, Jinzi Su, Jiong Tang, Jiyan Chen, Jiyan Yin, Juexin Fan, Jun Guan, Junbo Ge, Junming Liu, Junping Deng, Junping Fang, Junxia Li, Kaihong Chen, Kalan Luo, Keng Wu, Lang Ji, Lang Li, Li Jiang, Li Wei, Lijun Meng, Likun Ma, Lilong Tang, Lin Wang, Lin Wei, Ling Li, Ling Tao, Liqiong Yang, Lirong Wu, Man Zhang, Kaiming Chen, Meisheng Lai, Miao Tian, Mingcheng Bai, Minghua Han, Moshui Chen, Naiyi Liang, Nan Jia, Peiying Zhang, Peng Qu, Pengfei Zhang, Ping Chen, Ping Hou, Ping Xie, Pingshuan Dong, Qiang Wu, Qiang Xie, Qiaoqing Zhong, Qichun Wang, Qinfeng Su, Rong Chang, Rong Lin, Ruiping Zhao, Shaobin Jia, Shaoping Nie, Shaowu Ye, Shenghu He, Shengyong Chen, Shixin Ma, Shuangbin Li, Shuanli Xin, Shudong Xia, Shuhua Zhang, Shuqiu Qu, Shuren Ma, Siding Wang, Songbai Li, Suxin Luo, Tao Liu, Tao Zhang, Tian Tuo, Tianchang Li, Tianlun Yang, Tianmin Du, Tongguo Wu, Wei Liu, Wei Mao, Wei Tuo, Wei Wang, Weihong Jiang, Weijian Huang, Weijun Liu, Weiqing Fan, Weiting Xu, Wenhua Lin, Xi Su, Xia Chen, Xianan Zhang, Xianghua Fu, Xiangjun Yang, Xianxian Zhao, Xiaochuan Ma, Xiaofei Sun, Xiaojun Wang, Xiaolan Li, Xiaolei Li, Xiaoli Yang, Xiaoping Chen, Xiaoqin Zhang, Xiaoshu Cheng, Xiaowei Peng, Xiaowen Ma, Xiaoyong Qi, Xiaoyun Feng, Ximing Chen, Xin Tang, Xingsheng Tang, Xingsheng Zhao, Xiufeng Chen, Xudong Li, Xue Li, Xuebo Liu, Xuemei Peng, Yaling Han, Yan Wang, Yanbo Niu, Yang Yu, Yang Zheng, Yanli Wang, Yanlie Zheng, Yansong Guo, Yanzong Yang, Yi Huang, Yin Liu, Ying Guo, Yingchao Luo, Yinglu Hao, Yingxian Sun, Yingzhong Lin, Yitong Ma, Yong Guo, Yong Li, Yongdong Li, Yonglin Zhang, Yuanzhe Jin, Yue Li, Yuehua Huang, Yuemin Sun, Yuheng Yang, Yuhua Zhu, Yuhuan Shi, Yulan Zhao, Yuqing Hou, Zeqi Zheng, Zesheng Xu, Zewei Ouyang, Zeyuan He, Zhan Lv, Zhanquan Li, Zhaofa He, Zheng Ji, Zheng Zhang, Zhenguo Ji, Zhenqi Su, Zhenyu Yang, Zhihong Ou, Zhijian Yang, Zhiming Yang, Zhirong Wang, Zhiyuan Song, Zhongshan Wang, Zuyi Yuan

Summary: In patients with NSTEACS who were already taking P2Y12 receptor inhibitors, reloading of these inhibitors was associated with a decreased risk of in-hospital major adverse cardiac events (MACE) and all-cause death, without an increased risk of major bleeding.

EUROPEAN JOURNAL OF MEDICAL RESEARCH (2023)

No Data Available