Circular Discovery in Small Molecule and Conjugated Polymer Synthetic Methodology

An Exception to the Carothers Equation Caused by the Accelerated Chain Extension in a Pd/Ag Cocatalyzed Cross Dehydrogenative Coupling Polymerization

(2022) Liwen Xing et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Effect of Alkyl Spacers on the Mixed Ionic‐Electronic Conduction Properties of N‐Type Polymers

(2021) Iuliana P. Maria et al.   ADVANCED FUNCTIONAL MATERIALS

Single-layered organic photovoltaics with double cascading charge transport pathways: 18% efficiencies

(2021) Ming Zhang et al.   Nature Communications

Catalytic Synthesis of Conjugated Azopolymers from Aromatic Diazides

(2021) John M. Andjaba et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H Activation: Toward Sustainability and Applications

(2021) Toryn Dalton et al.   ACS Central Science

Versatile Porous Poly(arylene ether)s via Pd-Catalyzed C–O Polycondensation

(2021) Sheng Guo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Room Temperature C–H Arylation of Benzofurans by Aryl Iodides

(2021) Amy L. Mayhugh et al.   ORGANIC LETTERS

Mechanistic Investigation into the Gold-Catalyzed Decarboxylative Cross-Coupling of Iodoarenes

(2021) Ryan A. Daley et al.   ACS Catalysis

Improving the efficiency and sustainability of catalysts for direct arylation polymerization (DArP)

(2021) Liwei Ye et al.   JOURNAL OF POLYMER SCIENCE

Light Directs Monomer Coordination in Catalyst-Free Grignard Photopolymerization

(2021) Eliot F. Woods et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photocontrolled Synthesis of n-Type Conjugated Polymers

(2020) Eliot F. Woods et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ag/Pd Cocatalyzed Direct Arylation of Fluoroarene Derivatives with Aryl Bromides

(2020) Adyasha Panigrahi et al.   ACS Catalysis

The role of chemical design in the performance of organic semiconductors

(2020) Hugo Bronstein et al.   Nature Reviews Chemistry

Room-temperature Pd/Ag direct arylation enabled by a radical pathway

(2020) Amy L Mayhugh et al.   Beilstein Journal of Organic Chemistry

Influence of the Ester Directing Group on the Inhibition of Defect Formation in Polythiophenes with Direct Arylation Polymerization (DArP)

(2020) Robert M. Pankow et al.   MACROMOLECULES

Iridium-Catalyzed Direct C–H Amidation Producing Multicolor Fluorescent Molecules Emitting Blue-to-Red Light and White Light

(2020) Soon-Hyeok Hwang et al.   ORGANIC LETTERS

Gold Catalyzed Decarboxylative Cross-Coupling of Iodoarenes

(2020) Ryan A. Daley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Conjugated and Conducting Organic Polymers: The First 150 Years

(2020) Seth C. Rasmussen   ChemPlusChem

Single Electron Activation of Aryl Carboxylic Acids

(2020) Xiao-Qiang Hu et al.   iScience

C–H Acidity and Arene Nucleophilicity as Orthogonal Control of Chemoselectivity in Dual C–H Bond Activation

(2019) Ji-Ren Liu et al.   ORGANIC LETTERS

Cooperative Au/Ag Dual-Catalyzed Cross-Dehydrogenative Biaryl Coupling: Reaction Development and Mechanistic Insight

(2019) Weipeng Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Exploring the Utility of Buchwald Ligands for C–H Oxidative Direct Arylation Polymerizations

(2019) Graham S. Collier et al.   ACS Macro Letters

Direct (hetero)arylation polymerization: toward defect-free conjugated polymers

(2019) Mario Leclerc et al.   POLYMER JOURNAL

Catalytic Azoarene Synthesis from Aryl Azides Enabled by a Dinuclear Ni Complex

(2018) Ian G. Powers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct arylation polymerization: A guide to optimal conditions for effective conjugated polymers

(2018) Nemal S. Gobalasingham et al.   PROGRESS IN POLYMER SCIENCE

Highly Efficient Catalysts for Direct Arylation Polymerization (DArP)

(2018) Masayuki Wakioka et al.   Asian Journal of Organic Chemistry

CH Activation as a Shortcut to Conjugated Polymer Synthesis

(2018) J. Terence Blaskovits et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Influence of Branched Alkyl Ester-Labeled Side Chains on Specific Chain Arrangement and Charge-Transport Properties of Diketopyrrolopyrrole-Based Conjugated Polymers

(2018) Hyung Jong Kim et al.   ACS Applied Materials & Interfaces

Mechanistic Origin of β-Defect Formation in Thiophene-Based Polymers Prepared by Direct (Hetero)arylation

(2018) J. Terence Blaskovits et al.   MACROMOLECULES

Molecular weight dependence of carrier mobility and recombination rate in neat P3HT films

(2017) Alex G. Dixon et al.   JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS

Recent advances in high performance donor-acceptor polymers for organic photovoltaics

(2017) Sarah Holliday et al.   PROGRESS IN POLYMER SCIENCE

Direct heteroarylation polymerization: guidelines for defect-free conjugated polymers

(2017) Thomas Bura et al.   Chemical Science

Synthesis of Conjugated Polymers Containing Octafluorobiphenylene Unit via Pd-Catalyzed Cross-Dehydrogenative-Coupling Reaction

(2017) Hideaki Aoki et al.   ACS Macro Letters

Direct C–H arylation: a “Greener” approach towards facile synthesis of organic semiconducting molecules and polymers

(2017) Hassan Bohra et al.   Journal of Materials Chemistry A

The merger of transition metal and photocatalysis

(2017) Jack Twilton et al.   Nature Reviews Chemistry

Applications of Palladium-Catalyzed C–N Cross-Coupling Reactions

(2016) Paula Ruiz-Castillo et al.   CHEMICAL REVIEWS

Direct (Hetero)arylation Polymerization: Simplicity for Conjugated Polymer Synthesis

(2016) Jean-Rémi Pouliot et al.   CHEMICAL REVIEWS

Room-Temperature Direct β-Arylation of Thiophenes and Benzo[b]thiophenes and Kinetic Evidence for a Heck-type Pathway

(2016) Chiara Colletto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct (Hetero)arylation Polymerization: Trends and Perspectives

(2016) Thomas Bura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-catalyzed oxidative direct arylation polymerization (Oxi-DArP) of an ester-functionalized thiophene

(2016) Nemal S. Gobalasingham et al.   Polymer Chemistry

C–H Arylation in the Synthesis of π-Conjugated Polymers

(2016) Sabin-Lucian Suraru et al.   ACS Macro Letters

Au-Catalyzed Cross-Coupling of Arenes via Double C–H Activation

(2015) Xacobe C. Cambeiro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tuning Mechanical and Optoelectrical Properties of Poly(3-hexylthiophene) through Systematic Regioregularity Control

(2015) Jin-Seong Kim et al.   MACROMOLECULES

Iridium-Catalyzed Direct CH Amidation with Weakly Coordinating Carbonyl Directing Groups under Mild Conditions

(2014) Jinwoo Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Optimization of direct arylation polymerization (DArP) through the identification and control of defects in polymer structure

(2014) Andrey E. Rudenko et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Cu(II)-Mediated C–H Amidation and Amination of Arenes: Exceptional Compatibility with Heterocycles

(2014) Ming Shang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Scope of controlled synthesis via chain-growth condensation polymerization: from aromatic polyamides to π-conjugated polymers

(2013) Tsutomu Yokozawa et al.   CHEMICAL COMMUNICATIONS

Ir(III)-Catalyzed Mild C–H Amidation of Arenes and Alkenes: An Efficient Usage of Acyl Azides as the Nitrogen Source

(2013) Jaeyune Ryu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Thiophene based hyperbranched polymers with tunable branching using direct arylation methods

(2013) Ken Okamoto et al.   Polymer Chemistry

Radical/Anionic SRN1-Type Polymerization for Preparation of Oligoarenes

(2012) Sandip Murarka et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Origins of regioselectivity of the palladium-catalyzed (aromatic)CH bond metalation–deprotonation

(2012) Serge I. Gorelsky   COORDINATION CHEMISTRY REVIEWS

Cross-Coupling of Aryl Grignard Reagents with Aryl Iodides and Bromides through SRN1 Pathway

(2011) Eiji Shirakawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stille Polycondensation for Synthesis of Functional Materials

(2011) Bridget Carsten et al.   CHEMICAL REVIEWS

Mechanistic Origin of Ligand-Controlled Regioselectivity in Pd-Catalyzed CH Activation/Arylation of Thiophenes

(2011) Shi-Ya Tang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Analysis of the Palladium-Catalyzed (Aromatic)C–H Bond Metalation–Deprotonation Mechanism Spanning the Entire Spectrum of Arenes

(2011) Serge I. Gorelsky et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Intermolecular Directed C−H Amidation of Aromatic Ketones

(2011) Bin Xiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Polycondensation of Dibromofluorene Analogues with Tetrafluorobenzene via Direct Arylation

(2011) Wei Lu et al.   MACROMOLECULES

A New Biarylphosphine Ligand for the Pd-Catalyzed Synthesis of Diaryl Ethers under Mild Conditions

(2011) Luca Salvi et al.   ORGANIC LETTERS

Controlled polymerizations for the synthesis of semiconducting conjugated polymers

(2011) Ken Okamoto et al.   Polymer Chemistry

Electrochemistry of Conducting Polymers—Persistent Models and New Concepts†

(2010) Jürgen Heinze et al.   CHEMICAL REVIEWS

Overview of the Mechanistic Work on the Concerted Metallation–Deprotonation Pathway

(2010) David Lapointe et al.   CHEMISTRY LETTERS

Palladium-Catalyzed Dehydrohalogenative Polycondensation of 2-Bromo-3-hexylthiophene: An Efficient Approach to Head-to-Tail Poly(3-hexylthiophene)

(2010) Qifeng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Room-Temperature Direct Arylation of Polyfluorinated Arenes under Biphasic Conditions

(2010) Olivier René et al.   ORGANIC LETTERS

Organotrifluoroborates and Monocoordinated Palladium Complexes as Catalysts—A Perfect Combination for Suzuki–Miyaura Coupling

(2009) Gary A. Molander et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Suzuki Polycondensation: Polyarylenes à la Carte

(2009) Junji Sakamoto et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Single step reductive polymerization of functional 3,4-propylenedioxythiophenes via direct C–H arylation catalyzed by palladium acetate

(2009) Anshu Kumar et al.   Polymer Chemistry

Palladium-Catalyzed Suzuki−Miyaura Cross-Coupling Reactions Employing Dialkylbiaryl Phosphine Ligands

(2008) Ruben Martin et al.   ACCOUNTS OF CHEMICAL RESEARCH

Room Temperature and Phosphine Free Palladium Catalyzed Direct C-2 Arylation of Indoles

(2008) Nathalie Lebrasseur et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The mechanism of the oxidative polymerization of aniline and the formation of supramolecular polyaniline structures

(2008) Irina Sapurina et al.   POLYMER INTERNATIONAL