4.7 Article

Substantial submarine groundwater discharge in the estuaries of the east coast of India and its impact on marine strontium budget

Journal

GEOCHIMICA ET COSMOCHIMICA ACTA
Volume 324, Issue -, Pages 66-85

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.gca.2022.03.002

Keywords

Strontium; Sr-87/Sr-86; Submarine groundwater discharge (SGD); East Indian estuaries; Ganga-Brahmaputra

Funding

  1. MoES to the GEOTRACES (India) programme [SM-24-13]

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The concentration and isotopic compositions of dissolved Sr in four major estuaries of the east coast of India were measured, and it was found that dissolved Sr displayed conservative behavior while Sr isotopic composition behaved non-conservatively. The study also revealed that submarine groundwater discharge is an important source of Sr in these estuaries and can be used to estimate groundwater contribution to the water budget.
The concentration and isotopic compositions of dissolved Sr (Sr-87/Sr-86) were measured in four major estuaries of the east coast of India, including those of the Ganga (Hooghly), Mahanadi, Godavari, and the Krishna during their peak discharge period, July-September 2013, along with particulate matters in some of them. Dissolved Sr displays strong conservative behaviour in all four estuaries within the analytical uncertainties, emphasizing simple mixing between river water and seawater. Sr isotopic composition, however, behaved non-conservatively in all four estuaries. Dissolved Sr-87/Sr-86 of many samples in these estuaries deviate significantly from the theoretical mixing line defined by seawater and river water, indicating some additional sources of radiogenic Sr in all four estuaries. Such deviation in the Ganga estuary could result from a minor dissolution of suspended material with very radiogenic Sr in the turbid zone of the estuary. However, several lines of evidence support submarine groundwater discharge as an important source of Sr in these estuaries. We used an inverse modelling approach to characterize the significance of submarine groundwater discharge and quantified its fluxes from the four estuaries based on Sr-87/Sr-86 in this study, highlighting its potential to estimate groundwater contribution to the water budget in estuaries. The fluxes of submarine groundwater discharge from the estuaries of the east coast of India is estimated to be similar to 11000 +/- 900 m(3)s(-1), dominated by the Ganga-Brahmaputra system, and delivers similar to 1.1 +/- 0.06 x 10(9) moles of Sr annually with quite radiogenic Sr-87/Sr-86, 0.7228, comparable to their riverine fluxes. These estuaries contribute 0.3 - 0.7% to the global submarine groundwater discharge derived Sr. This study reveals a large supply of radiogenic Sr from submarine groundwater discharge which further increases the requirement of less radiogenic Sr to balance the continental radiogenic Sr in the global marine Sr budget. (c) 2022 Elsevier Ltd. All rights reserved.

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