High‐Entropy Energy Materials in the Age of Big Data: A Critical Guide to Next‐Generation Synthesis and Applications

Solution-based fabrication of high-entropy Ba(Ti,Hf,Zr,Fe,Sn)O3 films on fluorine-doped tin oxide substrates and their piezoelectric responses

(2021) Yi-Wei Chen et al.   CERAMICS INTERNATIONAL

Data-Driven Strategies for Accelerated Materials Design

(2021) Robert Pollice et al.   ACCOUNTS OF CHEMICAL RESEARCH

Top–Down Synthesis of Noble Metal Particles on High-Entropy Oxide Supports for Electrocatalysis

(2021) Zeyu Jin et al.   CHEMISTRY OF MATERIALS

Porous spinel-type (Al0.2CoCrFeMnNi)0.58O4-δ high-entropy oxide as a novel high-performance anode material for lithium-ion batteries

(2021) Hou-Zheng Xiang et al.   Journal of Materials Science

Synthesis of Novel (Be,Mg,Ca,Sr,Zn,Ni)3O4 High Entropy Oxide with Characterization of Structural and Functional Properties and Electrochemical Applications

(2021) Javeria Arshad et al.   Journal of Electrochemical Science and Technology

Spin-coating for fabrication of high-entropy high-k (AlTiVZrHf)O films on Si for advanced gate stacks

(2021) Ze-Wei Huang et al.   CERAMICS INTERNATIONAL

Machine learning approach to predict new multiphase high entropy alloys

(2021) Yegi Vamsi Krishna et al.   SCRIPTA MATERIALIA

High-entropy ceramics: Present status, challenges, and a look forward

(2021) Huimin Xiang et al.   Journal of Advanced Ceramics

High-Entropy 2D Carbide MXenes: TiVNbMoC3 and TiVCrMoC3

(2021) Srinivasa Kartik Nemani et al.   ACS Nano

High‐Entropy Atomic Layers of Transition‐Metal Carbides (MXenes)

(2021) Zhiguo Du et al.   ADVANCED MATERIALS

High‐Entropy Metal–Organic Frameworks for Highly Reversible Sodium Storage

(2021) Yanjiao Ma et al.   ADVANCED MATERIALS

Phase–Property Diagrams for Multicomponent Oxide Systems toward Materials Libraries

(2021) Leonardo Velasco et al.   ADVANCED MATERIALS

Structure prediction in high-entropy alloys with machine learning

(2021) D. Q. Zhao et al.   APPLIED PHYSICS LETTERS

Beyond Ternary OPV: High‐Throughput Experimentation and Self‐Driving Laboratories Optimize Multicomponent Systems

(2020) Stefan Langner et al.   ADVANCED MATERIALS

A high-entropy perovskite titanate lithium-ion battery anode

(2020) Jinhua Yan et al.   JOURNAL OF MATERIALS SCIENCE

High-Entropy Perovskite Fluorides: A New Platform for Oxygen Evolution Catalysis

(2020) Tao Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

High-Entropy Alloys as Catalysts for the CO2 and CO Reduction Reactions

(2020) Jack K. Pedersen et al.   ACS Catalysis

High-entropy ceramics

(2020) Corey Oses et al.   Nature Reviews Materials

Electrochemical Performance of (MgCoNiZn)1–xLixO High-Entropy Oxides in Lithium-Ion Batteries

(2020) Ersu Lökçü et al.   ACS Applied Materials & Interfaces

A reflection on lithium-ion battery cathode chemistry

(2020) Arumugam Manthiram   Nature Communications

The emergent field of high entropy oxides: Design, prospects, challenges, and opportunities for tailoring material properties

(2020) Brianna L. Musicó et al.   APL Materials

Role of intermediate 4f states in tuning the band structure of high entropy oxides

(2020) Abhishek Sarkar et al.   APL Materials

Self-driving laboratory for accelerated discovery of thin-film materials

(2020) B. P. MacLeod et al.   Science Advances

Computationally aided, entropy-driven synthesis of highly efficient and durable multi-elemental alloy catalysts

(2020) Yonggang Yao et al.   Science Advances

Combinatorial Synthesis and High-Throughput Characterization of Microstructure and Phase Transformation in NiTiCuV Quaternary Thin-Film Library

(2020) Naila M. Al Hasan et al.   Engineering

Robot-Accelerated Perovskite Investigation and Discovery

(2020) Zhi Li et al.   CHEMISTRY OF MATERIALS

A mobile robotic chemist

(2020) Benjamin Burger et al.   NATURE

Thermodynamics of High Entropy Oxides

(2020) Scott J. McCormack et al.   ACTA MATERIALIA

Mechanochemical synthesis: route to novel rock-salt-structured high-entropy oxides and oxyfluorides

(2020) Ling Lin et al.   Journal of Materials Science

Cation-disordered rocksalt-type high-entropy cathodes for Li-ion batteries

(2020) Zhengyan Lun et al.   NATURE MATERIALS

Multicomponent high-entropy Cantor alloys

(2020) B. Cantor   PROGRESS IN MATERIALS SCIENCE

High entropy oxides: The role of entropy, enthalpy and synergy

(2020) Abhishek Sarkar et al.   SCRIPTA MATERIALIA

High-Throughput Exploration of Metal Vanadate Thin-Film Systems (M–V–O, M = Cu, Ag, W, Cr, Co, Fe) for Solar Water Splitting: Composition, Structure, Stability, and Photoelectrochemical Properties

(2020) Swati Kumari et al.   ACS Combinatorial Science

Chemical Robotics Enabled Exploration of Stability in Multicomponent Lead Halide Perovskites via Machine Learning

(2020) Kate Higgins et al.   ACS Energy Letters

High-entropy oxide stabilized molybdenum oxide via high temperature for deep oxidative desulfurization

(2020) Chang Deng et al.   Applied Materials Today

Multivariate curve resolution analysis of operando XAS data for the investigation of the lithiation mechanisms in high entropy oxides

(2020) Francesco Tavani et al.   CHEMICAL PHYSICS LETTERS

Spinel-structured high entropy oxide (FeCoNiCrMn)3O4 as anode towards superior lithium storage performance

(2020) Dan Wang et al.   JOURNAL OF ALLOYS AND COMPOUNDS

Deep learning-based phase prediction of high-entropy alloys: Optimization, generation, and explanation

(2020) Soo Young Lee et al.   MATERIALS & DESIGN

A DFT Study of Hydrogen Storage in High-Entropy Alloy TiZrHfScMo

(2019) Jutao Hu et al.   Nanomaterials

High entropy oxides as anode material for Li-ion battery applications: A practical approach

(2019) Qingsong Wang et al.   ELECTROCHEMISTRY COMMUNICATIONS

High-Entropy Oxides: Fundamental Aspects and Electrochemical Properties

(2019) Abhishek Sarkar et al.   ADVANCED MATERIALS

Machine learning assisted design of high entropy alloys with desired property

(2019) Cheng Wen et al.   ACTA MATERIALIA

Machine-learning phase prediction of high-entropy alloys

(2019) Wenjiang Huang et al.   ACTA MATERIALIA

First-principles study, fabrication and characterization of (Zr0.25Nb0.25Ti0.25V0.25)C high-entropy ceramics

(2019) Beilin Ye et al.   ACTA MATERIALIA

Search for Catalysts by Inverse Design: Artificial Intelligence, Mountain Climbers, and Alchemists

(2019) Jessica G. Freeze et al.   CHEMICAL REVIEWS

Charge compensation mechanisms in Li‐substituted high‐entropy oxides and influence on Li superionic conductivity

(2019) Nicolas Osenciat et al.   JOURNAL OF THE AMERICAN CERAMIC SOCIETY

Polyelemental, Multicomponent Perovskite Semiconductor Libraries through Combinatorial Screening

(2019) Michael Saliba   Advanced Energy Materials

Understanding the electronic structure, mechanical properties, and thermodynamic stability of (TiZrHfNbTa)C combined experiments and first-principles simulation

(2019) Qian Zhang et al.   JOURNAL OF APPLIED PHYSICS

On the homogeneity of high entropy oxides: An investigation at the atomic scale

(2019) Mohammed Reda Chellali et al.   SCRIPTA MATERIALIA

Lattice doping regulated interfacial reactions in cathode for enhanced cycling stability

(2019) Lianfeng Zou et al.   Nature Communications

Unavoidable disorder and entropy in multi-component systems

(2019) Cormac Toher et al.   npj Computational Materials

Discovery of new materials using combinatorial synthesis and high-throughput characterization of thin-film materials libraries combined with computational methods

(2019) Alfred Ludwig   npj Computational Materials

Novel and promising electrocatalyst for oxygen evolution reaction based on MnFeCoNi high entropy alloy

(2019) Weiji Dai et al.   JOURNAL OF POWER SOURCES

High-throughput automatic batching equipment for solid state ceramic powders

(2019) Shuang Shuang et al.   REVIEW OF SCIENTIFIC INSTRUMENTS

High-Entropy Layered Oxide Cathodes for Sodium-Ion Batteries

(2019) Chenglong Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A possibility of Pd based high entropy alloy for hydrogen gas sensing applications

(2019) Bharat Sharma et al.   Materials Research Express

Phase prediction in high entropy alloys with a rational selection of materials descriptors and machine learning models

(2019) Yan Zhang et al.   ACTA MATERIALIA

A high throughput molecular screening for organic electronics via machine learning: present status and perspective

(2019) Akinori Saeki et al.   JAPANESE JOURNAL OF APPLIED PHYSICS

Machine learning guided appraisal and exploration of phase design for high entropy alloys

(2019) Ziqing Zhou et al.   npj Computational Materials

Mechanochemical-Assisted Synthesis of High-Entropy Metal Nitride via a Soft Urea Strategy

(2018) Tian Jin et al.   ADVANCED MATERIALS

Combinatorial metallurgical synthesis and processing of high-entropy alloys

(2018) Zhiming Li et al.   JOURNAL OF MATERIALS RESEARCH

Synthesis and sintering of (Mg, Co, Ni, Cu, Zn)O entropy-stabilized oxides obtained by wet chemical methods

(2018) Mattia Biesuz et al.   JOURNAL OF MATERIALS SCIENCE

Rare earth and transition metal based entropy stabilised perovskite type oxides

(2018) Abhishek Sarkar et al.   JOURNAL OF THE EUROPEAN CERAMIC SOCIETY

Combinatorial Nitrogen Gradients in Sputtered Thin Films

(2018) Yanbing Han et al.   ACS Combinatorial Science

Accelerating the discovery of materials for clean energy in the era of smart automation

(2018) Daniel P. Tabor et al.   Nature Reviews Materials

Data-Driven Design of Ecofriendly Thermoelectric High-Entropy Sulfides

(2018) Rui-Zhi Zhang et al.   INORGANIC CHEMISTRY

Breakthrough applications of high-entropy materials

(2018) Jien-Wei Yeh et al.   JOURNAL OF MATERIALS RESEARCH

High entropy oxides for reversible energy storage

(2018) Abhishek Sarkar et al.   Nature Communications

High-entropy high-hardness metal carbides discovered by entropy descriptors

(2018) Pranab Sarker et al.   Nature Communications

Discovery of a Multinary Noble Metal-Free Oxygen Reduction Catalyst

(2018) Tobias Löffler et al.   Advanced Energy Materials

In-situ high throughput synthesis of high-entropy alloys

(2018) Yuqing Xu et al.   SCRIPTA MATERIALIA

A high entropy oxide (Mg0.2Co0.2Ni0.2Cu0.2Zn0.2O) with superior lithium storage performance

(2018) Nan Qiu et al.   JOURNAL OF ALLOYS AND COMPOUNDS

Controlled Jahn-Teller distortion in (MgCoNiCuZn)O-based high entropy oxides

(2017) D. Berardan et al.   JOURNAL OF ALLOYS AND COMPOUNDS

Nanocrystalline multicomponent entropy stabilised transition metal oxides

(2017) Abhishek Sarkar et al.   JOURNAL OF THE EUROPEAN CERAMIC SOCIETY

Site-dependent multicomponent doping strategy for Ni-rich LiNi1−2yCoyMnyO2 (y = 1/12) cathode materials for Li-ion batteries

(2017) Chaoping Liang et al.   Journal of Materials Chemistry A

2D metal carbides and nitrides (MXenes) for energy storage

(2017) Babak Anasori et al.   Nature Reviews Materials

First-principles prediction of high-entropy-alloy stability

(2017) Rui Feng et al.   npj Computational Materials

Direct Observation of Lattice Aluminum Environments in Li Ion Cathodes LiNi1–y–zCoyAlzO2 and Al-Doped LiNixMnyCozO2 via 27Al MAS NMR Spectroscopy

(2016) Fulya Dogan et al.   ACS Applied Materials & Interfaces

Role of zirconium dopant on the structure and high voltage electrochemical performances of LiNi 0.5 Co 0.2 Mn 0.3 O 2 cathode materials for lithium ion batteries

(2016) Ding Wang et al.   ELECTROCHIMICA ACTA

Design of efficient molecular organic light-emitting diodes by a high-throughput virtual screening and experimental approach

(2016) Rafael Gómez-Bombarelli et al.   NATURE MATERIALS

Colossal dielectric constant in high entropy oxides

(2016) David Bérardan et al.   Physica Status Solidi-Rapid Research Letters

High-throughput computational design of cathode coatings for Li-ion batteries

(2016) Muratahan Aykol et al.   Nature Communications

Room temperature lithium superionic conductivity in high entropy oxides

(2016) D. Bérardan et al.   Journal of Materials Chemistry A

High-Entropy Metal Diborides: A New Class of High-Entropy Materials and a New Type of Ultrahigh Temperature Ceramics

(2016) Joshua Gild et al.   Scientific Reports

Effect of Fe in suppressing the discharge voltage decay of high capacity Li-rich cathodes for Li-ion batteries

(2015) Prasant Kumar Nayak et al.   JOURNAL OF SOLID STATE ELECTROCHEMISTRY

Machine learning: Trends, perspectives, and prospects

(2015) M. I. Jordan et al.   SCIENCE

Entropy-stabilized oxides

(2015) Christina M. Rost et al.   Nature Communications

Excellent rate capability of Mg doped Li[Li0.2Ni0.13Co0.13Mn0.54]O2 cathode material for lithium-ion battery

(2014) Xue Jin et al.   ELECTROCHIMICA ACTA

High throughput first-principles calculations of bixbyite oxides for TCO applications

(2014) Nasrin Sarmadian et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Unlocking the Potential of Cation-Disordered Oxides for Rechargeable Lithium Batteries

(2014) J. Lee et al.   SCIENCE

An understanding of high entropy alloys from phase diagram calculations

(2013) F. Zhang et al.   CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY

Alloy Design Strategies and Future Trends in High-Entropy Alloys

(2013) Jien-Wei Yeh   JOM

Two-Dimensional Transition Metal Carbides

(2012) Michael Naguib et al.   ACS Nano

Electrochemical and Physical Properties of Ti-Substituted Layered Nickel Manganese Cobalt Oxide (NMC) Cathode Materials

(2012) Kinson C. Kam et al.   JOURNAL OF THE ELECTROCHEMICAL SOCIETY

Combinatorial thin film materials science: From alloy discovery and optimization to alloy design

(2012) Thomas Gebhardt et al.   THIN SOLID FILMS

Two-Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2

(2011) Michael Naguib et al.   ADVANCED MATERIALS

Effect of Aluminum Substitution on the Structure, Electrochemical Performance and Thermal Stability of Li1+x(Ni0.40Mn0.40Co0.20−zAlz)1−xO2

(2011) L. Croguennec et al.   JOURNAL OF THE ELECTROCHEMICAL SOCIETY

Combinatorial and High-Throughput Screening of Materials Libraries: Review of State of the Art

(2011) Radislav Potyrailo et al.   ACS Combinatorial Science

Finding Nature’s Missing Ternary Oxide Compounds Using Machine Learning and Density Functional Theory

(2010) Geoffroy Hautier et al.   CHEMISTRY OF MATERIALS

Hydrogen storage properties of multi-principal-component CoFeMnTixVyZrz alloys

(2010) Yih-Farn Kao et al.   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

Reproducible, High-Throughput Synthesis of Colloidal Nanocrystals for Optimization in Multidimensional Parameter Space

(2010) Emory M. Chan et al.   NANO LETTERS

Development of multifunctional thin films using high-throughput experimentation methods

(2009) Alfred Ludwig et al.   International Journal of Materials Research

Characteristics of (TiAlCrNbY)C films deposited by reactive magnetron sputtering

(2009) M. Braic et al.   SURFACE & COATINGS TECHNOLOGY

Solid-Solution Phase Formation Rules for Multi-component Alloys

(2008) Y. Zhang et al.   ADVANCED ENGINEERING MATERIALS

Sputter Deposition of Multi-Element Nanoparticles as Electrocatalysts for Methanol Oxidation

(2008) Chih-Fang Tsai et al.   JAPANESE JOURNAL OF APPLIED PHYSICS

High-Throughput Synthesis and Characterization of Bulk Ceramics from Dry Powders

(2008) Tobias A. Stegk et al.   JOURNAL OF COMBINATORIAL CHEMISTRY