Origins of Internal Regioselectivity in Copper-Catalyzed Borylation of Terminal Alkynes

Cyclic (Alkyl)(amino)carbene Ligands Enable Cu‐Catalyzed Markovnikov Protoboration and Protosilylation of Terminal Alkynes: A Versatile Portal to Functionalized Alkenes**

(2021) Yang Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tuning Polarity of Cu-O Bond in Heterogeneous Cu Catalyst to Promote Additive-free Hydroboration of Alkynes

(2020) Jian Zhang et al.   Chem

An Extensive Set of Accurate Fluoride Ion Affinities for p ‐Block Element Lewis Acids and Basic Design Principles for Strong Fluoride Ion Acceptors

(2020) Philipp Erdmann et al.   CHEMPHYSCHEM

Three-Component Borylallenylation of Alkynes: Access to Densely Boryl-Substituted Ene-allenes

(2020) Shang-Hai Yu et al.   ORGANIC LETTERS

Synthesis of Conjugated Boron‐Enynes via cis‐Alkynylboration of Terminal Alkynes

(2019) Kuan Li et al.   ADVANCED SYNTHESIS & CATALYSIS

Synthesis of Stereodefined Borylated Dendralenes through Copper-Catalyzed Allylboration of Alkynes

(2018) Eva Rivera-Chao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Anthranilamide (aam)-substituted diboron: palladium-catalyzed selective B(aam) transfer

(2018) Shintaro Kamio et al.   CHEMICAL COMMUNICATIONS

Copper-boryl mediated organic synthesis

(2018) David Hemming et al.   CHEMICAL SOCIETY REVIEWS

Copper-Catalyzed Borylstannylation of Alkynes with Tin Fluorides

(2017) Hiroto Yoshida et al.   ORGANOMETALLICS

Copper-catalyzed reductive borylations on water

(2017) Chihiro Tanaka et al.   TETRAHEDRON

Copper-Catalyzed Regioselective Formal Allylboration of Aryl-Substituted Terminal Alkynes with Bis(pinacolato)diboron and Allyl Halides/Sulfonates

(2017) Haitong Jing et al.   Asian Journal of Organic Chemistry

Diboron(4) Compounds: From Structural Curiosity to Synthetic Workhorse

(2016) Emily C. Neeve et al.   CHEMICAL REVIEWS

Borylation of Alkynes under Base/Coinage Metal Catalysis: Some Recent Developments

(2016) Hiroto Yoshida   ACS Catalysis

Borylstannylation of alkynes with inverse regioselectivity: copper-catalyzed three-component coupling using a masked diboron

(2015) H. Yoshida et al.   CHEMICAL COMMUNICATIONS

From unsuccessful H2-activation with FLPs containing B(Ohfip)3 to a systematic evaluation of the Lewis acidity of 33 Lewis acids based on fluoride, chloride, hydride and methyl ion affinities

(2015) Hannes Böhrer et al.   DALTON TRANSACTIONS

Copper-catalyzed borylative transformations of non-polar carbon–carbon unsaturated compounds employing borylcopper as an active catalyst species

(2015) Kazuhiko Semba et al.   TETRAHEDRON

Substrate-Controlled Regio- and Stereoselective Synthesis of Boron-Substituted 1,4-Dienes via Copper-Catalyzed Boryl–Allylation of Alkynes with Allyl Phosphates and Bis(pinacolato)diboron

(2015) Huai-Yu Bin et al.   ACS Catalysis

Copper-Catalyzed Cross-Coupling of Boronic Esters with Aryl Iodides and Application to the Carboboration of Alkynes and Allenes

(2014) Yiqing Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of a guanidine NHC complex and its application in borylation reactions

(2014) Chia-Cheng Tai et al.   CHEMICAL COMMUNICATIONS

A masked diboron in Cu-catalysed borylation reaction: highly regioselective formal hydroboration of alkynes for synthesis of branched alkenylborons

(2014) Hiroto Yoshida et al.   CHEMICAL COMMUNICATIONS

Ligand-free hydroboration of alkynes catalyzed by heterogeneous copper powder with high efficiency

(2013) Jie Zhao et al.   CHEMICAL COMMUNICATIONS

Formal Regiocontrolled Hydroboration of Unbiased Internal Alkynes via Borylation/Allylic Alkylation of Terminal Alkynes

(2013) Abraham L. Moure et al.   ORGANIC LETTERS

Copper-Catalyzed Three-Component Carboboration of Alkynes and Alkenes

(2013) Hiroto Yoshida et al.   ORGANIC LETTERS

Copper-Catalyzed Three-Component Borylstannylation of Alkynes

(2012) Yuki Takemoto et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper(I)-Catalyzed Formal Carboboration of Alkynes: Synthesis of Tri- and Tetrasubstituted Vinylboronates

(2012) Ricardo Alfaro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Boracarboxylation of Alkynes with Diborane and Carbon Dioxide by an N-Heterocyclic Carbene Copper Catalyst

(2012) Liang Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Borylation Reactions of Alkynes and Arynes

(2011) Hiroto Yoshida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Selective Methods for Synthesis of Internal (α-) Vinylboronates through Efficient NHC–Cu-Catalyzed Hydroboration of Terminal Alkynes. Utility in Chemical Synthesis and Mechanistic Basis for Selectivity

(2011) Hwanjong Jang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Anthranilamide: A Simple, Removableortho-Directing Modifier for Arylboronic Acids Serving also as a Protecting Group in Cross-Coupling Reactions

(2011) Hideki Ihara et al.   ORGANIC LETTERS

Percent buried volume for phosphine and N-heterocyclic carbene ligands: steric properties in organometallic chemistry

(2010) Hervé Clavier et al.   CHEMICAL COMMUNICATIONS

Differentially Protected Diboron for Regioselective Diboration of Alkynes: Internal-Selective Cross-Coupling of 1-Alkene-1,2-diboronic Acid Derivatives

(2010) Noriyuki Iwadate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, Biological Evaluation of 1,1-Diarylethylenes as a Novel Class of Antimitotic Agents

(2009) Abdallah Hamze et al.   ChemMedChem

Isocombretastatins A versus Combretastatins A: The ForgottenisoCA-4 Isomer as a Highly Promising Cytotoxic and Antitubulin Agent

(2009) Samir Messaoudi et al.   JOURNAL OF MEDICINAL CHEMISTRY

Synthesis of B-Protected β-Styrylboronic Acids via Iridium-Catalyzed Hydroboration of Alkynes with 1,8-Naphthalenediaminatoborane Leading to Iterative Synthesis of Oligo(phenylenevinylene)s

(2009) Noriyuki Iwadate et al.   ORGANIC LETTERS

Copper-catalyzed addition of diboron reagents to α,β-acetylenic esters: efficient synthesis of β-boryl-α,β-ethylenic esters

(2008) Ji-Eon Lee et al.   CHEMICAL COMMUNICATIONS

Differentially Protected Benzenediboronic Acids:  Divalent Cross-Coupling Modules for the Efficient Synthesis of Boron-Substituted Oligoarenes

(2008) Hiroyoshi Noguchi et al.   ORGANIC LETTERS