Stereodivergent Synthesis of Both Z- and E-Alkenes by Photoinduced, Ni-Catalyzed Enantioselective C(sp3)–H Alkenylation

Iridium-catalyzed Z-retentive asymmetric allylic substitution reactions

(2021) Ru Jiang et al.   SCIENCE

Photocatalytic (Het)arylation of C(sp3)–H Bonds with Carbon Nitride

(2021) Saikat Das et al.   ACS Catalysis

Diastereoselective and Stereodivergent Synthesis of 2‐Cinnamylpyrrolines Enabled by Photoredox‐Catalyzed Iminoalkenylation of Alkenes

(2021) Xu Shen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C(sp3)–H methylation enabled by peroxide photosensitization and Ni-mediated radical coupling

(2021) Aristidis Vasilopoulos et al.   SCIENCE

Enantioselective Photochemical Reactions Enabled by Triplet Energy Transfer

(2021) Johannes Großkopf et al.   CHEMICAL REVIEWS

Advances in the E → Z Isomerization of Alkenes Using Small Molecule Photocatalysts

(2021) Tomáš Neveselý et al.   CHEMICAL REVIEWS

Visible Light Induced Cu-Catalyzed Asymmetric C(sp3)–H Alkylation

(2021) Rupeng Qi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoinduced copper-catalysed asymmetric amidation via ligand cooperativity

(2021) Caiyou Chen et al.   NATURE

Catalytic asymmetric C–C cross-couplings enabled by photoexcitation

(2021) Giacomo E. M. Crisenza et al.   Nature Chemistry

Asymmetric benzylic C(sp3)−H acylation via dual nickel and photoredox catalysis

(2021) Leitao Huan et al.   Nature Communications

Stereo- and Enantioselective Benzylic C–H Alkenylation via Photoredox/Nickel Dual Catalysis

(2021) Xiaokai Cheng et al.   ACS Catalysis

Regioselective Hydroalkylation and Arylalkylation of Alkynes by Photoredox/Nickel Dual Catalysis: Application and Mechanism

(2020) Huifeng Yue et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalysed benzylic C–H coupling with alcohols via radical relay enabled by redox buffering

(2020) Huayou Hu et al.   Nature Catalysis

Enantioselective Synthesis of Functionalized Arenes by Nickel‐Catalyzed Siteselective Hydroarylation of 1,3‐Dienes with Aryl Boronates

(2020) Justin S. Marcum et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A review of enantioselective dual transition metal/photoredox catalysis

(2020) Hong-Hao Zhang et al.   Science China-Chemistry

Dual Catalytic Platform for Enabling sp3 α C–H Arylation and Alkylation of Benzamides

(2020) Alexander W. Rand et al.   ACS Catalysis

Cu-catalysed intramolecular radical enantioconvergent tertiary β-C(sp3)–H amination of racemic ketones

(2020) Chang-Jiang Yang et al.   Nature Catalysis

Intramolecular C(sp3)‐H Bond Oxygenation through Transition Metal Acylnitrenoids

(2020) Yuqi Tan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoinduction in Metallaphotoredox Catalysis

(2020) Alexander Lipp et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synergistic Activation of Amides and Hydrocarbons for Direct C(sp 3 )–H Acylation Enabled by Metallaphotoredox Catalysis

(2020) Geun Seok Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective radical C–H amination for the synthesis of β-amino alcohols

(2020) Kohki M. Nakafuku et al.   Nature Chemistry

Transition Metal-Catalyzed Organic Reactions under Visible Light: Recent Developments and Future Perspectives

(2020) Wan-Min Cheng et al.   ACS Catalysis

Triplet Energy Transfer Photocatalysis: Unlocking the Next Level

(2020) Felix Strieth-Kalthoff et al.   Chem

Nickel‐Catalyzed, Regio‐ and Enantioselective Benzylic Alkenylation of Olefins with Alkenyl Bromide

(2020) Jiandong Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Discovery and Elucidation of Counteranion Dependence in Photoredox Catalysis

(2019) Elliot P Farney et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-catalyzed Enantioselective Hydroarylation and Hydroalkenylation of Styrenes

(2019) Yue-Gang Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Arylation of Benzylic C-H bonds via Copper-Catalyzed Radical Relay

(2019) Guosheng Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Dual Role of Benzophenone in Visible-Light/Nickel Photoredox-Catalyzed C−H Arylations: Hydrogen-Atom Transfer and Energy Transfer

(2019) Abhishek Dewanji et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Electroreductive Coupling of Alkenyl and Benzyl Halides via Nickel Catalysis

(2019) Travis J. DeLano et al.   ACS Catalysis

A multicomponent synthesis of stereodefined olefins via nickel catalysis and single electron/triplet energy transfer

(2019) Chen Zhu et al.   Nature Catalysis

Regioselective Alkylative Cross-Coupling of Remote Unactivated C(sp3)–H Bonds

(2019) Scott M. Thullen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photochemical Asymmetric Nickel-Catalyzed Acyl Cross-Coupling

(2019) Eugenio Gandolfo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light-Enabled Stereodivergent Synthesis of E - and Z -Configured 1,4-Dienes by Photoredox/Nickel Dual Catalysis

(2019) Fan Song et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective benzylic C–H arylation via photoredox and nickel dual catalysis

(2019) Xiaokai Cheng et al.   Nature Communications

Copper-catalyzed enantioselective Sonogashira-type oxidative cross-coupling of unactivated C(sp3)−H bonds with alkynes

(2019) Zhen-Hua Zhang et al.   Nature Communications

Visible-Light-Induced Organic Photochemical Reactions via Energy Transfer Pathways

(2018) Wen-Jing Xiao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective C(sp3)‒H bond activation by chiral transition metal catalysts

(2018) Tyler G. Saint-Denis et al.   SCIENCE

Energy transfer catalysis mediated by visible light: principles, applications, directions

(2018) Felix Strieth-Kalthoff et al.   CHEMICAL SOCIETY REVIEWS

sp3 C–H Arylation and Alkylation Enabled by the Synergy of Triplet Excited Ketones and Nickel Catalysts

(2018) Yangyang Shen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct arylation of strong aliphatic C–H bonds

(2018) Ian B. Perry et al.   NATURE

Merging Transition-Metal Catalysis with Photoredox Catalysis: An Environmentally Friendly Strategy for C–H Functionalization

(2018) Wen-Jun Zhou et al.   SYNTHESIS-STUTTGART

The Combination of Benzaldehyde and Nickel-Catalyzed Photoredox C(sp3 )−H Alkylation/Arylation

(2018) Lumin Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Advances in Alkyl Carbon-Carbon Bond Formation by Nickel/Photoredox Cross-Coupling

(2018) Gary Molander et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct C–C Bond Formation from Alkanes Using Ni-Photoredox Catalysis

(2018) Laura K. G. Ackerman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

syn-Selective alkylarylation of terminal alkynes via the combination of photoredox and nickel catalysis

(2018) Lei Guo et al.   Nature Communications

Nickel/N-Heterocyclic Carbene Complex-Catalyzed Enantioselective Redox-Neutral Coupling of Benzyl Alcohols and Alkynes to Allylic Alcohols

(2018) Yuan Cai et al.   ACS Catalysis

Bromide Photo-oxidation Sensitized to Visible Light in Consecutive Ion Pairs

(2017) Guocan Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Enantioenriched Allylic Silanes via Nickel-Catalyzed Reductive Cross-Coupling

(2017) Julie L. Hofstra et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoinduced Nickel-Catalyzed Chemo- and Regioselective Hydroalkylation of Internal Alkynes with Ether and Amide α-Hetero C(sp3)–H Bonds

(2017) Hong-Ping Deng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-Light-Activated Asymmetric β-C–H Functionalization of Acceptor-Substituted Ketones with 1,2-Dicarbonyl Compounds

(2017) Jiajia Ma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective sp3 C–H alkylation via polarity-match-based cross-coupling

(2017) Chip Le et al.   NATURE

Photocatalytic α-Acylation of Ethers

(2017) Zhongdong Sun et al.   ORGANIC LETTERS

Nickel-Catalyzed Enantioselective Cross-Coupling of N-Hydroxyphthalimide Esters with Vinyl Bromides

(2017) Naoyuki Suzuki et al.   ORGANIC LETTERS

Photoredox-Mediated Routes to Radicals: The Value of Catalytic Radical Generation in Synthetic Methods Development

(2017) Jennifer K. Matsui et al.   ACS Catalysis

The merger of transition metal and photocatalysis

(2017) Jack Twilton et al.   Nature Reviews Chemistry

Direct Acylation of C(sp3 )−H Bonds Enabled by Nickel and Photoredox Catalysis

(2016) Candice L. Joe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

One Photocatalyst, n Activation Modes Strategy for Cascade Catalysis: Emulating Coumarin Biosynthesis with (−)-Riboflavin

(2016) Jan B. Metternich et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photochemical Nickel-Catalyzed C–H Arylation: Synthetic Scope and Mechanistic Investigations

(2016) Drew R. Heitz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct C(sp3)–H Cross Coupling Enabled by Catalytic Generation of Chlorine Radicals

(2016) Benjamin J. Shields et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric copper-catalyzed C-N cross-couplings induced by visible light

(2016) Q. M. Kainz et al.   SCIENCE

Native functionality in triple catalytic cross-coupling: sp3 C-H bonds as latent nucleophiles

(2016) M. H. Shaw et al.   SCIENCE

Enantioselective cyanation of benzylic C–H bonds via copper-catalyzed radical relay

(2016) Wen Zhang et al.   SCIENCE

C–H functionalization of amines with aryl halides by nickel-photoredox catalysis

(2016) Derek T. Ahneman et al.   Chemical Science

Photoredox sheds new light on nickel catalysis: from carbon–carbon to carbon–heteroatom bond formation

(2016) Yong-Yuan Gui et al.   Organic Chemistry Frontiers

A Bio-Inspired, Catalytic E → Z Isomerization of Activated Olefins

(2015) Jan B. Metternich et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Z-Selective Olefin Synthesis via Iron-Catalyzed Reductive Coupling of Alkyl Halides with Terminal Arylalkynes

(2015) Chi Wai Cheung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Cross-Coupling of Photoredox-Generated Radicals: Uncovering a General Manifold for Stereoconvergence in Nickel-Catalyzed Cross-Couplings

(2015) Osvaldo Gutierrez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Asymmetric Reductive Cross-Coupling Between Vinyl and Benzyl Electrophiles

(2014) Alan H. Cherney et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facile Synthesis of Z-Alkenes via Uphill Catalysis

(2014) Kamaljeet Singh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric photoredox transition-metal catalysis activated by visible light

(2014) Haohua Huo et al.   NATURE

Enantiospecific, Nickel-Catalyzed Cross-Couplings of Allylic Pivalates and Arylboroxines

(2014) Harathi D. Srinivas et al.   ORGANIC LETTERS

Single-electron transmetalation in organoboron cross-coupling by photoredox/nickel dual catalysis

(2014) J. C. Tellis et al.   SCIENCE

Merging photoredox with nickel catalysis: Coupling of  -carboxyl sp3-carbons with aryl halides

(2014) Z. Zuo et al.   SCIENCE

Combining Gold and Photoredox Catalysis: Visible Light-Mediated Oxy- and Aminoarylation of Alkenes

(2013) Basudev Sahoo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselective and Stereospecific Cross-Coupling of Primary Allylic Amines with Boronic Acids and Boronates through Palladium-Catalyzed CN Bond Cleavage

(2012) Man-Bo Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Cross-Couplings of Secondary Alkyl Electrophiles with Secondary Alkylmetal Nucleophiles: Negishi Reactions of Racemic Benzylic Bromides with Achiral Alkylzinc Reagents

(2012) Jörg T. Binder et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Merging Visible-Light Photocatalysis and Transition-Metal Catalysis in the Copper-Catalyzed Trifluoromethylation of Boronic Acids with CF3I

(2012) Yingda Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoinduced Ullmann C-N Coupling: Demonstrating the Viability of a Radical Pathway

(2012) S. E. Creutz et al.   SCIENCE

Room-Temperature C–H Arylation: Merger of Pd-Catalyzed C–H Functionalization and Visible-Light Photocatalysis

(2011) Dipannita Kalyani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Regioselective and Stereospecific Suzuki–Miyaura Coupling of Allylic Carbonates with Arylboronic Acids

(2011) Chenguang Li et al.   ORGANIC LETTERS

Enantioselective Synthesis of α-Methyl Carboxylic Acids from Readily Available Starting Materials via Chemoenzymatic Dynamic Kinetic Resolution

(2010) Lisa K. Thalén et al.   JOURNAL OF ORGANIC CHEMISTRY

Efficient Chiral N-Heterocyclic Carbene/Copper(I)-Catalyzed Asymmetric Allylic Arylation with Aryl Grignard Reagents

(2009) Khalid B. Selim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed γ-Selective and Stereospecific Allyl−Aryl Coupling between Acyclic Allylic Esters and Arylboronic Acids

(2009) Hirohisa Ohmiya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY