Cu(i) catalysis for selective condensation/bicycloaromatization of two different arylalkynes: direct and general construction of functionalized C–N axial biaryl compounds

Synthesis of Axially Chiral 2,2′-Bisphosphobiarenes via a Nickel-Catalyzed Asymmetric Ullmann Coupling: General Access to Privileged Chiral Ligands without Optical Resolution

(2021) Ziqing Zuo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight

(2021) Qiang Ma et al.   Nature Communications

Direct Arylation of Simple Arenes with Aryl Bromides by Synergistic Silver and Palladium Catalysis

(2021) Adrian Tlahuext-Aca et al.   ACS Catalysis

Pd-Catalyzed Enantioselective Tandem C–C Bond Activation/Cacchi Reaction between Cyclobutanones and o-Ethynylanilines

(2021) Wan-Chun Yang et al.   ORGANIC LETTERS

Recent Advances in Catalytic Asymmetric Construction of Atropisomers

(2021) Jun Kee Cheng et al.   CHEMICAL REVIEWS

Discovery of Novel Benzimidazole and Indazole Analogues as Tubulin Polymerization Inhibitors with Potent Anticancer Activities

(2021) Yichang Ren et al.   JOURNAL OF MEDICINAL CHEMISTRY

Azahelicene-Fused BODIPY Analogs Showing Circularly Polarized Luminescence

(2020) Chihiro Maeda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Ligand-Free Double Cyclization Reactions for the Synthesis of 3-(1′-Indolyl)-phthalides

(2020) Shuo Yuan et al.   ORGANIC LETTERS

Feedback Inhibition in Chemical Catalysis Leads the Dynamic Kinetic to Kinetic Resolution in C3-Indolylation of Spiro-epoxyoxindoles

(2020) Saumen Hajra et al.   ORGANIC LETTERS

Organocatalytic asymmetric N-sulfonyl amide C-N bond activation to access axially chiral biaryl amino acids

(2020) Guanjie Wang et al.   Nature Communications

Regiospecificity in Ligand-Free Pd-Catalyzed C–H Arylation of Indoles: LiHMDS as Base and Transient Directing Group

(2020) Yorck Mohr et al.   ACS Catalysis

Organocatalytic Enantioselective Synthesis of Atropisomeric Aryl‐ p ‐Quinones: Platform Molecules for Diversity‐Oriented Synthesis of Biaryldiols

(2020) Ye‐Hui Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Atropisomers with Multiple Stereogenic Axes

(2020) Xiaoze Bao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition‐Metal‐Free Oxidative Cross‐Coupling of Tetraarylborates to Biaryls Using Organic Oxidants

(2020) Carolin Gerleve et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Ni-Catalyzed Electrochemical Synthesis of Biaryl Atropisomers

(2020) Hui Qiu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Design and Atroposelective Construction of IAN analogues by Organocatalytic Asymmetric Heteroannulation of Alkynes

(2020) Lei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Atroposelective Oxidative C–H/C–H Cross-Coupling Reaction of 1-Aryl Isoquinoline Derivatives with Electron-Rich Heteroarenes

(2020) Qiang Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective Synthesis of 2-Indolyl-3-oxoindolines or 2-(2-Aminophenyl)quinolines through Cu(II)- or Bi(III)-Catalyzed Tunable Dimerizations of 2-Alkynylanilines

(2020) Ruixue Jia et al.   ORGANIC LETTERS

Cobalt-Catalyzed C(sp2)–CN Bond Activation: Cross-Electrophile Coupling for Biaryl Formation and Mechanistic Insight

(2020) Céline Dorval et al.   ACS Catalysis

Enantioselective Synthesis of 3,3’‐Disubstituted 2‐Amino‐2'‐hydroxy‐1,1’‐binaphthyls by Copper‐Catalyzed Aerobic Oxidative Cross‐Coupling

(2020) Xiao-Jing Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Multi-stimuli-responsive fluorescence of axially chiral 4-ene-β-Diketones

(2020) Dehua Wu et al.   DYES AND PIGMENTS

Cu(I)-Catalyzed 6-endo-dig Cyclization of Terminal Alkynes, 2-Bromoaryl Ketones, and Amides toward 1-Naphthylamines: Applications and Photophysical Properties

(2019) Lebin Su et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Kinetic Resolution by Enantioselective Aromatization: Conversion of Racemic Intermediates of the Barton-Zard Reaction into Enantioenriched 3-Arylpyrroles

(2019) Sheng-Cai Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Reusable MOF-Supported Single-Site Zinc(II) Catalyst for Efficient Intramolecular Hydroamination of o -Alkynylanilines

(2019) Beibei Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cu-Complex Catalyzed Asymmetric Aerobic Oxidative Cross Coupling of 2-Naphthols: Enantioselective Synthesis of C1-symmetric BINOLs Bearing 3,3′-Disubstituents

(2019) Jin-Miao Tian et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemo‐ and Regioselective Catalyst‐Controlled Carbocyclization of Alkynyl Ketones: Rapid Synthesis of 1‐Indanones and 1‐Naphthols

(2019) Liangliang Song et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Carbon-Carbon Bond Cleavage for Biaryl Atropisomers Synthesis

(2019) Ruixian Deng et al.   Chem

Rhodium-Catalyzed Atroposelective C–H Arylation: Efficient Synthesis of Axially Chiral Heterobiaryls

(2019) Qiang Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Asymmetric Synthesis of Axially Chiral Biindolyls by Merging C–H Activation and Nucleophilic Cyclization

(2019) Miaomiao Tian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Switchable Smiles Rearrangement for Enantioselective O-Aryl Amination

(2019) Xihao Chang et al.   ORGANIC LETTERS

A Bulky Chiral N-Heterocyclic Carbene Palladium Catalyst Enables Highly Enantioselective Suzuki–Miyaura Cross-Coupling Reactions for the Synthesis of Biaryl Atropisomers

(2019) Di Shen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold-Catalysed Atroposelective Synthesis of 1,1’-Binaphthalene-2,3’-diols

(2019) Manuel Alcarazo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Strategy for Synthesizing Axially Chiral Naphthyl-Indoles: Catalytic Asymmetric Addition Reactions of Racemic Substrates

(2019) Fei Jiang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

BOPHYs versus BODIPYs: A comparison of their performance as effective multi-function organic dyes

(2019) R. Sola-Llano et al.   DYES AND PIGMENTS

Gold-Catalyzed Oxidative Biaryl Cross-Coupling of Organometallics

(2019) Kai Liu et al.   Chem

Palladium-Catalyzed Enantioselective Cacchi Reaction: Asymmetric Synthesis of Axially Chiral 2,3-Disubstituted Indoles

(2019) Yu-Ping He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free Synthesis of Pharmaceutically Important Biaryls by Photosplicing

(2018) Florian Kloss et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Computationally Assisted Mechanistic Investigation and Development of Pd-Catalyzed Asymmetric Suzuki-Miyaura and Negishi Cross-Coupling Reactions for Tetra-ortho-Substituted Biaryl Synthesis

(2018) Nitinchandra Dahyabhai Patel et al.   ACS Catalysis

Upgrading Cross-Coupling Reactions for Biaryl Syntheses

(2018) Yun-Fei Zhang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic enantioselective synthesis of atropisomeric biaryls by a cation-directed O-alkylation

(2017) John D. Jolliffe et al.   Nature Chemistry

Organocatalytic asymmetric arylation of indoles enabled by azo groups

(2017) Liang-Wen Qi et al.   Nature Chemistry

Synthesis of benzil-o-carboxylate derivatives and isocoumarins through neighboring ester-participating bromocyclizations of o-alkynylbenzoates

(2017) Si-Tian Yuan et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Molecular-Iodine-Catalyzed Cyclization of 2-Alkynylanilines via Iodocyclization–Protodeiodination Sequence

(2017) Yuichiro Takeda et al.   ORGANIC LETTERS

A Tandem Oxidative Annulation Strategy for the Synthesis of Tetracyclic 3-Spirooxindole Benzofuranones

(2017) Chunxia Zhang et al.   ORGANIC LETTERS

Design and Enantioselective Construction of Axially Chiral Naphthyl-Indole Skeletons

(2016) Hong-Hao Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of axially chiral biaryl compounds by asymmetric catalytic reactions with transition metals

(2016) Pauline Loxq et al.   COORDINATION CHEMISTRY REVIEWS

Catalytic repertoire of bacterial bisindole formation

(2016) Yi-Ling Du et al.   CURRENT OPINION IN CHEMICAL BIOLOGY

Synthesis of α-Aminonaphthalenes via Copper-Catalyzed Aminobenzannulation of (o-Alkynyl)arylketones with Amines

(2016) Mingliang Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Indolo[3,2- b ]carbazole-based multi-donor–π–acceptor type organic dyes for highly efficient dye-sensitized solar cells

(2016) Xing Qian et al.   JOURNAL OF POWER SOURCES

Copper Catalysis for Selective Heterocoupling of Terminal Alkynes

(2016) Lebin Su et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Symmetry in Cascade Chirality-Transfer Processes: A Catalytic Atroposelective Direct Arylation Approach to BINOL Derivatives

(2016) Jin-Zheng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free Oxidative Annulation of 2-Naphthols with Terminal Alkynes Affording 2-Arylnaphtho[2,1-b]furans

(2016) Long Liu et al.   ORGANIC LETTERS

CuSO4·5H2O-catalyzed aminobenzannulation of ortho-alkynylaromatic ketones with anilines approach towards 1-aminonaphthalenes

(2016) Biao Guo et al.   TETRAHEDRON

Practical Organocatalytic Synthesis of Functionalized Non-C 2 -Symmetrical Atropisomeric Biaryls

(2015) Hongyin Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances and new concepts for the synthesis of axially stereoenriched biaryls

(2015) J. Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Palladium catalyzed asymmetric Suzuki–Miyaura coupling reactions to axially chiral biaryl compounds: Chiral ligands and recent advances

(2015) Dao Zhang et al.   COORDINATION CHEMISTRY REVIEWS

Gold-Catalyzed Ammonium Acetate Assisted Cascade Cyclization of 2-Alkynylarylketones

(2015) Maciej E. Domaradzki et al.   JOURNAL OF ORGANIC CHEMISTRY

Xanthone dimers: a compound family which is both common and privileged

(2015) Tim Wezeman et al.   NATURAL PRODUCT REPORTS

A twist of nature – the significance of atropisomers in biological systems

(2015) Jamie E. Smyth et al.   NATURAL PRODUCT REPORTS

Multimetallic catalysed cross-coupling of aryl bromides with aryl triflates

(2015) Laura K. G. Ackerman et al.   NATURE

Atropselective syntheses of (−) and (+) rugulotrosin A utilizing point-to-axial chirality transfer

(2015) Tian Qin et al.   Nature Chemistry

Enantioselective and diastereoselective azo-coupling/iminium-cyclizations: a unified strategy for the total syntheses of (−)-psychotriasine and (+)-pestalazine B

(2015) Qi Li et al.   Chemical Science

Kumada–Grignard-type biaryl couplings on water

(2015) Anish Bhattacharjya et al.   Nature Communications

Design of a Versatile and Improved Precatalyst Scaffold for Palladium-Catalyzed Cross-Coupling: (η3-1-tBu-indenyl)2(μ-Cl)2Pd2

(2015) Patrick R. Melvin et al.   ACS Catalysis

Expansion of Bisindole Biosynthetic Pathways by Combinatorial Construction

(2015) Yi-Ling Du et al.   ACS Synthetic Biology

1,2-N-Migration in a Gold-Catalysed Synthesis of Functionalised Indenes by the 1,1-Carboalkoxylation of Ynamides

(2014) Holly V. Adcock et al.   CHEMISTRY-A EUROPEAN JOURNAL

New 1-arylindoles based serotonin 5-HT7 antagonists. Synthesis and binding evaluation studies

(2014) Charlène Sagnes et al.   EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY

Synthesis of Chrysene Derivatives via Copper-Catalyzed One-Pot Dimerization of 2-Alkynyl-1-acetylbenzenes

(2014) Biao Guo et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Asymmetric Synthesis of Mixed 3,3′-Bisindoles and Their Evaluation as Wnt Signaling Inhibitors

(2013) Takayoshi Arai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Silver Phosphate Catalyzed Transformation ofortho-Alkynylaryl Ketones into 1H-Isochromene Derivatives through an Intramolecular-Cyclization/Enantioselective-Reduction Sequence

(2013) Masahiro Terada et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient Syntheses of Korupensamines A, B and Michellamine B by Asymmetric Suzuki-Miyaura Coupling Reactions

(2013) Guangqing Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

General Approach for Preparing Epidithiodioxopiperazines from Trioxopiperazine Precursors: Enantioselective Total Syntheses of (+)- and (−)-Gliocladine C, (+)-Leptosin D, (+)-T988C, (+)-Bionectin A, and (+)-Gliocladin A

(2013) John E. DeLorbe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic Aryl–Aryl Bond Formation: An Atroposelective [3,3]-Rearrangement Approach to BINAM Derivatives

(2013) Gong-Qiang Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Bactericidal Guanidinomethyl Biaryl That Alters the Dynamics of Bacterial FtsZ Polymerization

(2012) Malvika Kaul et al.   JOURNAL OF MEDICINAL CHEMISTRY

Structural Reassignment of a Marine Metabolite from a Binaphthalenetetrol to a Tetrabrominated Diphenyl Ether

(2012) Erin E. Podlesny et al.   JOURNAL OF NATURAL PRODUCTS

Synthesis of N-Azolylindoles by Copper-Catalyzed C–H/N–H Coupling–Annulation Sequence of o-Alkynylanilines

(2012) Yoshiro Oda et al.   ORGANIC LETTERS

Neighbouring Formyl Group Assisted Oxidation of o-Alkynylarenecarbaldehydes by an Iodine/Water System

(2011) Karuppusamy Sakthivel et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Assessing Atropisomer Axial Chirality in Drug Discovery and Development

(2011) Steven R. LaPlante et al.   JOURNAL OF MEDICINAL CHEMISTRY

Atroposelective Total Synthesis of Axially Chiral Biaryl Natural Products

(2010) Gerhard Bringmann et al.   CHEMICAL REVIEWS

Catalytic Enantioselective Synthesis of Atropisomeric Indoles with an NC Chiral Axis

(2010) Nobutaka Ototake et al.   CHEMISTRY-A EUROPEAN JOURNAL

1H,1′H-[3,3′]biindolyl from the terrestrial fungus Gliocladium catenulatum

(2010) Brenda V Bertinetti et al.   JOURNAL OF ANTIBIOTICS

Chemical and Structural Diversity in Eumelanins: Unexplored Bio-Optoelectronic Materials

(2009) Marco d'Ischia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total synthesis of chiral biaryl natural products by asymmetric biaryl coupling

(2009) Marisa C. Kozlowski et al.   CHEMICAL SOCIETY REVIEWS

Practical, general, and systematic method for optical resolution of gem-dihalo- and monohalocyclopropanecarboxylic acids utilizing chiral 1,1′-binaphtholmonomethyl ethers: Application to the synthesis of three chiral pesticides

(2007) Hiroaki Yasukochi et al.   ORGANIC & BIOMOLECULAR CHEMISTRY