Application of sulfoxonium ylide in transition-metal-catalyzed C-H bond activation and functionalization reactions

Co(III), Rh(III) & Ir(III)‐Catalyzed Direct C–H Alkylation/ Alkenylation/ Arylation with carbene precursors

(2021) Saiprasad Nunewar et al.   Chemistry-An Asian Journal

Transition metal-catalyzed synthesis of N, O−Heterocycles via C–H functionalization

(2021) Togati Naveen   TETRAHEDRON

Synthesis of C6-Substituted Isoquinolino[1,2-b]quinazolines via Rh(III)-Catalyzed C–H Annulation with Sulfoxonium Ylides

(2020) Jin Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Rh(III)-Catalyzed Tandem Acylmethylation/Nitroso Migration/Cyclization of N-Nitrosoanilines with Sulfoxonium Ylides in One Pot: Approach to 3-Nitrosoindoles

(2020) Yingtao Wu et al.   ORGANIC LETTERS

Rh(III)-Catalyzed Reaction of α-Carbonyl Sulfoxonium Ylides and Alkenes: Synthesis of Indanones via [4 + 1] Cycloaddition

(2020) Yadagiri Kommagalla et al.   ORGANIC LETTERS

Rhodium-catalyzed regioselective C(sp2)–H bond activation reactions of N-(hetero)aryl-7-azaindoles and cross-coupling with α-carbonyl sulfoxonium ylides

(2020) Yan Tian et al.   TETRAHEDRON LETTERS

Rh(III)‐Catalyzed C−H Acylmethylation of 6‐Arylpurines Using Sulfoxonium Ylides as Carbene Precursors

(2020) Zhibing Chen et al.   ChemistrySelect

Sulfoxonium-Ylide-Directed C–H Activation and Tandem (4 + 1) Annulation

(2020) Vinayak Hanchate et al.   ORGANIC LETTERS

Thioether-Directed C4-Selective C–H Acylmethylation of Indoles Using α-Carbonyl Sulfoxonium Ylides

(2020) Chandrababu Naidu Kona et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Synthesis of Pyrrolo[1,2-a]quinoxaline Derivatives from 1-(2-Aminophenyl)pyrroles and Sulfoxonium Ylides

(2020) Guo-Sheng Huang et al.   SYNLETT

Rh(III)‐Catalyzed [4+1] Cyclization of Sulfoxonium Ylides and Anthranils for Accessing N ‐Arylisatins

(2020) Peng Zhou et al.   ChemCatChem

Transition Metal‐Catalyzed Intermolecular Cascade C‐H Activation/Annulation Processes for the Synthesis of Polycycles

(2020) Erik Van der Eycken et al.   CHEMISTRY-A EUROPEAN JOURNAL

Transition Metal Promoted Cascade Heterocycle Synthesis through C−H Functionalization

(2020) Alessio Baccalini et al.   CHEMISTRY-A EUROPEAN JOURNAL

Regioselective Synthesis of α-Phosphinoylnaphthols through Rhodium-Catalyzed Annulation of 1-Alkynylphosphine Oxides with Sulfoxonium Ylides

(2020) Wucheng Xie et al.   SYNLETT

Rhodium(III)‐Catalyzed Cross Coupling of Sulfoxonium Ylides and 1,3‐Diynes to Produce Naphthol‐Indole Derivatives: An Arene ortho C−H Activation/Annulation Cascade

(2020) Ruixing Liu et al.   ChemCatChem

Direct synthesis of benzoxazinones via Cp*Co(III)-catalyzed C–H activation and annulation of sulfoxonium ylides with dioxazolones

(2020) Yongqi Yu et al.   CHINESE CHEMICAL LETTERS

Rhodium-catalyzed [4+1] annulation of sulfoxonium ylides: Sequential ortho-C H functionalization/carbonyl α-amination toward polycyclic quinazolinones

(2020) Chang Wang et al.   TETRAHEDRON LETTERS

Selective Synthesis of Fused Tricyclic [1,3]oxazino[3,4‐ a ]indolone and Dihydropyrimido [1,6‐a]indolone via Rh(III)‐catalyzed [3+3] or [4+2] C−H Annulation

(2020) Junyu Chen et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium-catalyzed C H activation/cyclization of enaminones with sulfoxonium ylides toward polysubstituted naphthalenes

(2019) Zhenlian Wang et al.   TETRAHEDRON LETTERS

Rhodium(III)-catalyzed intermolecular cyclization of anilines with sulfoxonium ylides toward indoles

(2019) Zhihao Shen et al.   CHINESE CHEMICAL LETTERS

Rh(III)‐Catalyzed Aldehydic C–H Functionalization Reaction between Salicylaldehydes and Sulfoxonium Ylides

(2019) Guo-Dong Xu et al.   ADVANCED SYNTHESIS & CATALYSIS

Cp*IrIII -Catalyzed [3+2] Annulations of N -Aryl-2-aminopyrimidines with Sulfoxonium Ylides to Access 2-Alkyl Indoles Through C-H Bond Activation

(2019) Yi Luo et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Rhodium(III)-Catalyzed [4+2] Annulation via C-H Activation: Synthesis of Multi-Substituted Naphthalenone Sulfoxonium Ylides

(2019) Xiaohan Song et al.   MOLECULES

Rh(III)-Catalyzed Cascade Reactions of Sulfoxonium Ylides with α-Diazocarbonyl Compounds: An Access to Highly Functionalized Naphthalenones

(2019) Xi Chen et al.   ORGANIC LETTERS

Synthesis of 2-substituted indoles by iridium (III)-catalyzed C H functionalization of N-phenylpyridin-2-amines

(2019) Lei Zhang et al.   TETRAHEDRON LETTERS

Ruthenium(II)-Catalyzed C–H Acylmethylation between (Hetero)arenes and α-Cl Ketones/Sulfoxonium Ylides

(2019) Huihui Li et al.   JOURNAL OF ORGANIC CHEMISTRY

RuII-Catalyzed/NH2-Assisted Selective Alkenyl C–H [5 + 1] Annulation of Alkenylanilines with Sulfoxonium Ylides to Quinolines

(2019) Pu Chen et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Regioselective C3–H Acylmethylation of [2,2′-Bipyridine]-6-carboxamides with Sulfoxonium Ylides

(2019) Jia Yu et al.   ORGANIC LETTERS

Redox-Neutral Rhodium(III)-Catalyzed Annulation of Arylhydrazines with Sulfoxonium Ylides To Synthesize 2-Arylindoles

(2019) Ningning Lv et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed Reaction of Sulfoxonium Ylides and Anthranils toward Indoloindolones via a (4 + 1) Annulation

(2019) Xiaopeng Wu et al.   ORGANIC LETTERS

Rhodium(III)-catalyzed one-pot synthesis of flavonoids from salicylaldehydes and sulfoxonium ylides

(2019) Kang Cheng et al.   JOURNAL OF CHEMICAL RESEARCH

Ruthenium(II)‐Catalyzed Homocoupling of Weakly Coordinating Sulfoxonium Ylides via C−H Activation/Annulations: Synthesis of Functionalized Isocoumarins

(2019) Ming‐Dong Zhou et al.   ADVANCED SYNTHESIS & CATALYSIS

Sulfoxonium Ylides as Carbene Precursors: Rhodium(III)‐Catalyzed Sequential C−H Functionalization, Selective Enol Oxygen‐Atom Nucleophilic Addition, and Hydrolysis

(2019) Yuanqiong Huang et al.   ADVANCED SYNTHESIS & CATALYSIS

Chemospecific Cyclizations of α-Carbonyl Sulfoxonium Ylides on Aryls and Heteroaryls

(2019) Daniel Clare et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium Catalyzed C−H Acylmethylation of N ‐Arylphthalazine‐1,4‐diones with α‐Carbonyl Sulfoxonium Ylides: Highway to Diversely Functionalized Phthalazino‐fused Cinnolines

(2019) Pidiyara Karishma et al.   Chemistry-An Asian Journal

Rhodium(III)-Catalyzed Chemo-divergent Couplings of Sulfoxonium Ylides with Oxa/azabicyclic Olefins

(2019) Peiyuan Wang et al.   ORGANIC LETTERS

Synthesis of Naphthols by Rh(III)-Catalyzed Domino C–H Activation, Annulation, and Lactonization Using Sulfoxonium Ylide as a Traceless Directing Group

(2019) Vinayak Hanchate et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Annulative Coupling of Sulfoxonium Ylides and Allenoates: An Arene C–H Activation/Cyclopropanation Cascade

(2019) Jiang Lou et al.   ORGANIC LETTERS

Ruthenium(II)-Catalyzed Construction of Isocoumarins via Dual C–H/C–C Activation of Sulfoxonium Ylides

(2019) Si Wen et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium(iii)-catalyzed chemodivergent annulations between N-methoxybenzamides and sulfoxonium ylides via C–H activation

(2018) Youwei Xu et al.   CHEMICAL COMMUNICATIONS

Synthesis of (2H)-Indazoles through Rh(III)-Catalyzed Annulation Reaction of Azobenzenes with Sulfoxonium Ylides

(2018) Hyunjung Oh et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed Relay Carbenoid Functionalization of Aromatic C–H Bonds toward Fused Heteroarenes

(2018) Xiaopeng Wu et al.   ORGANIC LETTERS

Construction of (Dihydro)naphtho[1,8-bc]pyrans via Rh(III)-Catalyzed Twofold C–H Activation of Benzoylacetonitriles

(2018) Panjie Hu et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Imidoyl C–H Activation for Annulations to Azolopyrimidines

(2018) Kim Søholm Halskov et al.   ORGANIC LETTERS

Rhodium-Catalyzed Annulation of 2-Arylimidazoles and α-Aroyl Sulfoxonium Ylides toward 5-Arylimidazo[2,1-a]isoquinolines

(2018) Jiang Cheng et al.   SYNTHESIS-STUTTGART

Rhodium(III)-catalyzed C–H functionalization of C-alkenyl azoles with sulfoxonium ylides for the synthesis of bridgehead N -fused [5,6]-bicyclic heterocycles

(2018) Gia L. Hoang et al.   TETRAHEDRON

Rh(III)-catalyzed [4 + 1]-annulation of azobenzenes with α - carbonyl sulfoxonium ylides toward 3-acyl-(2 H )-indazoles

(2018) Jiawei Zhu et al.   TETRAHEDRON LETTERS

Rhodium(iii)-catalyzed annulative coupling between arenes and sulfoxonium ylides via C–H activation

(2018) Guangfan Zheng et al.   Organic Chemistry Frontiers

Selective Synthesis of Benzo[a ]Carbazoles and Indolo[2,1-a ]-Isoquinolines via Rh(III)-Catalyzed C−H Functionalizations of 2-Arylindoles with Sulfoxonium Ylides

(2018) Guang Chen et al.   ADVANCED SYNTHESIS & CATALYSIS

Ruthenium (II)-Catalyzed Oxidant-Free Coupling/Cyclization of Benzimidates and Sulfoxonium Ylides to Form Substituted Isoquinolines

(2018) Xinxia Shi et al.   ADVANCED SYNTHESIS & CATALYSIS

Rh(III)-Catalyzed Selective C8−H Acylmethylation of Quinoline N -Oxides

(2018) Chang You et al.   ADVANCED SYNTHESIS & CATALYSIS

Ru (II)-Catalyzed Coupling-Cyclization of Sulfoximines with alpha -Carbonyl Sulfoxonium Ylides as an Approach to 1,2-Benzothiazines

(2018) Haisheng Xie et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium(III)-Catalyzed C-H Activation of Benzoylacetonitriles and Cyclization with Sulfoxonium Ylides to Naphthols

(2018) Chaofan Zhou et al.   ADVANCED SYNTHESIS & CATALYSIS

A Catalytic Cross-Olefination of Diazocompounds with Sulfoxonium Ylides

(2018) James Neuhaus et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

(2018) Carlo Sambiagio et al.   CHEMICAL SOCIETY REVIEWS

Ruthenium(IV) Intermediates in C−H Activation/Annulation by Weak O-Coordination

(2018) Yu-Feng Liang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cp*Co(III)-Catalyzed C–H Acylmethylation of Arenes by Employing Sulfoxonium Ylides as Carbene Precursors

(2018) Shuying Ji et al.   ORGANIC LETTERS

Recent Applications of α-Carbonyl Sulfoxonium Ylides in Rhodium- and Iridium-Catalyzed C–H Functionalizations

(2018) Jiang Cheng et al.   SYNLETT

Diazo Compounds: Versatile Synthons for the Synthesis of Nitrogen Heterocycles via Transition Metal-Catalyzed Cascade C-H Activation/Carbene Insertion/Annulation Reactions

(2018) Yunyu Xiang et al.   ADVANCED SYNTHESIS & CATALYSIS

3d Transition Metals for C–H Activation

(2018) Parthasarathy Gandeepan et al.   CHEMICAL REVIEWS

Iridium(III)-Catalyzed Tandem Annulation Synthesis of Pyrazolo[1,2-α]cinnolines from Pyrazolones and Sulfoxonium Ylides

(2018) Chen-Fei Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Three-Component Coupling of Aldehydes, Aminopyrazoles, and Sulfoxonium Ylides via Rhodium(III)-Catalyzed Imidoyl C–H Activation: Synthesis of Pyrazolo[1,5-a]pyrimidines

(2018) Gia L. Hoang et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Synthesis of Bis-Substituted Sulfoxonium Ylides

(2018) Christopher Janot et al.   ORGANIC LETTERS

Sulfoxonium Ylide Derived Metal Carbenoids in Organic Synthesis

(2018) Janakiram Vaitla et al.   SYNTHESIS-STUTTGART

Rhodium(III)-Catalyzed Synthesis of Naphthols via C–H Activation of Sulfoxonium Ylides

(2017) Youwei Xu et al.   ORGANIC LETTERS

Divergent Access to 1-Naphthols and Isocoumarins via Rh(III)-Catalyzed C–H Activation Assisted by Phosphonium Ylide

(2017) Yunyun Li et al.   ORGANIC LETTERS

Sulfoxonium Ylides as a Carbene Precursor in Rh(III)-Catalyzed C–H Acylmethylation of Arenes

(2017) Youwei Xu et al.   ORGANIC LETTERS

Enaminones as Synthons for a Directed C−H Functionalization: RhIII -Catalyzed Synthesis of Naphthalenes

(2016) Shuguang Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand-Controlled Synthesis of Azoles via Ir-Catalyzed Reactions of Sulfoxonium Ylides with 2-Amino Heterocycles

(2016) Alicia M. Phelps et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalyst-Free Insertion of Sulfoxonium Ylides into Aryl Thiols. A Direct Preparation of β-Keto Thioethers

(2016) Rafael M. P. Dias et al.   ORGANIC LETTERS

Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups

(2015) Zhengkai Chen et al.   Organic Chemistry Frontiers

Ruthenium-Catalyzed Cascade CH Functionalization of Phenylacetophenones

(2014) Vaibhav P. Mehta et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Sulfoxonium and Sulfonium Ylides as Diazocarbonyl Equivalents in Metal-Catalyzed Insertion Reactions

(2013) Antonio C. B. Burtoloso et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Catalyst-Controlled Divergent C–H Functionalization of Unsymmetrical 2-Aryl Cyclic 1,3-Dicarbonyl Compounds with Alkynes and Alkenes

(2013) Johnathon D. Dooley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

CRTH2 Antagonist MK-7246: A Synthetic Evolution from Discovery through Development

(2012) Carmela Molinaro et al.   JOURNAL OF ORGANIC CHEMISTRY

Rh-Catalyzed Intermolecular Carbenoid Functionalization of Aromatic C–H Bonds by α-Diazomalonates

(2012) Wai-Wing Chan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Cascade Oxidative Annulation Leading to Substituted Naphtho[1,8-bc]pyrans by Sequential Cleavage of C(sp2)–H/C(sp3)–H and C(sp2)–H/O–H Bonds

(2012) Xing Tan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed X−H Insertions of Sulfoxonium Ylides

(2009) Ian K. Mangion et al.   ORGANIC LETTERS