4.8 Article

Identification of opportunities for integrating chemical processes for carbon (dioxide) utilization to nuclear power plants

Journal

RENEWABLE & SUSTAINABLE ENERGY REVIEWS
Volume 150, Issue -, Pages -

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.rser.2021.111450

Keywords

CO2; Integrated energy systems; Energy-to-molecules; Catalysis; Electrocatalysis; Radiolysis; Heat integration; Electricity integration; Radiation integration; CO2 utilization

Funding

  1. Laboratory Directed Research & Development Program of Battelle Energy Alliance, LLC under US DOE Idaho Operations Office [DE-AC07-05ID14517]

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The energy and industrial sectors are major contributors to carbon emissions, necessitating urgent decarbonization strategies. The zero waste strategy within Circular Economy aims to transform industrial emissions and waste into valuable products, requiring significant support from low carbon energy sources.
The energy and industrial sectors are responsible for more than 75% of global carbon dioxide emissions, which are primary contributors to climate change. Decarbonization strategies to reduce overall carbon dioxide emissions are urgently needed. Among the numerous decarbonization strategies that are being defined and implemented, a particular strategy of interest for the present work is the Re-X or zero waste strategy, which involves recycling, reuse, repurposing, and remanufacturing of industrial emissions, by-products, and waste in general. A circular value chain or Circular Economy is embedded within this strategy. In a circular carbon economy, efficient reuse of emitted carbon dioxide is considered. However, the stability of carbon dioxide implies the requirement of significant amounts of energy for its transformation into value-added chemicals or products, which must be supplied by low carbon emitting energy sources. Nuclear power plants are low carbon energy sources that, additionally to electricity, could also supply heat and radiation for chemical transformations. This work identifies the opportunities and challenges for the development of integrated energy systems to upgrade and transform carbon dioxide, involving chemical and nuclear energy. The analysis encompasses possible use of the different forms of energy that can be obtain from nuclear reactors (i.e., radiation, electricity, and heat), by reviewing the published literature on potential routes for its conversion. Our review indicates that an universal technology of the one-fits-all solution-type is an utopic dream. Instead, a suite of (contaminants tolerant) technologies for processing various concentrations CO2 and producing a variety of products is currently needed.

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