Catalytic Enantioselective Synthesis of 2,3-Dihydrobenzo[b]oxepines via Asymmetric Oxetane Opening by Internal Carbon Nucleophiles

Pd‐Catalyzed Cascade to Benzoxepins by Using Vinyl‐Substituted Donor‐Acceptor Cyclopropanes

(2021) Matteo Faltracco et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fischdiabietane A, an Antitumoral Diterpenoid Dimer Featuring an Unprecedented Carbon Skeleton from Euphorbia fischeriana

(2021) Jun He et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly Enantioselective, Hydrogen-Bond-Donor Catalyzed Additions to Oxetanes

(2020) Daniel A. Strassfeld et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric (4 + 3) and (4 + 1) Annulations of Isatin-derived Morita–Baylis–Hillman Carbonates to Construct Diverse Chiral Heterocyclic Frameworks

(2020) Ru-Jie Yan et al.   ORGANIC LETTERS

Copper‐Catalyzed Azide‐Ynamide Cyclization for Generation of α‐Imino Copper Carbenes: Divergent and Enantioselective Access to Polycyclic N‐Heterocycles

(2020) Longwu Ye et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild C–C Bond Formation via Lewis Acid Catalyzed Oxetane Ring Opening with Soft Carbon Nucleophiles

(2020) Hai Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Advances in Enantioselective Desymmetrizations of Prochiral Oxetanes

(2020) Alexander Sandvoß et al.   CHEMISTRY-A EUROPEAN JOURNAL

Lewis Base-Catalyzed [4 + 3] Annulation of ortho-Quinone Methides and MBH Carbonates: Synthesis of Functionalized Benzo[b]oxepines Bearing Oxindole Scaffolds

(2019) Ji-Yuan Du et al.   ORGANIC LETTERS

Catalytic Asymmetric (4+3) Cyclizations of In Situ Generated ortho -Quinone Methides with 2-Indolylmethanols

(2019) Meng Sun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of (−)-14-Hydroxygelsenicine and Six Biogenetically Related Gelsemium Alkaloids

(2019) Atsushi Saito et al.   ORGANIC LETTERS

Highly Regio-, Diastereo-, and Enantioselective Synthesis of Tetrahydroazepines and Benzo[b ]oxepines through Palladium-Catalyzed [4+3] Cycloaddition Reactions

(2019) Barry M. Trost et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Target Identification of Benzoxepane Derivatives as Potential Anti-neuroinflammatory Agents for Ischemic Stroke

(2019) Xu-Wen Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Desymmetrization of Oxetanes for the Synthesis of Chiral Tetrahydrothiophenes and Tetrahydroselenophenes

(2019) Renwei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Synthesis of 1,4-Benzodioxepines

(2019) Xi Zou et al.   ORGANIC LETTERS

Pd-Catalyzed Enantioselective [6+4] Cycloaddition of Vinyl Oxetanes with Azadienes to Access Ten-Membered Heterocycles

(2018) Ya-Nong Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper Catalyzed Cascade Synthesis of 2-Aryl-3-cyanobenzofuran and Dibenzo[b,f]oxepine-10-carbonitrile Derivatives

(2018) Bharath KUMAR VILLURI et al.   JOURNAL OF ORGANIC CHEMISTRY

Straightforward Entry toward Highly Substituted 2,3-Dihydrobenz[b]oxepines by Ring Expansion of Benzopyryliums with Donor–Acceptor Diazo Compounds

(2018) Thibaut Courant et al.   ORGANIC LETTERS

Divergent Entry to Gelsedine-Type Alkaloids: Total Syntheses of (−)-Gelsedilam, (−)-Gelsenicine, (−)-Gelsedine, and (−)-Gelsemoxonine

(2018) Pingluan Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Oxidative [5 + 2] Annulation Using Two Transient Assisting Groups: Stereospecific Assembly of 3-Alkenylated Benzoxepine Framework

(2018) Wei Yi et al.   ORGANIC LETTERS

Lead Optimization of Benzoxepin-Type Selective Estrogen Receptor (ER) Modulators and Downregulators with Subtype-Specific ERα and ERβ Activity

(2017) Niamh M. O’Boyle et al.   JOURNAL OF MEDICINAL CHEMISTRY

Enantioselective Oxetane Ring Opening with Chloride: Unusual Use of Wet Molecular Sieves for the Controlled Release of HCl

(2016) Wen Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxetanes: Recent Advances in Synthesis, Reactivity, and Medicinal Chemistry

(2016) James A. Bull et al.   CHEMICAL REVIEWS

(±)-Japonicols A–D, Acylphloroglucinol-Based Meroterpenoid Enantiomers with Anti-KSHV Activities from Hypericum japonicum

(2016) Linzhen Hu et al.   JOURNAL OF NATURAL PRODUCTS

Diastereoselective Ring-Closing Metathesis as a Means to Construct Medium-Sized Cyclic Ethers: Application to the Synthesis of a Photoactivatable Gambierol Derivative

(2016) Yu Onodera et al.   JOURNAL OF ORGANIC CHEMISTRY

The Synthesis of 5-Amino-dihydrobenzo[b]oxepines and 5-Amino-dihydrobenzo[b]azepines via Ichikawa Rearrangement and Ring-Closing Metathesis

(2016) Monika Chwastek et al.   JOURNAL OF ORGANIC CHEMISTRY

Organocatalytic Enantioselective Synthesis of 1,4-Dioxanes and Other Oxa-Heterocycles by Oxetane Desymmetrization

(2015) Wen Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver Triflate Catalyzed Cyclopropyl Carbinol Rearrangement for Benzo[b]oxepine and 2H-Chromene Synthesis

(2015) Philip Wai Hong Chan et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Recent Applications of Oxetanes in the Synthesis of Heterocyclic Compounds

(2015) Christian A. Malapit et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis and Structural Revision of a Brominated Sesquiterpenoid, Aldingenin C

(2014) Shunya Takahashi et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic asymmetric nucleophilic openings of 3-substituted oxetanes

(2014) Zhaobin Wang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Asymmetric Chlorination/Ring Expansion for the Synthesis of α-Quaternary Cycloalkanones

(2014) Qin Yin et al.   ORGANIC LETTERS

Complex Bioactive Alkaloid-Type Polycycles through Efficient Catalytic Asymmetric Multicomponent Aza-Diels-Alder Reaction of Indoles with Oxetane as Directing Group

(2013) Zhilong Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Intermolecular Desymmetrization of 3-Substituted Oxetanes

(2013) Zhaobin Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Synthesis of Tetrahydroisoquinolines and Their Analogues Bearing a C4 Stereocenter: Formal Synthesis of (+)-(8S,13R)-Cyclocelabenzine

(2013) Zhilong Chen et al.   CHEMISTRY-A EUROPEAN JOURNAL

FeCl3-catalyzed synthesis of functionally diverse dibenzo[b,f]oxepines and benzo[b]oxepines via alkyne–aldehyde metathesis

(2013) Krishnendu Bera et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Recent Advances in the Metal-Catalyzed Ring Expansions of Three- and Four-Membered Rings

(2013) Daniel J. Mack et al.   ACS Catalysis

Catalytic Ring Expansion of Vinyl Oxetanes: Asymmetric Synthesis of Dihydropyrans Using Chiral Counterion Catalysis

(2012) Boying Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Eight-Membered Lactones: Intermolecular [6+2] Cyclization of Amphoteric Molecules with Siloxy Alkynes

(2012) Wanxiang Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold-Catalyzed Cyclizations of (o-Alkynyl)phenoxyacrylates with External Nucleophiles: Regio- and Stereoselective Synthesis of Functionalized Benzo[b]oxepines

(2012) Jun Liu et al.   ORGANIC LETTERS

Rational Design of Phosphoinositide 3-Kinase α Inhibitors That Exhibit Selectivity over the Phosphoinositide 3-Kinase β Isoform

(2011) Timothy P. Heffron et al.   JOURNAL OF MEDICINAL CHEMISTRY

Enantioselective Intramolecular Openings of Oxetanes Catalyzed by (salen)Co(III) Complexes: Access to Enantioenriched Tetrahydrofurans

(2009) Rebecca N. Loy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY