Development of Axially Chiral Styrene-Type Carboxylic Acid Ligands via Palladium-Catalyzed Asymmetric C–H Alkynylation

Combined Dynamic Kinetic Resolution and C‐H Functionalization for Facile Synthesis of Non‐Biaryl‐Atropisomer‐type Axially Chiral Organosilanes

(2021) Li-Wen Xu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Development of Pseudo-C2-symmetric Chiral Binaphthyl Monocarboxylic Acids for Enantioselective C(sp3)–H Functionalization Reactions under Rh(III) Catalysis

(2021) Yoshimi Kato et al.   ACS Catalysis

Chiral Carboxylic Acid Assisted Enantioselective C–H Activation with Achiral CpxMIII (M = Co, Rh, Ir) Catalysts

(2021) Tatsuhiko Yoshino et al.   ACS Catalysis

Tandem Iridium Catalysis as a General Strategy for Atroposelective Construction of Axially Chiral Styrenes

(2021) Jie Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Atroposelective Synthesis of Conjugated Diene-Based Axially Chiral Styrenes via Pd(II)-Catalyzed Thioether-Directed Alkenyl C–H Olefination

(2021) Liang Jin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Axially Chiral Styrenes through Pd-Catalyzed Asymmetric C−H Olefination Enabled by an Amino Amide Transient Directing Group

(2020) Hong Song et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diverse Approaches for Enantioselective C–H Functionalization Reactions Using Group 9 CpxMIII Catalysts

(2020) Tatsuhiko Yoshino et al.   CHEMISTRY-A EUROPEAN JOURNAL

Atroposelective Synthesis of Axially Chiral Styrenes via an Asymmetric C–H Functionalization Strategy

(2020) Liang Jin et al.   Chem

Enantioselective C–H functionalization of bicyclo[1.1.1]pentanes

(2020) Zachary J. Garlets et al.   Nature Catalysis

From Pd(OAc)2 to Chiral Catalysts: The Discovery and Development of Bifunctional Mono-N-Protected Amino Acid Ligands for Diverse C–H Functionalization Reactions

(2020) Qian Shao et al.   ACCOUNTS OF CHEMICAL RESEARCH

Distal γ‐C(sp3)−H Olefination of Ketone Derivatives and Free Carboxylic Acids

(2020) Han Seul Park et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Axially Chiral Aryl‐Alkene‐Indole Framework: A Nascent Member of the Atropisomeric Family and Its Catalytic Asymmetric Construction

(2020) Cong‐Shuai Wang et al.   CHINESE JOURNAL OF CHEMISTRY

Transition Metal‐Catalyzed Enantioselective C–H Functionalization via Chiral Transient Directing Group Strategy

(2020) Gang Liao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand-Accelerated Palladium(II)-Catalyzed Enantioselective Amination of C(sp2)–H Bonds

(2020) Xiu-Fen Cheng et al.   ORGANIC LETTERS

Atroposelective Access to Oxindole-Based Axially Chiral Styrenes via the Strategy of Catalytic Kinetic Resolution

(2020) Chun Ma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Atroposelective Oxidative C–H/C–H Cross-Coupling Reaction of 1-Aryl Isoquinoline Derivatives with Electron-Rich Heteroarenes

(2020) Qiang Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)/Chiral Carboxylic Acid Catalyzed Enantioselective C(sp3)–H Alkylation of 8-Ethylquinolines with α,β-Unsaturated Carbonyl Compounds

(2020) Long-Tao Huang et al.   ORGANIC LETTERS

Chiral paddle-wheel diruthenium complexes for asymmetric catalysis

(2020) Taku Miyazawa et al.   Nature Catalysis

Recent Advances on Enantioselective Direct C−H Addition to Carbonyls and Michael Acceptors

(2020) Qing Gu et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Enantioselective Synthesis of Azoniahelicenes by Rh-Catalyzed C–H Annulation with Alkynes

(2020) Qiang Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Atropisomers Featuring Pentatomic Heteroaromatics by Pd-Catalyzed C–H Alkynylation

(2019) Shuo Zhang et al.   ACS Catalysis

Pd(II)-Catalyzed Enantioselective Alkynylation of Unbiased Methylene C(sp3)–H Bonds Using 3,3′-Fluorinated-BINOL as a Chiral Ligand

(2019) Ye-Qiang Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective C-H Activation with Earth-Abundant 3d Transition Metals

(2019) Joachim Loup et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cp*CoIII-Catalyzed C–H Functionalization and Asymmetric Reactions Using External Chiral Sources

(2019) Tatsuhiko Yoshino et al.   SYNLETT

Dirhodium tetracarboxylates as catalysts for selective intermolecular C–H functionalization

(2019) Huw M. L. Davies et al.   Nature Reviews Chemistry

Chiral 2-Aryl Ferrocene Carboxylic Acids for the Catalytic Asymmetric C(sp3)–H Activation of Thioamides

(2019) Daichi Sekine et al.   ORGANOMETALLICS

Rational design, enantioselective synthesis and catalytic applications of axially chiral EBINOLs

(2019) Yong-Bin Wang et al.   Nature Catalysis

Catalytic Enantioselective Methylene C(sp3 )−H Amidation of 8-Alkylquinolines Using a Cp*RhIII /Chiral Carboxylic Acid System

(2019) Seiya Fukagawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A general asymmetric copper-catalysed Sonogashira C(sp3)–C(sp) coupling

(2019) Xiao-Yang Dong et al.   Nature Chemistry

Cp*Co III /Chiral Carboxylic Acid‐Catalyzed Enantioselective 1,4‐Addition Reactions of Indoles to Maleimides

(2019) Takumaru Kurihara et al.   Asian Journal of Organic Chemistry

Palladium-Catalyzed Enantioselective C−H Olefination of Diaryl Sulfoxides through Parallel Kinetic Resolution and Desymmetrization

(2018) Yu-Chao Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Scalable, Stereocontrolled Formal Syntheses of (+)-Isoschizandrin and (+)-Steganone: Development and Applications of Palladium(II)-Catalyzed Atroposelective C−H Alkynylation

(2018) Gang Liao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective γ-C(sp3)–H Activation of Alkyl Amines via Pd(II)/Pd(0) Catalysis

(2018) Qian Shao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic Enantioselective Construction of Axially Chiral Sulfone-Containing Styrenes

(2018) Shiqi Jia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Understanding Regiodivergence in a Pd(II)-Mediated Site-Selective C–H Alkynylation

(2018) Kenji Usui et al.   ACS Catalysis

Chiral Carboxylic Acid Enabled Achiral Rhodium(III)-Catalyzed Enantioselective C−H Functionalization

(2018) Luqing Lin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Cobalt(III)-Catalyzed C−H Activation Enabled by Chiral Carboxylic Acid Cooperation

(2018) Fabio Pesciaioli et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

PdII -Catalyzed Enantioselective C(sp3 )−H Activation/Cross-Coupling Reactions of Free Carboxylic Acids

(2018) Liang Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective C(sp3 )-H Amidation of Thioamides Catalyzed by a CobaltIII /Chiral Carboxylic Acid Hybrid System

(2018) Seiya Fukagawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Construction of Vicinal Diaxial Styrenes and Multiaxis System via Organocatalysis

(2018) Yu Tan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Desymmetrization of cyclohexanes by site- and stereoselective C–H functionalization

(2018) Jiantao Fu et al.   NATURE

Organocatalytic atroposelective synthesis of axially chiral styrenes

(2017) Sheng-Cai Zheng et al.   Nature Communications

Palladium-Catalyzed Transformations of Alkyl C–H Bonds

(2016) Jian He et al.   CHEMICAL REVIEWS

Silver-Free Palladium-Catalyzed sp3 and sp2 C–H Alkynylation Promoted by a 1,2,3-Triazole Amine Directing Group

(2016) Xiaohan Ye et al.   ORGANIC LETTERS

The mechanism of palladium(II)-mediated C–H cleavage with mono-N-protected amino acid (MPAA) ligands: origins of rate acceleration

(2016) Keary M. Engle   PURE AND APPLIED CHEMISTRY

Ligand-accelerated enantioselective methylene C(sp3)–H bond activation

(2016) Gang Chen et al.   SCIENCE

Stronger Brønsted Acids: Recent Progress

(2015) Takahiko Akiyama et al.   CHEMICAL REVIEWS

Dual role of carboxylic acid additive: mechanistic studies and implication for the asymmetric C–H amidation

(2015) Donghyeon Gwon et al.   TETRAHEDRON

Chemicals from Alkynes with Palladium Catalysts

(2013) Rafael Chinchilla et al.   CHEMICAL REVIEWS

Developing Ligands for Palladium(II)-Catalyzed C–H Functionalization: Intimate Dialogue between Ligand and Substrate

(2013) Keary M. Engle et al.   JOURNAL OF ORGANIC CHEMISTRY

Pd(II)-Catalyzed Enantioselective C–H Activation/C–O Bond Formation: Synthesis of Chiral Benzofuranones

(2013) Xiu-Fen Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrophilic alkynylation: the dark side of acetylene chemistry

(2012) Jonathan P. Brand et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Alkenylation and Alkynylation of ortho-C(sp2)–H Bonds of Benzylamine Picolinamides

(2012) Yingsheng Zhao et al.   ORGANIC LETTERS

Click chemistry: function follows form

(2010) M. G. Finn et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Direct Alkynylation of C−H Bonds in Benzenes

(2009) Mamoru Tobisu et al.   ORGANIC LETTERS

PdII-Catalyzed Enantioselective Activation of C(sp2)H and C(sp3)H Bonds Using Monoprotected Amino Acids as Chiral Ligands

(2008) Bing-Feng Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION