4.7 Article

Effect of Y addition on microstructure evolution and precipitation of Cu-Co-Si alloy during hot deformation

Journal

MATERIALS CHARACTERIZATION
Volume 181, Issue -, Pages -

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.matchar.2021.111502

Keywords

Cu-Co-Si and Cu-Co-Si-Y alloys; Hot deformation; Constitutive equations; Microstructure evolution; Precipitates

Funding

  1. Outstanding Talents Innovation Fund of Henan Province [ZYQR201912164]
  2. Key Scientific Research Projects of Higher Education in Henan Province [21A430013]
  3. Natural Science Foundation of Henan Province [202300410144]
  4. National Natural Science Foundation of China [52071134]

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The effects of Y on the microstructure evolutions of Cu-Co-Si alloys during hot deformation were investigated, and it was found that the addition of Y promoted the nucleation and growth of dynamic recrystallization grains, reduced texture strength, and decreased the number of small angle grain boundaries. Transmission electron microscopy analysis revealed the distribution of Co2Si nanoparticles and their interaction with dislocations during hot deformation to improve deformation resistance.
The effects of Y for the microstructure evolutions of Cu-Co-Si alloys during hot deformation were investigated. The hot deformation behaviors for Cu-2.6Co-0.655i and Cu-2.6Co-0.655i-0.2Y alloys were carried out on the Gleeble-1500 simulator with the strain rates from 0.001 to 10 s(-1) and temperatures from 500 degrees C to 900 degrees C. The hot deformation activation energies for two copper alloys were calculated and the constitutive equations were also established. According to the true stress-strain curves and EBSD image analysis, it showed that the nucleation of dynamic recrystallization (DRX) grain and the growth of DRX grain were promoted with the addition of 0.2 wt% Y. Electron backscatter diffraction (EBSD) was used to characterize the microstructure of the hot deformed Cu-Co-Si alloy. The electrode diagram and ODF diagram were established to analyze the textures. The texture strength and the number of small angle grain boundaries were reduced by the addition of 0.2 wt% Y. The microstructure of two alloys was analyzed by transmission electron microscopy, it was found that a large number of Co2Si nanoparticles were distributed on the copper matrix. Y could promote the precipitation process of delta-Co2Si, and these nanoparticles interacted with dislocations during the hot deformation process to improve the deformation resistance.

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