4.7 Article

Overview of relevant economic and environmental aspects of waste-based activated carbons aimed at adsorptive water treatments

Journal

JOURNAL OF CLEANER PRODUCTION
Volume 344, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.jclepro.2022.130984

Keywords

Handling Editor; Panos Seferlis; Cost-effective activated carbon; Water treatment adsorption processes; Environmental impact assessment; Life cycle assessment; Environmental sustainability

Funding

  1. FCT - Fundacao para a Ciencia e a Tecnologia, I.P., through national funds [POCI-01-0145-FEDER-028598]
  2. FEDER
  3. CESAM by FCT/MCTES through national funds [UIDP/50017/2020+UIDB/50017/2020+LA/P/0094/2020]
  4. National Funds and FSE through FCT, POCH (Programa Operacional Capital Humano) and European Union [SFRH/BD/138388/2018]
  5. FCT [CEECIND/00007/2017, IF/00314/2015]
  6. Fundação para a Ciência e a Tecnologia [SFRH/BD/138388/2018] Funding Source: FCT

Ask authors/readers for more resources

The production and application of waste-based activated carbon (AC) for water treatment is a hot research topic. While waste-based AC is regarded as low-cost and environmentally friendly, few studies have estimated its cost and assessed its environmental impacts. This review aims to provide an overview of the economic and environmental costs of waste-based AC, highlighting the need for evaluating its sustainability.
The production of waste-based activated carbon (AC) for application in adsorptive water treatment is a hot research topic. The use of residues as AC precursors is generally presented as a promissory option because they are free of charge and allow for the minimization of non-renewable resources depletion. Despite waste-based AC being usually labelled as low-cost and environmental-friendly adsorbents, few studies involve cost estimations and even less assess the environmental impacts associated to their production and application. In the last few years, there has been a growing awareness about the search for greener processes, resulting in the increase of publications on the cost estimation and the life cycle assessment (LCA) of waste-based AC. Still, to the best of the authors' knowledge, a review focusing on the distinct approaches and conclusions carried out by different authors does not exist. Therefore, the aim of this work is to present an overview on relevant aspects of the economic and environmental costs of waste-based AC for application in water treatment. Overall, published studies show that the price of the precursors, the energy required for production (which can be optimized at industrial scale) and the properties of the produced material largely influence the AC final cost. As for LCA studies, they generally evidence that producing AC from wastes is an interesting management route that may present important energy and resource savings when compared to the production of AC from fossil resources. Moreover, literature points out that attention must be paid to regeneration of waste-based AC to sustainably post-pone their end-of-life. This review stresses the necessity of assessing the economic and environmental costs of waste-based AC in order to avoid vague and unsupported conclusions on their sustainability.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Engineering, Environmental

Multivariable optimization of activated carbon production from microwave pyrolysis of brewery wastes-Application in the removal of antibiotics from water

Erika M. L. Sousa, Marta Otero, Luciana S. Rocha, Maria Gil, Paula Ferreira, Valdemar Esteves, Vania Calisto

Summary: This study aimed to optimize the one-step chemical activation and microwave pyrolysis process to obtain a microporous activated carbon with superior textural and adsorptive properties. The results showed that by using fast pyrolysis and low load of activating agent, it is possible to obtain ideal adsorption performance while reducing the environmental and economic impact.

JOURNAL OF HAZARDOUS MATERIALS (2022)

Article Environmental Sciences

Estrogens in wastewaters: Can different operating conditions improve their removal in anaerobic conditions?

Vitoria L. Louros, Andreia F. C. Sousa, Diana L. D. Lima, Pedro M. P. Santos, Jorge H. Leitao, Valdemar Esteves, Helena G. A. Nadais

Summary: This study assessed the removal of estrone (E1) and 17 alpha-ethinylestradiol (EE2) from synthetic wastewater under anaerobic conditions. The results showed that an increase in temperature favored E1 removal, while EE2 was not affected. Lower mixed liquor suspended solid (MLSS) concentrations promoted higher removal of E1 and EE2. The presence of nitrate did not influence the removal of E1 and EE2.

WATER AND ENVIRONMENT JOURNAL (2022)

Article Marine & Freshwater Biology

Metabolic and oxidative status alterations induced in Ruditapes philippinarum exposed chronically to estrogen 17α-ethinylestradiol under a warming scenario

Monica G. Silva, Valdemar Esteves, Valentina Meucci, Federica Battaglia, Amadeu M. V. M. Soares, Carlo Pretti, Rosa Freitas

Summary: The presence of pharmaceuticals in the aquatic environment is a concern, but the effects of these substances under different climate change scenarios are not well understood. This study examined the toxicological impacts of a specific pharmaceutical, 17 alpha-ethinylestradiol (EE2), on edible clams under current and predicted warming scenarios. The results showed that EE2 concentrations disturbed the redox homeostasis of the clams, but the clams were able to activate their defense mechanisms to cope with the stress.

AQUATIC TOXICOLOGY (2022)

Article Environmental Sciences

Responses of Ruditapes philippinarum to contamination by pharmaceutical drugs under ocean acidification scenario

Angela Almeida, Vania Calisto, Valdemar I. Esteves, Rudolf J. Schneider, Amadeu M. V. M. Soares, Rosa Freitas

Summary: This study aimed to evaluate the impacts of pharmaceutical drugs and acidification on edible clams. The results showed that the combination of drugs had fewer impacts on the clams compared to when the drugs were acting alone. Acidification had negative effects on the clams, but it did not enhance the toxicity when combined with pharmaceutical drugs.

SCIENCE OF THE TOTAL ENVIRONMENT (2022)

Article Environmental Sciences

Sulfadiazine's photodegradation using a novel magnetic and reusable carbon based photocatalyst: Photocatalytic efficiency and toxic impacts to marine bivalves

Vitoria L. Louros, Valentina Silva, Carla Patricia Silva, Vania Calisto, Marta Otero, Valdemar Esteves, Rosa Freitas, Diana L. D. Lima

Summary: In this study, waste-based biochar functionalized with titanium dioxide and magnetized using an ex-situ approach was used for the photocatalytic degradation of the antibiotic sulfadiazine in the aquaculture industry. The application of the synthetic photosensitizer (SPS) enhanced the degradation efficiency, and the magnetization procedure allowed for good reusability of the SPS. The effects of the treated water on marine bivalves were evaluated, and the results showed that the SPS treatment effectively decreased the biochemical impacts on the mussels.

JOURNAL OF ENVIRONMENTAL MANAGEMENT (2022)

Article Thermodynamics

Halimione portulacoides biomass - a sustainable feedstock for bioenergy production from an integrated water-energy-food system

Ricardo N. Coimbra, Marco Custodio, Eduardo M. Cuerda-Correa, Moonis Ali Khan, Ricardo Calado, Ana Lillebo, Marta Otero

Summary: This study evaluated the bioenergy production potential of Halimione portulacoides for the phytoremediation of nutrient-rich simulated wastewater. The study found that the roots and canes of Halimione portulacoides have high carbon content and low ash content, making them suitable for bioenergy production. The nutrient treatments did not have a significant impact on bioenergy production or biomass characteristics. This suggests that Halimione portulacoides can be used as a source of bioenergy in water phytoremediation.

ENERGY CONVERSION AND MANAGEMENT (2022)

Article Environmental Sciences

Dynamic adsorption of diclofenac onto a magnetic nanocomposite in a continuous stirred-tank reactor

L. Rocha, E. M. L. Sousa, M. V. Gil, M. Otero, V. I. Esteves, V. Calisto

Summary: This study evaluated the dynamic removal of diclofenac (DCF) from water and wastewater using waste-based magnetic activated carbon (MAC) in a continuous-flow stirred tank reactor (CSTR) for the first time. The results demonstrated the feasibility of producing MAC composites with high adsorption efficiency, easy retrievability, and successful regeneration for further reutilization.

JOURNAL OF ENVIRONMENTAL MANAGEMENT (2022)

Article Engineering, Environmental

Ex-situ magnetic activated carbon for the adsorption of three pharmaceuticals with distinct physicochemical properties from real wastewater

Diogo Pereira, Marta V. Gil, Valdemar I. Esteves, Nuno J. O. Silva, Marta Otero, Vania Calisto

Summary: Pharmaceuticals are frequently found in the environment and can cause harm to human and wildlife as they are able to evade conventional wastewater treatments. This study developed a waste-based magnetic activated carbon (MAC) from paper mill sludge for the adsorptive removal of carbamazepine (CBZ), sulfamethoxazole (SMX), and ibuprofen (IBU) from water and wastewater. The MAC was obtained through electrostatic interactions between magnetic and activated carbon particles. The optimized condition (MACX3) showed excellent properties in terms of surface area and saturation magnetization. Kinetic and equilibrium adsorption studies demonstrated the broad applicability of MACX3 in pharmaceutical adsorption in both ultrapure water and wastewater.

JOURNAL OF HAZARDOUS MATERIALS (2023)

Article Environmental Sciences

Chitin-Based Magnesium Oxide Biocomposite for the Removal of Methyl Orange from Water

Hicham Majdoubi, Ayoub Abdullah Alqadami, Rachid E. L. Kaim Billah, Marta Otero, Byong-Hun Jeon, Hassan Hannache, Youssef Tamraoui, Moonis Ali Khan

Summary: In this study, a cost-effective chitin-based magnesium oxide (CHt@MgO) biocomposite was developed for efficient removal of anionic methyl orange (MO) dye from water. The CHt@MgO biocomposite was successfully synthesized and characterized. Experimental parameters such as pH, adsorbent amount, contact time, temperature, and initial MO concentration were optimized for MO removal. Langmuir and pseudo-first-order (PFO) models were found to be the most suitable for describing equilibrium and kinetic results, respectively. The CHt@MgO biocomposite exhibited a maximum adsorption capacity of 252 mg/g at 60 degrees C. Reusability tests showed a high removal efficiency of 90.7% after the fifth regeneration cycle.

INTERNATIONAL JOURNAL OF ENVIRONMENTAL RESEARCH AND PUBLIC HEALTH (2023)

Article Polymer Science

A Novel Chitosan/Nano-Hydroxyapatite Composite for the Adsorptive Removal of Cd(II) from Aqueous Solution

Rachid El Kaim Billah, Ikrame Ayouch, Youness Abdellaoui, Zineb Kassab, Moonis Ali Khan, Mahfoud Agunaou, Abdessadik Soufiane, Marta Otero, Byong-Hun Jeon

Summary: A novel polymer bio-composite (CS/n-Hap) consisting of nano-hydroxyapatite (n-Hap) and chitosan (CS) was synthesized for the efficient removal of toxic cadmium ions from water. The CS/n-Hap bio-composite exhibited superior adsorption capacity compared to pristine CS, with a maximum uptake of 126.65 mg/g under optimized conditions. The adsorption mechanism involved the formation of chemical bonds between Cd(II) and CS/n-Hap, as confirmed by the kinetic and thermodynamic studies.

POLYMERS (2023)

Article Biotechnology & Applied Microbiology

Insights into matrix and competitive effects on antibiotics removal from wastewater by activated carbon produced from brewery residues

Erika M. L. Sousa, Marta Otero, Maria V. Gil, Paula Ferreira, Valdemar I. Esteves, Vania Calisto

Summary: The efficient removal of antibiotics from wastewater is necessary to prevent their discharge into the aquatic environment and the associated negative effects. An optimized brewery waste-derived activated carbon (AC-SBG) was evaluated for its adsorptive performance in removing three antibiotics from relevant matrix conditions. The results showed that AC-SBG had similar adsorption kinetics to a commercial activated carbon (CAC) and exhibited higher maximum adsorption capacities in ultrapure water. However, in wastewater, the maximum adsorption capacities decreased due to competitive effects. The study also revealed that electrostatic interactions and pH had significant influences on the antibiotics adsorption.

ENVIRONMENTAL TECHNOLOGY & INNOVATION (2023)

Article Chemistry, Analytical

Removal of Sr(II) in Aqueous Solutions Using Magnetic Crayfish Shell Biochar

Wenchao Lu, Jundong Feng, Marta Otero, Tao Liao, Liang Qiu

Summary: In this study, magnetic biochar produced by crayfish shells (mag@CSBC) was used as an adsorbent to remove radionuclide Sr(II) in an aqueous solution and under irradiation conditions. It has low cost, easy synthesis, environmental friendliness, and easy recyclability, making it suitable for large-scale removal of Sr(II) from aqueous solutions.

SEPARATIONS (2023)

Article Chemistry, Applied

Enhanced solar driven photocatalytic removal of antibiotics from aquaculture effluents by TiO2/carbon quantum dot composites

Valentina Silva, Joana F. A. Fernandes, Maria Clara Tomas, Carla Patricia Silva, Vania Calisto, Marta Otero, Diana L. D. Lima

Summary: The combination of carbon quantum dots (CQDs) and titanium dioxide (TiO2) shows promising results in efficiently removing antibiotics from aquaculture effluents through solar-driven photodegradation. This method achieves remarkable reductions in the half-life times of SDZ, SMX, and TMP in both fresh and brackish water matrices.

CATALYSIS TODAY (2023)

Review Engineering, Environmental

Metal-organic framework-based composites for biogas and natural gas uptake: An overview of adsorption and storage mechanisms of gaseous fuels

Mohammed Yusuf, Ramesh Kumar, Moonis Ali Khan, M. J. Ahmed, Marta Otero, Subbaiah Muthu Prabhu, Moon Son, Jae-Hoon Hwang, Woo Hyoung Lee, Byong-Hun Jeon

Summary: Biogas and natural gas have the potential to be renewable energy sources and need to be upgraded to increase their CH4 content. Adsorption-based methods using metal-organic frameworks (MOFs) could be an attractive option for upgrading. MOFs, as versatile porous solid-state materials, have various unique properties and can play a significant role in gas adsorption and storage.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Green & Sustainable Science & Technology

Relative evaluation of probabilistic methods for spatio-temporal wind forecasting

Lars odegaard Bentsen, Narada Dilp Warakagoda, Roy Stenbro, Paal Engelstad

Summary: This study investigates uncertainty modeling in wind power forecasting using different parametric and non-parametric methods. Johnson's SU distribution is found to outperform Gaussian distributions in predicting wind power. This research contributes to the literature by introducing Johnson's SU distribution as a candidate for probabilistic wind forecasting.

JOURNAL OF CLEANER PRODUCTION (2024)

Article Green & Sustainable Science & Technology

Comparison of ethane recovery processes for lean gas based on a coupled model

Xing Liu, Qiuchen Wang, Yunhao Wen, Long Li, Xinfang Zhang, Yi Wang

Summary: This study analyzes the characteristics of process parameters in three lean gas ethane recovery processes and establishes a prediction and multiobjective optimization model for ethane recovery and system energy consumption. A new method for comparing ethane recovery processes for lean gas is proposed, and the addition of extra coolers improves the ethane recovery. The support vector regression model based on grey wolf optimization demonstrates the highest prediction accuracy, and the multiobjective multiverse optimization algorithm shows the best optimization performance and diversity in the solutions.

JOURNAL OF CLEANER PRODUCTION (2024)

Article Green & Sustainable Science & Technology

A novel deep-learning framework for short-term prediction of cooling load in public buildings

Cairong Song, Haidong Yang, Xian-Bing Meng, Pan Yang, Jianyang Cai, Hao Bao, Kangkang Xu

Summary: The paper proposes a novel deep learning-based prediction framework, aTCN-LSTM, for accurate cooling load predictions. The framework utilizes a gate-controlled multi-head temporal convolutional network and a sparse probabilistic self-attention mechanism with a bidirectional long short-term memory network to capture both temporal and long-term dependencies in the cooling load sequences. Experimental results demonstrate the effectiveness and superiority of the proposed method, which can serve as an effective guide for HVAC chiller scheduling and demand management initiatives.

JOURNAL OF CLEANER PRODUCTION (2024)

Article Green & Sustainable Science & Technology

The impact of social interaction and information acquisition on the adoption of soil and water conservation technology by farmers: Evidence from the Loess Plateau, China

Zhe Chen, Xiaojing Li, Xianli Xia, Jizhou Zhang

Summary: This study uses survey data from the Loess Plateau in China to evaluate the impact of social interaction on the adoption of soil and water conservation (SWC) technology by farmers. The study finds that social interaction increases the likelihood of farmers adopting SWC, and internet use moderates this effect. The positive impact of social interaction on SWC adoption is more pronounced for farmers in larger villages and those who join cooperative societies.

JOURNAL OF CLEANER PRODUCTION (2024)

Article Green & Sustainable Science & Technology

Study on synergistic heat transfer enhancement and adaptive control behavior of baffle under sudden change of inlet velocity in a micro combustor

Chenghua Zhang, Yunfei Yan, Kaiming Shen, Zongguo Xue, Jingxiang You, Yonghong Wu, Ziqiang He

Summary: This paper reports a novel method that significantly improves combustion performance, including heat transfer enhancement under steady-state conditions and adaptive stable flame regulation under velocity sudden increase.

JOURNAL OF CLEANER PRODUCTION (2024)