Article
Chemistry, Physical
Weiyang Wang, Shuang Zhou, Zhu Xiao, Wenting Qiu, Qian Lei
Summary: This study investigated the microstructure evolution and properties of a CuCrZrSc alloy undergoing aging treatment and equal channel angular pressing (ECAP). The results showed that pre-aging treatment significantly improved the mechanical properties and electrical conductivity of the alloy. After 12 passes of deformation and aging treatment, the alloy exhibited enhanced mechanical properties.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Materials Science, Multidisciplinary
A. R. Eivani, S. M. Mirghasemi, S. H. Seyedein, J. Zhou, H. R. Jafarian
Summary: This research aimed to lower the deformation temperature of AZ31 magnesium alloy samples by applying cover tube casing (CTC) and incorporating the Cockcroft Latham (C & L) fracture model into finite element simulation. The results showed that increasing CTC thickness improved the workability of the alloy and enabled the production of high-quality products with a uniform grain structure at lower temperatures.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2021)
Article
Nanoscience & Nanotechnology
Y. L. Bian, Z. D. Feng, N. B. Zhang, Y. X. Li, X. F. Wang, B. B. Zhang, Y. Cai, L. Lu, S. Chen, X. H. Yao, S. N. Luo
Summary: This study investigates the processing of a high-entropy alloy through dynamic equal channel angular pressing (D-ECAP) and subsequent annealing, and observes the occurrence of kink bands within a face-centered cubic HEA. The strengthening mechanisms are discussed.
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
(2022)
Article
Chemistry, Physical
Song-Jeng Huang, Matoke Peter Mose, Veeramanikandan Rajagopal
Summary: The ECAP method significantly refines the microstructure of AZ61 alloy, enhancing its hydrogen storage capacity and reaction kinetics. The addition of Ni catalyst after ECAP treatment accelerates hydrogen absorption and desorption kinetics.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Physical
Shiwen Hu, Taojun Li, Qinglin Li, Dexue Liu
Summary: Equal channel angular pressing (ECAP) was used to enhance the mechanical properties and wear resistance of a biomedical TiZrNb medium entropy alloy (MEA). The alloy exhibited an increased yield strength and hardness after multiple deformation passes, with the formation of coarse grains and dense dislocation walls (HDDWs) that evolved into shear bands.
Article
Materials Science, Multidisciplinary
Xiaoru Zhuo, Cong Shao, Peng Zhang, Zhichao Hu, Huan Liu
Summary: An Mg-5Sn alloy was processed by ECAP, and the microstructure evolution and mechanical properties were studied. The grain size, amount of Mg2Sn precipitates, and texture varied with the number of passes. ECAP alloys showed improved strengths due to various strengthening mechanisms. The UTS increased while the EL decreased with increasing ECAP pass.
Article
Materials Science, Multidisciplinary
Hongfei Wang, Chunyan Ban, Nannan Zhao, Lei Li, Qingfeng Zhu, Jianzhong Cui
Summary: In this study, pure titanium samples with a purity of 99.99 wt.% were successfully processed by ECAP at cryogenic temperature, leading to significant grain refinement and increased hardness. The activation of slip systems during deformation process was observed, and the influence of temperature on grain refinement was discussed. Factors affecting the homogeneity of microstructure were also analyzed.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2021)
Article
Materials Science, Multidisciplinary
Saman Khalilpourazary, Vali Alimirzaloo, Shahrad Karami Goodarzi, Gholamreza Hosseinpour
Summary: The research shows that the friction coefficients in ECAPed copper in the first and second passes are similar while using graphite and Molybdenum disulfide lubricants, but in the third pass and annealed copper, graphite and Molybdenum disulfide lubricants have a better effect on reducing friction coefficients. Additionally, in all copper samples except for ECAPed copper in the third pass, Molybdenum disulfide lubricant decreases the friction coefficient more compared to graphite lubricant.
JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE
(2022)
Article
Multidisciplinary Sciences
Przemyslaw Snopinski
Summary: This study focused on electron microscopy studies of microstructural defects in an additively manufactured AlSi10Mg alloy. The findings revealed that deformation twinning, phase transformation, and amorphization are possible deformation mechanisms for the silicon phase. It was also found that dislocation slip and stacking faults were the predominant deformation modes for the aluminum matrix. These findings contribute to a better understanding of the deformation micro-mechanism of the alloy and provide potential for the development of new structural materials.
Article
Materials Science, Multidisciplinary
G. S. Dyakonov, T. Yakovleva, A. G. Stotskiy, S. Mironov
Summary: The microstructural characterization of the Ti-5.7Al-3.8Mo-1.2Zr-1.3Sn alloy after equal channel angular pressing (ECAP) showed that the spheroidization process was governed by the conventional boundary splitting mechanism, with a nearly-Burgers orientation relationship between the spheroidized a-and b phases. This suggests a high cooperation in slip activity between the phases.
Article
Materials Science, Multidisciplinary
Jianqiang Hao, Li Zhao, Jinshan Zhang, Hongxia Wang, Weili Cheng, Boqiong Li, Yang Bai
Summary: This study investigates the solution to the problem of internal surface cracking during equal channel angular pressing (ECAP) by modifying a conventional die. The modified die is compared and analyzed with DEFORM-3D software. A modified ECAP die is manufactured to examine the effect of different pressing passes on the microstructure and mechanical properties of the solution-treated Mg93.5Zn2.5Y2.5Mn1Ti0.5 alloy.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2023)
Article
Materials Science, Multidisciplinary
Guzide Meltem Lule Senoz, Taha Alper Yilmaz
Summary: Optimization of ECAP parameters improved the mechanical and microstructural properties of Al-Zn-Mg alloy, with the optimal condition identified. Temperature was found to have a significant effect on grain size.
METALS AND MATERIALS INTERNATIONAL
(2021)
Article
Chemistry, Physical
Przemyslaw Snopinski, Augustine Nana Sekyi Appiah, Ondrej Hilser, Michal Kotoul
Summary: In this study, the microstructural evolution and mechanical properties of SLM-produced AlSi10Mg alloy were investigated using post-processing with ECAP. Low-temperature annealing and ECAP treatment resulted in partial breakage of Si networks and nucleation of β-Si precipitates in the Al matrix, leading to improved microhardness and yield strength of the alloy.
Article
Multidisciplinary Sciences
Przemyslaw Snopinski, Anna Wozniak, Dariusz Lukowiec, Krzysztof Matus, Tomasz Tanski, Stanislav Rusz, Ondrej Hilser
Summary: This study presents experimental results on the effects of heat treatment and ECAP on microstructure modification and corrosion behavior of SLM-fabricated AlSi10Mg alloy. The results show that the imposed strain reduces the grain size and improves the corrosion resistance by providing more nucleation sites for oxide film formation.
Article
Nanoscience & Nanotechnology
Meshal Y. Alawadhi, Shima Sabbaghianrad, Yi Huang, Terence G. Langdon
Summary: The research shows that processing oxygen-free copper through equal-channel angular pressing at room temperature can alter its microstructure and mechanical properties, indicating the occurrence of dynamic recovery in tensile testing.
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
(2021)
Article
Materials Science, Multidisciplinary
Tao Zhou, Jie Dai, Zhu Xiao, Wen-Ting Qiu, Qian Lei, Xinwei Liu, Liuxin Qin, Muzhi Ma
Summary: The Cu2O-Gr composites prepared by short-process reduction and vacuum hot pressing exhibit higher density and strength, as well as lower friction coefficients and wear rates compared to Cu-Gr composites prepared by conventional hot pressing. The study shows that the modification of graphite morphology and enhancement of interface bonding contribute to the improved mechanical performance of the composites.
Article
Chemistry, Physical
Yidi Li, Xiaobo Yuan, Biaobiao Yang, Xianjue Ye, Ping Zhang, Haoyu Lang, Qian Lei, Jiantao Liu, Yunping Li
Summary: A near-full dense Cu-36.8Fe alloy was manufactured by selective laser melting, showing excellent mechanical performances due to the unique hierarchical microstructures. These findings provide insights for applying SLM technique to other immiscible alloys to design for higher mechanical performances.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Materials Science, Multidisciplinary
Yihai Yang, Qian Lei, Huan Liu, Jianda Hong, Zhen Han, Qi An, Jimin Shan, Xi Chen, Haoran Xu, Zhu Xiao, Shen Gong
Summary: This study characterized the second phase particles in Cu-Cr-Nb alloys and uncovered their crystal structure, precipitation, phase transformation behavior, and orientation relationship. The findings are significant for developing high-performance Cu-Cr-Nb alloys.
MATERIALS & DESIGN
(2022)
Article
Nanoscience & Nanotechnology
Muzhi Ma, Zhou Li, Zhu Xiao, Yanlin Jia, Xiangpeng Meng, Yanbin Jiang, Yue Hu
Summary: This paper investigates the microstructure and properties of a series of Cu-based alloys fabricated through multi-step thermo-mechanical treatment (TMT). The results show that these alloys exhibit a combination of high strengths and high conductivity. The study also reveals the influence of alloy composition on the properties.
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
(2022)
Article
Materials Science, Multidisciplinary
Dong Jiang, Zhou Li, Jinjun Xu, Qianye Ren, Solomon-Oshioke Agbedor, Qian Lei
Summary: In this study, the high-temperature oxidation behavior and mechanism of a high-entropy alloy were investigated. The results revealed three oxidation stages and the formation of three layers of oxide. These findings contribute to the understanding and potential applications of high-entropy alloys.
MATERIALS TODAY COMMUNICATIONS
(2022)
Article
Materials Science, Multidisciplinary
Yuntian Zhu, Zhu Xiao, Zhou Li, Kerui Song, Qian Lei, Yu Chen
Summary: Polycrystalline tantalum sheets were deformed using different rolling methods, resulting in changes in recrystallization and grain size. Cryogenic-rolled samples showed easier recrystallization and larger grain size after annealing. Additionally, the fraction of alpha-texture in APR-ed samples decreased significantly with increasing annealing time.
Article
Chemistry, Physical
Jinjuan Cheng, Yi Gao, Ziyan Zhang, Xueping Gan, Qian Lei, Xijun Wu
Summary: The addition of yttrium to Cu-15Ni-8Sn alloy affects the grain growth and mechanical properties, resulting in increased strength and hardness.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Materials Science, Multidisciplinary
Meng Wang, Qianru Yang, Yanbin Jiang, Liuxin Qin, Fei Tan, Zhao Xin, Zhu Xiao
Summary: A Cu-9Ni-6Sn alloy bar with axial columnar grains was prepared by directional solidification. The effects of aging on the microstructure and mechanical properties of the alloy were studied. The results showed that aging treatment significantly increased the tensile strength but decreased the elongation of the alloy.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2022)
Article
Chemistry, Physical
Weiyang Wang, Shuang Zhou, Zhu Xiao, Wenting Qiu, Qian Lei
Summary: This study investigated the microstructure evolution and properties of a CuCrZrSc alloy undergoing aging treatment and equal channel angular pressing (ECAP). The results showed that pre-aging treatment significantly improved the mechanical properties and electrical conductivity of the alloy. After 12 passes of deformation and aging treatment, the alloy exhibited enhanced mechanical properties.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
Xu Wang, Zhu Xiao, Xiang-peng Meng, Yu-hang Yi, Lei Chen
Summary: A Cu-based alloy was deformed by equal channel angular pressing (ECAP) at different temperatures, and the evolution of its microstructure and mechanical properties was studied. The cryogenic-deformed samples exhibited slightly higher hardness compared to the room-temperature-deformed samples, but their yield strengths were similar after multiple ECAP passes. ECAP deformation significantly refined the grain size of the alloy through dislocation subdivision and twin fragmentation.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Materials Science, Multidisciplinary
Yang Gao, Zihan Yang, Haibo Xiao, Qian Lei, Bin Liu, Yong Liu
Summary: A Cu35Ni25Co25Cr15 high-entropy alloy (HEA) coating was deposited on a pure Cu substrate by plasma transfer arc (PTA) welding to enhance its surface hardness and wear resistance. The coating consisted of Cu-rich A1 phase and NiCoCr-rich γ' phase, with an apparent structural gradient and different microstructures in different zones. The coating exhibited improved interfacial bonding with increased welding current, but the hardness showed a non-monotonic trend. At a welding current of 150 A, the coating showed good metallurgical bonding with the Cu substrate and excellent wear resistance, especially at high temperatures.
Article
Materials Science, Multidisciplinary
Ruilin Lai, Weijun Zhang, Xiaofei Sheng, Xianjue Ye, Yingfeng Cai, Xiwei Zhang, Temiao Luo, Pinghu Chen, Qian Lei, Yunping Li
Summary: Lap joints between embossed projection phosphorus bronze and flat brass were successfully fabricated through resistance projection welding (RPW). The bronze projection moved into the softer brass without deformation during welding. Tensile shear loads of the joint reached a maximum value of 273.6 N at a welding current of 5.5 kA. A reaction layer, consisting of a columnar crystal solidification layer and a diffusion layer, formed at the interface beside the boundary of bronze. An elemental transition diffusion layer of about 1.5 μm was observed between H62 brass and XYK-6 phosphorus bronze. Fracture occurred on the XYK-6 side, passing through the bump instead of the welding interface, resulting in intactness of the welding interface. The results indicate the effectiveness of resistance projection welding as a method for welding copper alloys, suggesting its promising prospects in welding electrical parts.
Article
Chemistry, Physical
J. Zamora, T. Bautista, N. S. Portillo-Velez, A. Reyes-Montero, H. Pfeiffer, F. Sanchez-Ochoa, H. A. Lara-Garcia
Summary: Experimental and DFT studies were conducted on the structural, magnetic, and optical properties of RFeO3 perovskites. The perovskites exhibited an orthorhombic crystal structure and weak ferromagnetic behavior. They were confirmed to be semiconductors with a bandgap of approximately 2.1 eV.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Xianxiang Lv, Jing Jin, Weiguang Yang
Summary: By depositing TiN and TiO2 surface layers on AlSi films, the electrochemical performance of silicon-based anodes can be significantly improved, suppressing volume expansion and promoting the formation of a stable SEI layer.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Sharafat Ali, Haider Ali, Syedul Hasnain Bakhtiar, Sajjad Ali, Muhammad Zahid, Ahmed Ismail, Pir Muhammad Ismail, Amir Zada, Imran Khan, Huahai Shen, Rizwan Ullah, Habib Khan, Mohamed Bououdina, Xiaoqiang Wu, Fazal Raziq, Liang Qiao
Summary: The construction and optimization of redox-heterojunctions using a bifunctional phosphate as an electron-bridge demonstrated significant improvements in photo catalytic activity, including enhanced dispersion, reduced interfacial migration resistance, and increased abundance of active-sites.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Ren-Ni Luan, Na Xu, Chao-Ran Li, Zhi-Jie Zhang, Yu-Sheng Zhang, Jun Nan, Shu-Tao Wang, Yong-Ming Chai, Bin Dong
Summary: Extensive research has revealed that oxygen evolution reaction (OER) in alkaline conditions involves dynamic surface restructuring. The development and design of sulfide/oxide pre-catalysts can reasonably adjust the composition and structure after surface reconstruction, which is crucial for OER. This study utilized a simple two-step hydrothermal method to achieve in situ S leaching and doping, inducing the composition change and structure reconstruction of CoFe oxides. The transformed FeOOH and CoOOH exhibited excellent OER activity and could be easily mass-produced using low-cost iron based materials and simple methods.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Jun'an Lai, Daofu Wu, Peng He, Kang An, Yijia Wang, Peng Feng, WeiWei Chen, Zixian Wang, Linfeng Guo, Xiaosheng Tang
Summary: Zero-dimensional organic-inorganic metal halides (OMHs) are gaining attention in the fabrication of light-emitting diodes due to their broad emission band and high photoluminescence quantum yield. This work synthesized a zero-dimensional organic tetraphenylphosphonium bismuth chloride (TBC) that showed efficient blue light emission, with the emission mechanism attributed to the transition of Bi3+ ions. White light-emitting diodes (WLEDs) were fabricated using TBC, along with green-emitting and red-emitting single crystals, achieving single-component white emissions. These findings demonstrate the different emission mechanism of ns2 ions-based OMHs and highlight the potential of bismuth-based OMHs in WLEDs applications.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Xuewei Liang, Yunhai Su, Taisen Yang, Zhiyong Dai, Yingdi Wang, Xingping Yong
Summary: The revolutionary design concept of high-entropy alloys has brought new opportunities and challenges to the development of advanced metal materials. In this work, AlCrCuFe2NiTix high-entropy flux cored wires were prepared by combining the design idea of a high-entropy alloy with the characteristics of flux cored wire. AlCr-CuFe2NiTix high-entropy surfacing alloys were prepared using gas metal arc welding technology. The wear properties of the alloys were analyzed, and the phase composition, microstructure, strengthening mechanism, and wear mechanism were discussed. The results show that the alloys exhibit a dendritic microstructure with BCC/B2 + FCC phases. Increasing Ti content leads to the precipitation of Laves phase. The alloys show improved microhardness and wear resistance due to the precipitation of coherent B2 and Laves phases. However, excessive Ti addition results in the increase of Laves phase and reduced wear resistance of the alloys.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
M. Vadivel, M. Senthil Pandian, P. Ramasamy, Qiang Jing, Bo Liu
Summary: This work presents the enhanced photocatalytic and electrochemical performance of g-C3N4 assisted PAA on CoFe2O4 ternary nanocomposites. The incorporation of PAA and g-C3N4 improves the separation efficiency of photogenerated charge carriers, resulting in superior photocatalytic degradation and high specific capacitance values.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Vibhu T. Sivanandan, Ramany Revathy, Arun S. Prasad
Summary: In this study, pure and doped cobalt ferrite nanoparticles were prepared using the sol-gel auto-combustion method with the aid of lemon juice as eco-fuel. The crystal structure, lattice parameter, crystallite size, microstrain, optical parameters, and room temperature magnetic properties of the samples were analyzed. The effect of doping on the magnetic properties was also investigated.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Qing Guo, Bowen Zhang, Benzhe Sun, Yang Qi
Summary: This study prepared ZnO films with various nonpolar preferred orientations using conventional chemical bath deposition method and characterized their growth process and mechanism. It was found that the type and concentration of nitrate could control the preferred orientation and surface roughness of ZnO films. Additionally, ZnO films with different preferred orientations exhibited different optical properties.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Chong Zhang, Yan Liu, Zhaoyan Wang, Hang Yang
Summary: In this study, six bimetallic FeCo particles were synthesized via the hydrothermal method at different Fe:Co ratios. The Fe:Co ratio not only modulates the composition of the particles but also influences their structure and magnetic properties. The FeCo alloys showed a transformation from an Fe-based structure to a Co-based structure with increasing Co content. The Fe:Co ratio of 1:1 and 3:1 resulted in particles with the highest and lowest saturation magnetization, respectively.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Jianning Zhang, Jing Li, Yiren Wang, Xiaodong Mao, Yong Jiang
Summary: We conducted a study on the formation of ultra-fine Y-Ti-Ta-O nano-oxides in Ta+B micro-alloyed 13CrWTi-ODS alloys using electron microscopy and first-principles calculations. The Y-Ti-Ta-O nano-oxides were found to be mainly Y2(Ti,Ta)2O7, with an average size of 7 nm and a number density of 6.8 x 1023 m-3. Excess boron was found to enhance the adhesion of some low-sigma grain boundaries but weaken the Fe/Y2Ti2O7 interface, while excess tantalum enhanced the Fe/Y2Ti2O7 interface but caused serious degradation of grain boundaries.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Yirong Fang, Pei Cheng, Hang Yuan, Hao Zhao, Lishu Zhang
Summary: A new composite system of nitrogen-doped reduced graphene oxide and black phosphorus quantum dots has been developed for tumor therapy, showing improved electrochemical properties and stability. The system generates hydrogen peroxide and hydroxyl radical to effectively kill tumor cells.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Xiufang Qin, Yuanli Ma, Hui Zhang, Ting Zhang, Fang Wang, Xiaohong Xu
Summary: The structure and magnetism of cobalt ferrites after Mn2+-Tb3+ co-doping were studied. Co-doped samples exhibited cubic spinel structure and spherical shape of ferrite nanoparticles. The redistribution of Co2+ and Fe3+ ions between octahedral and tetrahedral sites was observed due to Mn2+-Tb3+ co-doping. The coercivity and magnetization saturation of co-doped samples were significantly improved, leading to a maximum energy product that is 190% higher than that of the un-doped sample.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Ho Yeon Lee, Wonjong Yu, Yoon Ho Lee
Summary: Recently, there has been an increasing interest in developing ultra-fine nanostructured electrodes with extensive reaction areas to enhance the performance and low-temperature operation of solid oxide fuel cells. The use of a refined approach involving co-sputtering metal alloys and oxide targets has demonstrated the feasibility of nano-columnar structures in perovskite-based electrodes, expanding the temperature range of thin film electrodes. This study systematically examines the effects of chamber pressure control in the co-sputtering process and identifies the intricate relationship between sputtering pressure and film structure. By fine-tuning the columnar growth in the electrode, significant improvements in performance and thermo-mechanical properties were achieved, resulting in high-performance all-sputtered solid oxide fuel cells.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Qianyun Bai, Xiaoxiao Yan, Da Liu, Kang Xiang, Xin Tu, Yanhui Guo, Renbing Wu
Summary: This study proposes a simple method to develop a non-precious transition metal-based electrocatalyst with high catalytic activity and robustness for the hydrogen evolution reaction. The as-synthesized electrode exhibits a low overpotential and high current density, indicating its potential in energy conversion.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)