Alkoxy Radicals See the Light: New Paradigms of Photochemical Synthesis

Synthetic and Mechanistic Implications of Chlorine Photoelimination in Nickel/Photoredox C(sp3)–H Cross-Coupling

(2021) Stavros K. Kariofillis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Energy Read-out as a Probe of Kinetically Hidden Transition States

(2021) Scheherzad Alvi et al.   ORGANIC LETTERS

Photocatalytic Dehydroxymethylative Arylation by Synergistic Cerium and Nickel Catalysis

(2021) Yuegang Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C(sp3)–H methylation enabled by peroxide photosensitization and Ni-mediated radical coupling

(2021) Aristidis Vasilopoulos et al.   SCIENCE

Bimodal Evans–Polanyi Relationships in Hydrogen Atom Transfer from C(sp3)–H Bonds to the Cumyloxyl Radical. A Combined Time-Resolved Kinetic and Computational Study

(2021) Michela Salamone et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photo-induced deep aerobic oxidation of alkyl aromatics

(2021) Chang-Cheng Wang et al.   Science China-Chemistry

Electrophotocatalytic Si–H Activation Governed by Polarity-Matching Effects

(2021) Yangye Jiang et al.   CCS Chemistry

N-(Alkoxy)- and N-(acyloxy)phthalimides in organic synthesis: free radical synthetic approaches and applications (microreview)

(2020) Alexander S. Budnikov et al.   Chemistry of Heterocyclic Compounds

δ-C–H Mono- and Dihalogenation of Alcohols

(2020) Alastair N. Herron et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthetic Methods Driven by the Photoactivity of Electron-Donor Acceptor Complexes

(2020) Giacomo E. M. Crisenza et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular Aromatic C–H Acyloxylation Enabled by Iron Photocatalysis

(2020) Siqi Xia et al.   ORGANIC LETTERS

When Light Meets Nitrogen-Centered Radicals: From Reagents to Catalysts

(2020) Xiao-Ye Yu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic Hydroetherification of Unactivated Alkenes Enabled by Proton‐Coupled Electron Transfer

(2020) Elaine Tsui et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbon–Carbon Bond Cleavage at Allylic Positions: Retro-allylation and Deallylation

(2020) Keisuke Nogi et al.   CHEMICAL REVIEWS

Total Synthesis of (+)-Polyoxamic Acid via Visible-Light-Mediated Photocatalytic β-Scission and 1,5-Hydrogen Atom Transfer of Glucose Derivative

(2020) Takuro Matsuoka et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Three-Component Fluoroalkylarylation of Unactivated Olefins through Nickel-Catalyzed Cross-Electrophile Coupling

(2020) Hai-Yong Tu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cerium-Catalyzed C–H Functionalizations of Alkanes Utilizing Alcohols as Hydrogen Atom Transfer Agents

(2020) Qing An et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Remote Trifluoromethylthiolation Enabled by Organophotocatalytic C–C Bond Cleavage

(2020) Tengfei Ji et al.   ORGANIC LETTERS

Visible-Light-Mediated Access to Phosphate Esters

(2020) Alya Inial et al.   ORGANIC LETTERS

Remote trifluoromethylthiolation of alcohols under visible light

(2020) Manuel Barday et al.   TETRAHEDRON

Dual Catalytic Platform for Enabling sp3 α C–H Arylation and Alkylation of Benzamides

(2020) Alexander W. Rand et al.   ACS Catalysis

Visible-Light-Promoted Site-Specific and Diverse Functionalization of a C(sp3)–C(sp3) Bond Adjacent to an Arene

(2020) Yaxin Wang et al.   ACS Catalysis

Radical-Mediated Remote Functional Group Migration

(2020) Xinxin Wu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Photocatalytic trifluoromethoxylation of arenes and heteroarenes in continuous-flow

(2020) Alexander V Nyuchev et al.   Beilstein Journal of Organic Chemistry

Selective Carbon–Carbon Bond Cleavage of Cyclopropylamine Derivatives

(2020) Olga O. Sokolova et al.   CHEMICAL REVIEWS

Metal-Catalyzed Carbon–Carbon Bond Cleavage of Unstrained Alcohols

(2020) Marius D. R. Lutz et al.   CHEMICAL REVIEWS

Transition Metal-Catalyzed Selective Carbon–Carbon Bond Cleavage of Vinylcyclopropanes in Cycloaddition Reactions

(2020) Jianhua Wang et al.   CHEMICAL REVIEWS

Selective Decarbonylation via Transition-Metal-Catalyzed Carbon–Carbon Bond Cleavage

(2020) Hong Lu et al.   CHEMICAL REVIEWS

Metal‐free, Visible Light‐induced Selective C‐C Bond Cleavage of Cycloalkanones with Molecular Oxygen

(2020) Li-Na Guo et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Copper-Catalyzed Alkynylation of Benzylic C–H Bonds via Radical Relay

(2020) Liang Fu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phosphoranyl Radical Fragmentation Reactions Driven by Photoredox Catalysis

(2020) James A. Rossi-Ashton et al.   ACS Catalysis

Enantioselective Copper-Catalyzed Trifluoromethylation of Benzylic Radicals via Ring Opening of Cyclopropanols

(2020) Chao Jiang et al.   Chem

Radical Dehydroxylative Alkylation of Tertiary Alcohols by Ti Catalysis

(2020) Hao Xie et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoinduced Fragmentation Borylation of Cyclic Alcohols and Hemiacetals

(2020) Chao Shu et al.   ORGANIC LETTERS

Metal-Free Radical-Mediated C(sp3)–H Heteroarylation of Alkanes

(2020) Xin Shao et al.   ORGANIC LETTERS

Tandem Radical Fragmentation/Cyclization of Guanidinylated Monosaccharides Grants Access to Medium-Sized Polyhydroxylated Heterocycles

(2020) Andrés G. Santana et al.   ORGANIC LETTERS

Alcohol Etherification via Alkoxy Radicals Generated by Visible-Light Photoredox Catalysis

(2020) Alexandra R. Rivero et al.   ORGANIC LETTERS

Visible-light-induced C-C bond cleavage of lignin model compounds with cyanobenziodoxolone

(2020) Ming Zheng et al.   TETRAHEDRON LETTERS

Photo-mediated selective deconstructive geminal dihalogenation of trisubstituted alkenes

(2020) Han Wang et al.   Nature Communications

Photocatalytic Generation of Aminium Radical Cations for C–N Bond Formation

(2020) Jacob M. Ganley et al.   ACS Catalysis

ROS systems are a new integrated network for sensing homeostasis and alarming stresses in organelle metabolic processes

(2020) Yu Sun et al.   Redox Biology

Temporary or removable directing groups enable activation of unstrained C–C bonds

(2020) Ying Xia et al.   Nature Reviews Chemistry

Photocatalytic Aerobic Oxidative Ring Expansion of Cyclic Ketones to Macrolactones by Cerium and Cyanoanthracene Catalysis

(2020) Jianbo Du et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoredox‐Catalyzed Multicomponent Cyclization of 2‐Vinyl Phenols, N ‐Alkoxypyridinium Salts, and Sulfur Ylides for Synthesis of Dihydrobenzofurans

(2020) Fan Yuan et al.   ChemCatChem

General Method for Enantioselective Three-Component Carboarylation of Alkenes Enabled by Visible-Light Dual Photoredox/Nickel Catalysis

(2020) Lei Guo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dual Catalytic Strategy for Forging sp2–sp3 and sp3–sp3 Architectures via β-Scission of Aliphatic Alcohol Derivatives

(2020) Fei Cong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-Light-Driven, Metal-Free Divergent Difunctionalization of Alkenes Using Alkyl Formates

(2020) Ming Zheng et al.   ACS Catalysis

Alkylation of Allyl/alkenyl Sulfones by Deoxygenation of Alkoxyl Radicals

(2019) Jia-Bin Han et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Redox Strategy for Light-Driven, Out-of-Equilibrium Isomerizations and Application to Catalytic C–C Bond Cleavage Reactions

(2019) Eisuke Ota et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cyanohydrin-Mediated Cyanation of Remote Unactivated C(sp3)–H Bonds

(2019) Min Wang et al.   ORGANIC LETTERS

Generation of Dithianyl and Dioxolanyl Radicals Using Photoredox Catalysis: Application in the Total Synthesis of the Danshenspiroketallactones via Radical Relay Chemistry

(2019) Yifan Deng et al.   ORGANIC LETTERS

Deacylative transformations of ketones via aromatization-promoted C–C bond activation

(2019) Yan Xu et al.   NATURE

Enantioselective Construction of Quaternary All-Carbon Centers via Copper-Catalyzed Arylation of Tertiary Carbon-Centered Radicals

(2019) Lianqian Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoredox-Catalyzed Site-Selective α-C(sp3 )−H Alkylation of Primary Amine Derivatives

(2019) Melissa A. Ashley et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Deoxygenative Borylation of Secondary and Tertiary Alcohols

(2019) Florian Werner Friese et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light Photoredox-Catalyzed and Copper-Promoted Trifluoromethoxylation of Arenediazonium Tetrafluoroborates

(2019) Shaoqiang Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reactive Oxygen Species (ROS)-Based Nanomedicine

(2019) Bowen Yang et al.   CHEMICAL REVIEWS

Visible Light‐Promoted Ring‐Opening Alkynylation, Alkenylation and Allylation of Cyclic Hemiacetals through beta‐Scission of Alkoxy Radicals

(2019) Jiang-Ling Shi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chemical Basis of Reactive Oxygen Species Reactivity and Involvement in Neurodegenerative Diseases

(2019) Fabrice Collin   INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES

Catalytic Ring Expansions of Cyclic Alcohols Enabled by Proton-Coupled Electron Transfer

(2019) Kuo Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site-Selective Functionalization of Pyridinium Derivatives via Visible Light Driven Photocatalysis with Quinolinone

(2019) Inwon Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversing conventional site-selectivity in C(sp3)–H bond activation

(2019) Guoqin Xia et al.   Nature Chemistry

Ligand-Accelerated Iron Photocatalysis Enabling Decarboxylative Alkylation of Heteroarenes

(2019) Zhenlong Li et al.   ORGANIC LETTERS

Selective Late-Stage Oxygenation with Ground-State Oxygen Based on Sulfides by Uranyl Photocatalysis

(2019) Yiming Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Remote‐C(sp3)‐H Arylation and Vinylation of N‐Alkoxypyridinium Salts to δ‐Aryl and δ‐Vinyl Alcohols

(2019) Xu Bao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Dehydroxymethylation of Alcohols Enabled by Cerium Photocatalysis

(2019) Kaining Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Factors Controlling Reactivity in the Hydrogen Atom Transfer and Radical Addition Steps of a Radical Relay Cascade

(2019) Yike Zou et al.   ORGANIC LETTERS

Surgical Cleavage of Unstrained C( sp 3 )−C( sp 3 ) Bonds in General Alcohols for Heteroaryl C−H Alkylation and Acylation

(2019) Yaxin Wang et al.   ADVANCED SYNTHESIS & CATALYSIS

Oxazoline-/Copper-Catalyzed Alkoxyl Radical Generation: Solvent-Switched to Access 3a,3a′-Bisfuroindoline and 3-Alkoxyl Furoindoline

(2019) Hai Ren et al.   ORGANIC LETTERS

Bisphosphonium salt: an effective photocatalyst for the intramolecular hydroalkoxylation of olefins

(2019) Hao Cheng et al.   Science Bulletin

Redox-neutral photocatalytic strategy for selective C–C bond cleavage of lignin and lignin models via PCET process

(2019) Yinling Wang et al.   Science Bulletin

Merging Photocatalysis with Electrochemistry: The Dawn of a new Alliance in Organic Synthesis

(2019) Luca Capaldo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoinduced Deoxygenative Borylations of Aliphatic Alcohols

(2019) Jingjing Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Anti-Markovnikov Hydroamination of Unactivated Alkenes with Primary Alkyl Amines

(2019) David C. Miller et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site-specific allylic C–H bond functionalization with a copper-bound N-centred radical

(2019) Jiayuan Li et al.   NATURE

Site-Tunable Csp3–H Bonds Functionalization by Visible-Light-Induced Radical Translocation of N-Alkoxyphthalimides

(2019) Chuanyong Wang et al.   ORGANIC LETTERS

Site-Selective C–H Acylation of Pyridinium Derivatives by Photoredox Catalysis

(2019) Sungwoo Jung et al.   ACS Catalysis

Synthetic Photoelectrochemistry

(2019) Joshua Philip Barham et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Light-Driven Depolymerization of Native Lignin Enabled by Proton-Coupled Electron Transfer

(2019) Suong T. Nguyen et al.   ACS Catalysis

Selective C-C Bond Scission of Ketones via Visible-Light-Mediated Cerium Catalysis

(2019) Yilin Chen et al.   Chem

Chiral Piperidines from Acyclic Amines via Enantioselective, Radical-Mediated δ C–H Cyanation

(2019) Zuxiao Zhang et al.   Chem

The Fate of the Peroxyl Radical in Autoxidation: How Does Polymer Degradation Really Occur?

(2018) Leesa M. Smith et al.   ACCOUNTS OF CHEMICAL RESEARCH

Photocatalyzed ortho -Alkylation of Pyridine N -Oxides through Alkene Cleavage

(2018) Wang Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light-Accelerated Copper(II)-Catalyzed Regio- and Chemoselective Oxo-Azidation of Vinyl Arenes

(2018) Asik Hossain et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic C−H Trifluoromethoxylation of Arenes and Heteroarenes

(2018) Weijia Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Radical Trifluoromethoxylation of Arenes Triggered by a Visible-Light-Mediated N-O Redox Fragmentation

(2018) Antonio Togni et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Emergence of Uranium as a Distinct Metal Center for Building Intrinsic X-ray Scintillators

(2018) Yaxing Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tertiary-Alcohol-Directed Functionalization of Remote C(sp3 )−H Bonds by Sequential Hydrogen Atom and Heteroaryl Migrations

(2018) Xinxin Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-light-induced alkoxyl radical generation for inert chemical bond cleavage/functionalization

(2018) Kunfang Jia et al.   CHEMICAL COMMUNICATIONS

Photocatalytic acylarylation of unactivated alkenes with diaryliodonium salts toward indanones and related compounds

(2018) Yongtao Chen et al.   CHEMICAL COMMUNICATIONS

Recent Advances in Ring-Opening Functionalization of Cycloalkanols by C-C σ-Bond Cleavage

(2018) Xinxin Wu et al.   CHEMICAL RECORD

Selective P−C(sp3 ) Bond Cleavage and Radical Alkynylation of α-Phosphorus Alcohols by Photoredox Catalysis

(2018) Kunfang Jia et al.   CHEMISTRY-A EUROPEAN JOURNAL

Quantitative wave function analysis for excited states of transition metal complexes

(2018) Sebastian Mai et al.   COORDINATION CHEMISTRY REVIEWS

Intermolecular Anti-Markovnikov Hydroamination of Unactivated Alkenes with Sulfonamides Enabled by Proton-Coupled Electron Transfer

(2018) Qilei Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

δ-Selective Functionalization of Alkanols Enabled by Visible-Light-Induced Ligand-to-Metal Charge Transfer

(2018) Anhua Hu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-Light-Enhanced Ring Opening of Cycloalkanols Enabled by Brønsted Base-Tethered Acyloxy Radical Induced Hydrogen Atom Transfer-Electron Transfer

(2018) Rong Zhao et al.   ORGANIC LETTERS

Remote C–H Functionalization via Selective Hydrogen Atom Transfer

(2018) David Nagib et al.   SYNTHESIS-STUTTGART

Photocatalytic alkoxy radical-mediated transformations

(2018) Jing-Jing Guo et al.   TETRAHEDRON LETTERS

Visible light-promoted ring-opening functionalization of unstrained cycloalkanols via inert C–C bond scission

(2018) Dongping Wang et al.   Chemical Science

Silver-catalyzed remote Csp3-H functionalization of aliphatic alcohols

(2018) Yuchao Zhu et al.   Nature Communications

Recent Insights on Hydrogen Atom Transfer in the Inhibition of Hydrocarbon Autoxidation

(2018) Jia-Fei Poon et al.   ACCOUNTS OF CHEMICAL RESEARCH

Copper-Catalyzed Radical Relay for Asymmetric Radical Transformations

(2018) Fei Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Alkoxyl Radicals Generated under Photoredox Catalysis: A Strategy for anti-Markovnikov Alkoxylation Reactions

(2018) Anne-Laure Barthelemy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox-Active Reagents for Photocatalytic Generation of the OCF3 Radical and (Hetero)Aryl C−H Trifluoromethoxylation

(2018) Weijia Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light-Mediated Ring-Opening Strategy for the Regiospecific Allylation/Formylation of Cycloalkanols

(2018) Junlei Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Tandem Catalysis: Transforming Alcohols to Alkenes by Oxidative Dehydroxymethylation

(2018) Xuesong Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective functionalization of methane, ethane, and higher alkanes by cerium photocatalysis

(2018) Anhua Hu et al.   SCIENCE

Copper-catalyzed methylative difunctionalization of alkenes

(2018) Xu Bao et al.   Nature Communications

Metal-free alcohol-directed regioselective heteroarylation of remote unactivated C(sp3)–H bonds

(2018) Xinxin Wu et al.   Nature Communications

Visible-Light-Induced Pyridylation of Remote C(sp3 )−H Bonds by Radical Translocation of N-Alkoxypyridinium Salts

(2018) Inwon Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dual Photoredox/Copper Catalysis for the Remote C(sp3 )−H Functionalization of Alcohols and Alkyl Halides by N -Alkoxypyridinium Salts

(2018) Xu Bao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light-Driven, Copper-Catalyzed Decarboxylative C(sp3 )−H Alkylation of Glycine and Peptides

(2018) Chao Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Toolbox Approach To Construct Broadly Applicable Metal-Free Catalysts for Photoredox Chemistry: Deliberate Tuning of Redox Potentials and Importance of Halogens in Donor–Acceptor Cyanoarenes

(2018) Elisabeth Speckmeier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cerium-Catalyzed Formal Cycloaddition of Cycloalkanols with Alkenes through Dual Photoexcitation

(2018) Anhua Hu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

What Are the Radical Intermediates in Oxidative N-Heterocyclic Carbene Organocatalysis?

(2018) Vianney Regnier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Zn-Mediated Fragmentation of Tertiary Alkyl Oxalates Enabling Formation of Alkylated and Arylated Quaternary Carbon Centers

(2018) Yang Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoinduced Ligand-to-Metal Charge Transfer Enables Photocatalyst-Independent Light-Gated Activation of Co(II)

(2018) Benjamin D. Ravetz et al.   ACS Catalysis

Generation of Phosphoranyl Radicals via Photoredox Catalysis Enables Voltage–Independent Activation of Strong C–O Bonds

(2018) Erin E. Stache et al.   ACS Catalysis

Directed γ-C(sp3)–H Alkylation of Carboxylic Acid Derivatives through Visible Light Photoredox Catalysis

(2017) Dian-Feng Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective sp3 C–H alkylation via polarity-match-based cross-coupling

(2017) Chip Le et al.   NATURE

Silver-catalyzed C2-selective direct alkylation of heteroarenes with tertiary cycloalkanols

(2017) Shi-Chao Lu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Direct Phosphonation of Quinolinones and Coumarins Driven by the Photochemical Activity of Substrates and Products

(2017) Inwon Kim et al.   ORGANIC LETTERS

Catalytic intermolecular hydroaminations of unactivated olefins with secondary alkyl amines

(2017) Andrew J. Musacchio et al.   SCIENCE

“Cut and Sew” Transformations via Transition-Metal-Catalyzed Carbon–Carbon Bond Activation

(2017) Peng-hao Chen et al.   ACS Catalysis

The merger of transition metal and photocatalysis

(2017) Jack Twilton et al.   Nature Reviews Chemistry

Synthetic Applications of Proton-Coupled Electron Transfer

(2016) Emily C. Gentry et al.   ACCOUNTS OF CHEMICAL RESEARCH

Role of Double Hydrogen Atom Transfer Reactions in Atmospheric Chemistry

(2016) Manoj Kumar et al.   ACCOUNTS OF CHEMICAL RESEARCH

C−C Bond-Forming Strategy by Manganese-Catalyzed Oxidative Ring-Opening Cyanation and Ethynylation of Cyclobutanol Derivatives

(2016) Rongguo Ren et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Csp3 −H Functionalization under Photoredox Conditions by Radical Translocation and Stereocontrolled Alkene Addition

(2016) Chuanyong Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photocatalytic C−C Bond Cleavage and Amination of Cycloalkanols by Cerium(III) Chloride Complex

(2016) Jing-Jing Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Manganese-catalyzed regiospecific sp3 C–S bond formation through C–C bond cleavage of cyclobutanols

(2016) Rongguo Ren et al.   CHEMICAL COMMUNICATIONS

Organic Photoredox Catalysis

(2016) Nathan A. Romero et al.   CHEMICAL REVIEWS

New amination strategies based on nitrogen-centered radical chemistry

(2016) Tao Xiong et al.   CHEMICAL SOCIETY REVIEWS

Manganese-Promoted Ring-Opening Hydrazination of Cyclobutanols: Synthesis of Alkyl Hydrazines

(2016) Dongping Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Visible-Light-Promoted Activation of Unactivated C(sp3)–H Bonds and Their Selective Trifluoromethylthiolation

(2016) Satobhisha Mukherjee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Ring-Opening of Cyclic Alcohols Enabled by PCET Activation of Strong O–H Bonds

(2016) Hatice G. Yayla et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free, Visible Light-Photocatalyzed Synthesis of Benzo[b]phosphole Oxides: Synthetic and Mechanistic Investigations

(2016) Valentin Quint et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alcohols as Latent Coupling Fragments for Metallaphotoredox Catalysis: sp3–sp2 Cross-Coupling of Oxalates with Aryl Halides

(2016) Xiaheng Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct C(sp3)–H Cross Coupling Enabled by Catalytic Generation of Chlorine Radicals

(2016) Benjamin J. Shields et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Potential of Metal-Catalyzed C–C Single Bond Cleavage for Organic Synthesis

(2016) Masahiro Murakami et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-Light-Induced Alkoxyl Radical Generation Enables Selective C(sp3)–C(sp3) Bond Cleavage and Functionalizations

(2016) Kunfang Jia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic activation of carbon–carbon bonds in cyclopentanones

(2016) Ying Xia et al.   NATURE

Amide-directed photoredox-catalysed C–C bond formation at unactivated sp3 C–H bonds

(2016) John C. K. Chu et al.   NATURE

Catalytic alkylation of remote C–H bonds enabled by proton-coupled electron transfer

(2016) Gilbert J. Choi et al.   NATURE

Regioselective Synthesis of Carbonyl-Containing Alkyl Chlorides via Silver-Catalyzed Ring-Opening Chlorination of Cycloalkanols

(2016) Feng-Qing Huang et al.   ORGANIC LETTERS

Manganese-catalyzed ring-opening chlorination of cyclobutanols: regiospecific synthesis of γ-chloroketones

(2016) Leitao Huan et al.   Organic Chemistry Frontiers

Regiospecific synthesis of distally chlorinated ketones via C–C bond cleavage of cycloalkanols

(2016) Xuefeng Fan et al.   Organic Chemistry Frontiers

Energy Cascades, Excited State Dynamics, and Photochemistry in Cob(III)alamins and Ferric Porphyrins

(2015) Aaron S. Rury et al.   ACCOUNTS OF CHEMICAL RESEARCH

Tuning Reactivity and Selectivity in Hydrogen Atom Transfer from Aliphatic C–H Bonds to Alkoxyl Radicals: Role of Structural and Medium Effects

(2015) Michela Salamone et al.   ACCOUNTS OF CHEMICAL RESEARCH

Generation of Alkoxyl Radicals by Photoredox Catalysis Enables Selective C(sp3 )−H Functionalization under Mild Reaction Conditions

(2015) Jing Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Manganese-Catalyzed Oxidative Azidation of Cyclobutanols: Regiospecific Synthesis of Alkyl Azides by CC Bond Cleavage

(2015) Rongguo Ren et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ring-opening Fluorination of Cyclobutanols and Cyclopropanols Catalyzed by Silver

(2015) Naoki Ishida et al.   CHEMISTRY LETTERS

Silver-Catalyzed Ring-Opening Strategy for the Synthesis of β- and γ-Fluorinated Ketones

(2015) Huijun Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling

(2015) Christopher C. Nawrat et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Alkene Carboaminations Enabled by Oxidative Proton-Coupled Electron Transfer

(2015) Gilbert J. Choi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A facile and regioselective synthesis of 1-tetralones via silver-catalyzed ring expansion

(2015) Jiajia Yu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Iron- or silver-catalyzed oxidative fluorination of cyclopropanols for the synthesis of β-fluoroketones

(2015) Shichao Ren et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

O-H hydrogen bonding promotes H-atom transfer from   C-H bonds for C-alkylation of alcohols

(2015) J. L. Jeffrey et al.   SCIENCE

Photocatalytic Generation of N-Centered Hydrazonyl Radicals:  A Strategy for Hydroamination of β,γ-Unsaturated Hydrazones

(2014) Xiao-Qiang Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Late-Stage Functionalization of Biologically Active Heterocycles Through Photoredox Catalysis

(2014) Daniel A. DiRocco et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Advances in Transition-Metal-Catalyzed Functionalization of Unstrained Carbon–Carbon Bonds

(2014) Feng Chen et al.   CHEMICAL REVIEWS

sp3 C–H oxidation by remote H-radical shift with oxygen- and nitrogen-radicals: a recent update

(2014) Shunsuke Chiba et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Reaction Pathways of Alkoxyl Radicals. The Role of Solvent Effects on C–C Bond Fragmentation and Hydrogen Atom Transfer Reactions

(2014) Massimo Bietti et al.   SYNLETT

An Air-Stable Oxyallyl Radical Cation

(2013) David Martin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

p-Xylene Oxidation to Terephthalic Acid: A Literature Review Oriented toward Process Optimization and Development

(2013) Rogério A. F. Tomás et al.   CHEMICAL REVIEWS

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

(2013) Christopher K. Prier et al.   CHEMICAL REVIEWS

Reductive Deoxygenation of Alcohols: Catalytic Methods Beyond Barton-McCombie Deoxygenation

(2013) Josef M. Herrmann et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

A Perspective on Free Radical Autoxidation: The Physical Organic Chemistry of Polyunsaturated Fatty Acid and Sterol Peroxidation

(2013) Ned A. Porter   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Photoredox Catalysis Enabled by Proton-Coupled Electron Transfer: Development of an Asymmetric Aza-Pinacol Cyclization

(2013) Lydia J. Rono et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Ketyl-Olefin Cyclizations Enabled by Proton-Coupled Electron Transfer

(2013) Kyle T. Tarantino et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

[Ru(bpy)3]2+* and other remarkable metal-to-ligand charge transfer (MLCT) excited states

(2013) David W. Thompson et al.   PURE AND APPLIED CHEMISTRY

Proton-Coupled Electron Transfer

(2012) David R. Weinberg et al.   CHEMICAL REVIEWS

Using combinations of oxidants and bases as PCET reactants: thermochemical and practical considerations

(2012) Christopher R. Waidmann et al.   Energy & Environmental Science

Reactions of the Cumyloxyl and Benzyloxyl Radicals with Strong Hydrogen Bond Acceptors. Large Enhancements in Hydrogen Abstraction Reactivity Determined by Substrate/Radical Hydrogen Bonding

(2012) Michela Salamone et al.   JOURNAL OF ORGANIC CHEMISTRY

Hydrogen Abstraction from Cyclic Amines by the Cumyloxyl and Benzyloxyl Radicals. The Role of Stereoelectronic Effects and of Substrate/Radical Hydrogen Bonding

(2012) Michela Salamone et al.   JOURNAL OF ORGANIC CHEMISTRY

Transition Metal Photoredox Catalysis of Radical Thiol-Ene Reactions

(2012) Elizabeth L. Tyson et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct Catalytic Anti-Markovnikov Hydroetherification of Alkenols

(2012) David S. Hamilton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxygenation and chlorination of aromatic hydrocarbons with hydrochloric acid photosensitized by 9-mesityl-10-methylacridinium under visible light irradiation

(2012) Kei Ohkubo et al.   RESEARCH ON CHEMICAL INTERMEDIATES

The Isomerization of Methoxy Radical: Intramolecular Hydrogen Atom Transfer Mediated through Acid Catalysis

(2011) Robert J. Buszek et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogen Atom Abstraction Selectivity in the Reactions of Alkylamines with the Benzyloxyl and Cumyloxyl Radicals. The Importance of Structure and of Substrate Radical Hydrogen Bonding

(2011) Michela Salamone et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Mediated Trifluoromethoxylation of Aryl Stannanes and Arylboronic Acids

(2011) Chenghong Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mn(III)-Mediated Formal [3+3]-Annulation of Vinyl Azides and Cyclopropanols: A Divergent Synthesis of Azaheterocycles

(2011) Yi-Feng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Understanding Kinetic Solvent Effects on Hydrogen Abstraction Reactions from Carbon by the Cumyloxyl Radical

(2011) Massimo Bietti et al.   ORGANIC LETTERS

Photoinduced Electron-Transfer-Promoted Redox Fragmentation ofN-Alkoxyphthalimides

(2011) Maria Zlotorzynska et al.   ORGANIC LETTERS

Thermochemistry of Proton-Coupled Electron Transfer Reagents and its Implications

(2010) Jeffrey J. Warren et al.   CHEMICAL REVIEWS

Estimation of standard reduction potentials of alkyl radicals involved in atom transfer radical polymerization

(2010) Nicola Bortolamei et al.   ELECTROCHIMICA ACTA

Differential Polarization of Spin and Charge Density in Substituted Phenoxy Radicals

(2009) Richard J. Fehir et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Electron-Transfer Photoredox Catalysis: Development of a Tin-Free Reductive Dehalogenation Reaction

(2009) Jagan M. R. Narayanam et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Visible Light Photocatalysis of [2+2] Enone Cycloadditions

(2008) Michael A. Ischay et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Merging Photoredox Catalysis with Organocatalysis: The Direct Asymmetric Alkylation of Aldehydes

(2008) D. A. Nicewicz et al.   SCIENCE