Fundamental understanding and practical challenges of lithium-rich oxide cathode materials: Layered and disordered-rocksalt structure

A High‐Performance Li–Mn–O Li‐rich Cathode Material with Rhombohedral Symmetry via Intralayer Li/Mn Disordering

(2020) Jin Song et al.   ADVANCED MATERIALS

Voltage decay and redox asymmetry mitigation by reversible cation migration in lithium-rich layered oxide electrodes

(2020) Donggun Eum et al.   NATURE MATERIALS

Structural evolution at the oxidative and reductive limits in the first electrochemical cycle of Li1.2Ni0.13Mn0.54Co0.13O2

(2020) Wei Yin et al.   Nature Communications

Synthesis and Electrochemical Properties of Bi2MoO6/Carbon Anode for Lithium-Ion Battery Application

(2020) Tingting Zhang et al.   Materials

A Long Cycle-Life High-Voltage Spinel Lithium-Ion Battery Electrode Achieved by Site-Selective Doping

(2020) Gemeng Liang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Progress in electrolytes for beyond-lithium-ion batteries

(2020) Juyan Zhang et al.   JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY

A reflection on lithium-ion battery cathode chemistry

(2020) Arumugam Manthiram   Nature Communications

Ultrahigh power and energy density in partially ordered lithium-ion cathode materials

(2020) Huiwen Ji et al.   Nature Energy

Mn4+-substituted Li-rich Li1.2Mn0.43+Mnx4+Ti0.4-xO2 materials with high energy density

(2020) Shiyao Zheng et al.   ACS Applied Materials & Interfaces

Carbon-coated cation-disordered rocksalt-type transition metal oxide composites for high energy Li-ion batteries

(2020) Zhenlu Yu et al.   CERAMICS INTERNATIONAL

Interfacial Degradation and Optimization of Li‐rich Cathode Materials

(2020) Yuefeng Su et al.   CHINESE JOURNAL OF CHEMISTRY

A disordered rock salt anode for fast-charging lithium-ion batteries

(2020) Haodong Liu et al.   NATURE

Cation-disordered rocksalt-type high-entropy cathodes for Li-ion batteries

(2020) Zhengyan Lun et al.   NATURE MATERIALS

First-cycle voltage hysteresis in Li-rich 3d cathodes associated with molecular O2 trapped in the bulk

(2020) Robert A. House et al.   Nature Energy

Redox Chemistry and the Role of Trapped Molecular O2 in Li-Rich Disordered Rocksalt Oxyfluoride Cathodes

(2020) Ryan Sharpe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enhanced high-temperature performance of Li-rich layered oxide via surface heterophase coating

(2020) Yuefeng Su et al.   Journal of Energy Chemistry

Enhanced Cycling Stability of Cation Disordered Rock-Salt Li1.2Ti0.4Mn0.4O2 Material by Surface Modification With Al2O3

(2019) Baojun Huang et al.   Frontiers in Chemistry

Hidden structural and chemical order controls lithium transport in cation-disordered oxides for rechargeable batteries

(2019) Huiwen Ji et al.   Nature Communications

Metal–oxygen decoordination stabilizes anion redox in Li-rich oxides

(2019) Jihyun Hong et al.   NATURE MATERIALS

Computational Investigation and Experimental Realization of Disordered High-Capacity Li-Ion Cathodes Based on Ni Redox

(2019) Huiwen Ji et al.   CHEMISTRY OF MATERIALS

Stabilizing the Oxygen Lattice and Reversible Oxygen Redox Chemistry through Structural Dimensionality in Lithium-Rich Cathode Oxides

(2019) Enyue Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Evolution of Local Structural Ordering and Chemical Distribution upon Delithiation of a Rock Salt-Structured Li1.3 Ta0.3 Mn0.4 O2 Cathode

(2019) Wang Hay Kan et al.   ADVANCED FUNCTIONAL MATERIALS

Chemical, Structural, and Electronic Aspects of Formation and Degradation Behavior on Different Length Scales of Ni‐Rich NCM and Li‐Rich HE‐NCM Cathode Materials in Li‐Ion Batteries

(2019) Lea de Biasi et al.   ADVANCED MATERIALS

Advances in the Cathode Materials for Making a Breakthrough in the Li Rechargeable Batteries

(2019) Wontae Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Injection of oxygen vacancies in the bulk lattice of layered cathodes

(2019) Pengfei Yan et al.   Nature Nanotechnology

Approaching high-performance potassium-ion batteries via advanced design strategies and engineering

(2019) Wenchao Zhang et al.   Science Advances

Lithium Deficiencies Engineering in Li-Rich Layered Oxide Li1.098Mn0.533Ni0.113Co0.138O2 for High-Stability Cathode

(2019) Pengfei Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Charge Transfer Band Gap as an Indicator of Hysteresis in Li-Disordered Rock Salt Cathodes for Li-Ion Batteries

(2019) Quentin Jacquet et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Understanding Performance Degradation in Cation‐Disordered Rock‐Salt Oxide Cathodes

(2019) Dongchang Chen et al.   Advanced Energy Materials

Li–Ti Cation Mixing Enhanced Structural and Performance Stability of Li‐Rich Layered Oxide

(2019) Shuai Liu et al.   Advanced Energy Materials

Insight of a Phase Compatible Surface Coating for Long‐Durable Li‐Rich Layered Oxide Cathode

(2019) Sijiang Hu et al.   Advanced Energy Materials

Structure solution and refinement of metal-ion battery cathode materials using electron diffraction tomography

(2019) Joke Hadermann et al.   Acta Crystallographica Section B-Structural Science Crystal Engineering and Materials

Manganese oxidation as the origin of the anomalous capacity of Mn-containing Li-excess cathode materials

(2019) Maxwell D. Radin et al.   Nature Energy

Understanding Rechargeable Battery Function Using In Operando Neutron Powder Diffraction

(2019) Gemeng Liang et al.   ADVANCED MATERIALS

Enhanced electrochemical performances of layered-spinel heterostructured lithium-rich Li1.2Ni0.13Co0.13Mn0.54O2 cathode materials

(2019) Lun Ku et al.   CHEMICAL ENGINEERING JOURNAL

Birnessite MnO2 decorated MWCNTs composite as a nonenzymatic hydrogen peroxide sensor

(2019) Muthu Dinesh et al.   CHEMICAL PHYSICS LETTERS

Fabrication of manganese oxide@nitrogen doped graphene oxide/polypyrrole (MnO2@NGO/PPy) hybrid composite electrodes for energy storage devices

(2019) Sivalingam Ramesh et al.   Journal of Materials Research and Technology-JMR&T

A facile strategy to improve the cycle stability of 4.45 V LiCoO2 cathode in gel electrolyte system via succinonitrile additive under elevated temperature

(2019) Ning Xu et al.   SOLID STATE IONICS

Structural insights into the formation and voltage degradation of lithium- and manganese-rich layered oxides

(2019) Weibo Hua et al.   Nature Communications

Unraveling the Voltage Decay Phenomenon in Li‐Rich Layered Oxide Cathode of No Oxygen Activity

(2019) Ning Li et al.   Advanced Energy Materials

Revealing Grain-Boundary-Induced Degradation Mechanisms in Li-Rich Cathode Materials

(2019) Soroosh Sharifi-Asl et al.   NANO LETTERS

Superstructure control of first-cycle voltage hysteresis in oxygen-redox cathodes

(2019) Robert A. House et al.   NATURE

Local electronic structure modulation enhances operating voltage in Li-rich cathodes

(2019) Gang Sun et al.   Nano Energy

Insight into the improved cycling stability of sphere-nanorod-like micro-nanostructured high voltage spinel cathode for lithium-ion batteries

(2019) Haiping Liu et al.   Nano Energy

Gradient Li-rich oxide cathode particles immunized against oxygen release by a molten salt treatment

(2019) Zhi Zhu et al.   Nature Energy

Renovating the electrode-electrolyte interphase for layered lithium- & manganese-rich oxides

(2019) Feng Wu et al.   Energy Storage Materials

Unraveling the Rapid Performance Decay of Layered High-Energy Cathodes: From Nanoscale Degradation to Drastic Bulk Evolution

(2018) Hanshuo Liu et al.   ACS Nano

Horizons for Li-Ion Batteries Relevant to Electro-Mobility: High-Specific-Energy Cathodes and Chemically Active Separators

(2018) Francis Amalraj Susai et al.   ADVANCED MATERIALS

Origin of High Capacity and Poor Cycling Stability of Li-Rich Layered Oxides: A Long-Duration in Situ Synchrotron Powder Diffraction Study

(2018) Karin Kleiner et al.   CHEMISTRY OF MATERIALS

Unravelling Solid-State Redox Chemistry in Li1.3Nb0.3Mn0.4O2 Single-Crystal Cathode Material

(2018) Wang Hay Kan et al.   CHEMISTRY OF MATERIALS

Reversible anionic redox activity in Na3RuO4 cathodes: a prototype Na-rich layered oxide

(2018) Yu Qiao et al.   Energy & Environmental Science

Design principles for high transition metal capacity in disordered rocksalt Li-ion cathodes

(2018) Daniil A. Kitchaev et al.   Energy & Environmental Science

Fluorine doping and Al 2 O 3 coating Co-modified Li[Li 0.20 Ni 0.133 Co 0.133 Mn 0.534 ]O 2 as high performance cathode material for lithium-ion batteries

(2018) Siyu Liu et al.   JOURNAL OF ALLOYS AND COMPOUNDS

Reversible Mn2+/Mn4+ double redox in lithium-excess cathode materials

(2018) Jinhyuk Lee et al.   NATURE

Elucidating anionic oxygen activity in lithium-rich layered oxides

(2018) Jing Xu et al.   Nature Communications

Designing principle for Ni-rich cathode materials with high energy density for practical applications

(2018) Yu Xia et al.   Nano Energy

Fundamental understanding and practical challenges of anionic redox activity in Li-ion batteries

(2018) Gaurav Assat et al.   Nature Energy

Nucleation of dislocations and their dynamics in layered oxide cathode materials during battery charging

(2018) A. Singer et al.   Nature Energy

Evolution of redox couples in Li- and Mn-rich cathode materials and mitigation of voltage fade by reducing oxygen release

(2018) Enyuan Hu et al.   Nature Energy

Fluorine-Doped Carbon Surface Modification of Li-Rich Layered Oxide Composite Cathodes for High Performance Lithium-Ion Batteries

(2018) Fenghua Zheng et al.   ACS Sustainable Chemistry & Engineering

Material design of high-capacity Li-rich layered-oxide electrodes: Li2MnO3 and beyond

(2017) Soo Kim et al.   Energy & Environmental Science

Requirements for reversible extra-capacity in Li-rich layered oxides for Li-ion batteries

(2017) Y. Xie et al.   Energy & Environmental Science

Simulation of First-Charge Oxygen-Dimerization and Mn-Migration in Li-Rich Layered Oxides xLi2MnO3·(1 – x)LiMO2 and Implications for Voltage Fade

(2017) Roy Benedek et al.   Journal of Physical Chemistry C

Exploring Oxygen Activity in the High Energy P2-Type Na0.78Ni0.23Mn0.69O2 Cathode Material for Na-Ion Batteries

(2017) Chuze Ma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Observation of partial reduction of manganese in the lithium rich layered oxides, 0.4Li2MnO3–0.6LiNi1/3Co1/3Mn1/3O2, during the first charge

(2017) Hyung Cheoul Shim et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Mitigating oxygen loss to improve the cycling performance of high capacity cation-disordered cathode materials

(2017) Jinhyuk Lee et al.   Nature Communications

Coupling between oxygen redox and cation migration explains unusual electrochemistry in lithium-rich layered oxides

(2017) William E. Gent et al.   Nature Communications

Fundamental interplay between anionic/cationic redox governing the kinetics and thermodynamics of lithium-rich cathodes

(2017) Gaurav Assat et al.   Nature Communications

Fluorination of Lithium-Excess Transition Metal Oxide Cathode Materials

(2017) William D. Richards et al.   Advanced Energy Materials

Review on Challenges and Recent Advances in the Electrochemical Performance of High Capacity Li- and Mn-Rich Cathode Materials for Li-Ion Batteries

(2017) Prasant Kumar Nayak et al.   Advanced Energy Materials

Highly stable Li 1.2 Mn 0.54 Co 0.13 Ni 0.13 O 2 enabled by novel atomic layer deposited AlPO 4 coating

(2017) Biwei Xiao et al.   Nano Energy

Reversible Three-Electron Redox Reaction of Mo3+/Mo6+ for Rechargeable Lithium Batteries

(2017) Satoshi Hoshino et al.   ACS Energy Letters

Mitigating Voltage Decay of Li-Rich Cathode Material via Increasing Ni Content for Lithium-Ion Batteries

(2016) Ji-Lei Shi et al.   ACS Applied Materials & Interfaces

Understanding the Effect of Cation Disorder on the Voltage Profile of Lithium Transition-Metal Oxides

(2016) Aziz Abdellahi et al.   CHEMISTRY OF MATERIALS

The intriguing question of anionic redox in high-energy density cathodes for Li-ion batteries

(2016) M. Saubanère et al.   Energy & Environmental Science

Performance and design considerations for lithium excess layered oxide positive electrode materials for lithium ion batteries

(2016) Sunny Hy et al.   Energy & Environmental Science

Electrochemical behaviours of SiO 2 -coated LiNi 0.8 Co 0.1 Mn 0.1 O 2 cathode materials by a novel modification method

(2016) Longwei Liang et al.   JOURNAL OF ALLOYS AND COMPOUNDS

Key strategies for enhancing the cycling stability and rate capacity of LiNi0.5Mn1.5O4 as high-voltage cathode materials for high power lithium-ion batteries

(2016) Ting-Feng Yi et al.   JOURNAL OF POWER SOURCES

Anion Redox Chemistry in the Cobalt Free 3d Transition Metal Oxide Intercalation Electrode Li[Li0.2Ni0.2Mn0.6]O2

(2016) Kun Luo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nanostructured cation disordered Li2FeTiO4/graphene composite as high capacity cathode for lithium-ion batteries

(2016) Meng Yang et al.   MATERIALS TECHNOLOGY

Explore the Effects of Microstructural Defects on Voltage Fade of Li- and Mn-Rich Cathodes

(2016) Enyuan Hu et al.   NANO LETTERS

The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials

(2016) Dong-Hwa Seo et al.   Nature Chemistry

Charge-compensation in 3d-transition-metal-oxide intercalation cathodes through the generation of localized electron holes on oxygen

(2016) Kun Luo et al.   Nature Chemistry

Identifying the redox activity of cation-disordered Li–Fe–V–Ti oxide cathodes for Li-ion batteries

(2016) Ruiyong Chen et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Origin of stabilization and destabilization in solid-state redox reaction of oxide ions for lithium-ion batteries

(2016) Naoaki Yabuuchi et al.   Nature Communications

Nickel-Rich Layered Lithium Transition-Metal Oxide for High-Energy Lithium-Ion Batteries

(2015) Wen Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Characterization of Disordered Li(1+x)Ti2xFe(1–3x)O2 as Positive Electrode Materials in Li-Ion Batteries Using Percolation Theory

(2015) Stephen L. Glazier et al.   CHEMISTRY OF MATERIALS

Structural and Chemical Evolution of Li- and Mn-Rich Layered Cathode Material

(2015) Jianming Zheng et al.   CHEMISTRY OF MATERIALS

A new class of high capacity cation-disordered oxides for rechargeable lithium batteries: Li–Ni–Ti–Mo oxides

(2015) Jinhyuk Lee et al.   Energy & Environmental Science

Understanding the Roles of Anionic Redox and Oxygen Release during Electrochemical Cycling of Lithium-Rich Layered Li4FeSbO6

(2015) Eric McCalla et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Re-entrant Lithium Local Environments and Defect Driven Electrochemistry of Li- and Mn-Rich Li-Ion Battery Cathodes

(2015) Fulya Dogan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A new active Li–Mn–O compound for high energy density Li-ion batteries

(2015) M. Freire et al.   NATURE MATERIALS

High-capacity electrode materials for rechargeable lithium batteries: Li3NbO4-based system with cation-disordered rocksalt structure

(2015) Naoaki Yabuuchi et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Visualization of O-O peroxo-like dimers in high-capacity layered oxides for Li-ion batteries

(2015) E. McCalla et al.   SCIENCE

Unravelling structural ambiguities in lithium- and manganese-rich transition metal oxides

(2015) Alpesh Khushalchand Shukla et al.   Nature Communications

Electron paramagnetic resonance imaging for real-time monitoring of Li-ion batteries

(2015) M. Sathiya et al.   Nature Communications

Visualizing nanoscale 3D compositional fluctuation of lithium in advanced lithium-ion battery cathodes

(2015) A. Devaraj et al.   Nature Communications

On the Localized Nature of the Structural Transformations of Li2MnO3Following Electrochemical Cycling

(2015) Patrick J. Phillips et al.   Advanced Energy Materials

Nickel-Rich and Lithium-Rich Layered Oxide Cathodes: Progress and Perspectives

(2015) Arumugam Manthiram et al.   Advanced Energy Materials

Design of surface protective layer of LiF/FeF 3 nanoparticles in Li-rich cathode for high-capacity Li-ion batteries

(2015) Taolin Zhao et al.   Nano Energy

Unraveling the Voltage-Fade Mechanism in High-Energy-Density Lithium-Ion Batteries: Origin of the Tetrahedral Cations for Spinel Conversion

(2014) Debasish Mohanty et al.   CHEMISTRY OF MATERIALS

Functioning Mechanism of AlF3 Coating on the Li- and Mn-Rich Cathode Materials

(2014) Jianming Zheng et al.   CHEMISTRY OF MATERIALS

Insight into the Atomic Structure of Cycled Lithium-Rich Layered Oxide Li1.20Mn0.54Co0.13Ni0.13O2 Using HAADF STEM and Electron Nanodiffraction

(2014) Cécile Genevois et al.   Journal of Physical Chemistry C

High Performance LiMn2O4 Cathode Materials Grown with Epitaxial Layered Nanostructure for Li-Ion Batteries

(2014) Min-Joon Lee et al.   NANO LETTERS

Origin of voltage decay in high-capacity layered oxide electrodes

(2014) M. Sathiya et al.   NATURE MATERIALS

Uncovering the roles of oxygen vacancies in cation migration in lithium excess layered oxides

(2014) Danna Qian et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Unlocking the Potential of Cation-Disordered Oxides for Rechargeable Lithium Batteries

(2014) J. Lee et al.   SCIENCE

Tuning charge–discharge induced unit cell breathing in layer-structured cathode materials for lithium-ion batteries

(2014) Yong-Ning Zhou et al.   Nature Communications

The Configurational Space of Rocksalt-Type Oxides for High-Capacity Lithium Battery Electrodes

(2014) Alexander Urban et al.   Advanced Energy Materials

Li4NiTeO6 as a positive electrode for Li-ion batteries

(2013) M. Sathiya et al.   CHEMICAL COMMUNICATIONS

First Evidence of Manganese–Nickel Segregation and Densification upon Cycling in Li-Rich Layered Oxides for Lithium Batteries

(2013) Adrien Boulineau et al.   NANO LETTERS

Reversible anionic redox chemistry in high-capacity layered-oxide electrodes

(2013) M. Sathiya et al.   NATURE MATERIALS

Transport and electrochemical properties of high potential tavorite LiVPO4F

(2013) P.F. Xiao et al.   SOLID STATE IONICS

Structural Changes in Li2MnO3Cathode Material for Li-Ion Batteries

(2013) Jatinkumar Rana et al.   Advanced Energy Materials

Understanding Li Diffusion in Li-Intercalation Compounds

(2012) Anton Van der Ven et al.   ACCOUNTS OF CHEMICAL RESEARCH

Formation of the Spinel Phase in the Layered Composite Cathode Used in Li-Ion Batteries

(2012) Meng Gu et al.   ACS Nano

Li1.20Mn0.54Co0.13Ni0.13O2 with Different Particle Sizes as Attractive Positive Electrode Materials for Lithium-Ion Batteries: Insights into Their Structure

(2012) Hideyuki Koga et al.   Journal of Physical Chemistry C

Understanding Structural Defects in Lithium-rich Layered Oxide Cathodes by Aberration-Corrected STEM

(2012) K. Jarvis et al.   MICROSCOPY AND MICROANALYSIS

Chromium substitution in ion exchanged Li3Fe2(PO4)3 and the effects on the electrochemical behavior as cathodes for lithium batteries

(2011) N. Plylahan et al.   ELECTROCHIMICA ACTA

Identifying surface structural changes in layered Li-excess nickel manganese oxides in high voltage lithium ion batteries: A joint experimental and theoretical study

(2011) Bo Xu et al.   Energy & Environmental Science

Ambivalent Effect of Oxygen Vacancies on Li2MnO3: A First-Principles Study

(2011) Yasuharu Okamoto   JOURNAL OF THE ELECTROCHEMICAL SOCIETY

Structural evolution of layered Li1.2Ni0.2Mn0.6O2 upon electrochemical cycling in a Li rechargeable battery

(2010) Jihyun Hong et al.   JOURNAL OF MATERIALS CHEMISTRY

Functional surface modifications of a high capacity layered Li[Li0.2Mn0.54Ni0.13Co0.13]O2 cathode

(2010) Jun Liu et al.   JOURNAL OF MATERIALS CHEMISTRY

Structure and performance of LiFePO4 cathode materials: A review

(2010) Wei-Jun Zhang   JOURNAL OF POWER SOURCES

Electron Transfer Mechanisms upon Lithium Deintercalation from LiCoO2to CoO2Investigated by XPS

(2007) L. Dahéron et al.   CHEMISTRY OF MATERIALS