Fundamental understanding and practical challenges of anionic redox activity in Li-ion batteries

Material design of high-capacity Li-rich layered-oxide electrodes: Li2MnO3 and beyond

(2017) Soo Kim et al.   Energy & Environmental Science

Requirements for reversible extra-capacity in Li-rich layered oxides for Li-ion batteries

(2017) Y. Xie et al.   Energy & Environmental Science

Review on anionic redox for high-capacity lithium- and sodium-ion batteries

(2017) Chenglong Zhao et al.   JOURNAL OF PHYSICS D-APPLIED PHYSICS

Effect of transition metal composition on electrochemical performance of nickel-manganese-based lithium-rich layer-structured cathode materials in lithium-ion batteries

(2017) Hiroaki Konishi et al.   JOURNAL OF SOLID STATE CHEMISTRY

The Role of Oxygen Release from Li- and Mn-Rich Layered Oxides during the First Cycles Investigated by On-Line Electrochemical Mass Spectrometry

(2017) Benjamin Strehle et al.   JOURNAL OF THE ELECTROCHEMICAL SOCIETY

Evidence for anionic redox activity in a tridimensional-ordered Li-rich positive electrode β-Li2IrO3

(2017) Paul E. Pearce et al.   NATURE MATERIALS

Energy and fuels from electrochemical interfaces

(2017) Vojislav R. Stamenkovic et al.   NATURE MATERIALS

Coupling between oxygen redox and cation migration explains unusual electrochemistry in lithium-rich layered oxides

(2017) William E. Gent et al.   Nature Communications

Fundamental interplay between anionic/cationic redox governing the kinetics and thermodynamics of lithium-rich cathodes

(2017) Gaurav Assat et al.   Nature Communications

Approaching the limits of cationic and anionic electrochemical activity with the Li-rich layered rocksalt Li3IrO4

(2017) Arnaud J. Perez et al.   Nature Energy

The future cost of electrical energy storage based on experience rates

(2017) O. Schmidt et al.   Nature Energy

Understanding the Stability for Li-Rich Layered Oxide Li2 RuO3 Cathode

(2016) Biao Li et al.   ADVANCED FUNCTIONAL MATERIALS

Synthesis and Electrochemical Properties of Li4MoO5–NiO Binary System as Positive Electrode Materials for Rechargeable Lithium Batteries

(2016) Naoaki Yabuuchi et al.   CHEMISTRY OF MATERIALS

Best Practice: Performance and Cost Evaluation of Lithium Ion Battery Active Materials with Special Emphasis on Energy Efficiency

(2016) Paul Meister et al.   CHEMISTRY OF MATERIALS

Synthesis and Electrode Performance of Li4MoO5-LiFeO2 Binary System as Positive Electrode Materials for Rechargeable Lithium Batteries

(2016) Takashi MATSUHARA et al.   ELECTROCHEMISTRY

The intriguing question of anionic redox in high-energy density cathodes for Li-ion batteries

(2016) M. Saubanère et al.   Energy & Environmental Science

Performance and design considerations for lithium excess layered oxide positive electrode materials for lithium ion batteries

(2016) Sunny Hy et al.   Energy & Environmental Science

X-ray Photoemission Spectroscopy Study of Cationic and Anionic Redox Processes in High-Capacity Li-Ion Battery Layered-Oxide Electrodes

(2016) Dominique Foix et al.   Journal of Physical Chemistry C

Quantitative probe of the transition metal redox in battery electrodes through soft x-ray absorption spectroscopy

(2016) Qinghao Li et al.   JOURNAL OF PHYSICS D-APPLIED PHYSICS

Editors' Choice—Practical Assessment of Anionic Redox in Li-Rich Layered Oxide Cathodes: A Mixed Blessing for High Energy Li-Ion Batteries

(2016) Gaurav Assat et al.   JOURNAL OF THE ELECTROCHEMICAL SOCIETY

The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials

(2016) Dong-Hwa Seo et al.   Nature Chemistry

Charge-compensation in 3d-transition-metal-oxide intercalation cathodes through the generation of localized electron holes on oxygen

(2016) Kun Luo et al.   Nature Chemistry

Anionic redox processes for electrochemical devices

(2016) A. Grimaud et al.   NATURE MATERIALS

Ground-state oxygen holes and the metal–insulator transition in the negative charge-transfer rare-earth nickelates

(2016) Valentina Bisogni et al.   Nature Communications

Origin of stabilization and destabilization in solid-state redox reaction of oxide ions for lithium-ion batteries

(2016) Naoaki Yabuuchi et al.   Nature Communications

Li- and Mn-Rich Cathode Materials: Challenges to Commercialization

(2016) Jianming Zheng et al.   Advanced Energy Materials

Evidence of reversible oxygen participation in anomalously high capacity Li- and Mn-rich cathodes for Li-ion batteries

(2016) Shoaib Muhammad et al.   Nano Energy

Nickel-Rich Layered Cathode Materials for Automotive Lithium-Ion Batteries: Achievements and Perspectives

(2016) Seung-Taek Myung et al.   ACS Energy Letters

Anion-redox nanolithia cathodes for Li-ion batteries

(2016) Zhi Zhu et al.   Nature Energy

Review of the U.S. Department of Energy’s “Deep Dive” Effort to Understand Voltage Fade in Li- and Mn-Rich Cathodes

(2015) Jason R. Croy et al.   ACCOUNTS OF CHEMICAL RESEARCH

Role of Mn Content on the Electrochemical Properties of Nickel-Rich Layered LiNi0.8–xCo0.1Mn0.1+xO2 (0.0 ≤ x ≤ 0.08) Cathodes for Lithium-Ion Batteries

(2015) Jianming Zheng et al.   ACS Applied Materials & Interfaces

Characterization of Disordered Li(1+x)Ti2xFe(1–3x)O2 as Positive Electrode Materials in Li-Ion Batteries Using Percolation Theory

(2015) Stephen L. Glazier et al.   CHEMISTRY OF MATERIALS

A new class of high capacity cation-disordered oxides for rechargeable lithium batteries: Li–Ni–Ti–Mo oxides

(2015) Jinhyuk Lee et al.   Energy & Environmental Science

Origin of hysteresis between charge and discharge processes in lithium-rich layer-structured cathode material for lithium-ion battery

(2015) Hiroaki Konishi et al.   JOURNAL OF POWER SOURCES

Direct observation of reversible charge compensation by oxygen ion in Li-rich manganese layered oxide positive electrode material, Li 1.16 Ni 0.15 Co 0.19 Mn 0.50 O 2

(2015) Masatsugu Oishi et al.   JOURNAL OF POWER SOURCES

Understanding the Roles of Anionic Redox and Oxygen Release during Electrochemical Cycling of Lithium-Rich Layered Li4FeSbO6

(2015) Eric McCalla et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Re-entrant Lithium Local Environments and Defect Driven Electrochemistry of Li- and Mn-Rich Li-Ion Battery Cathodes

(2015) Fulya Dogan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible Li-Intercalation through Oxygen Reactivity in Li-Rich Li-Fe-Te Oxide Materials

(2015) E. McCalla et al.   JOURNAL OF THE ELECTROCHEMICAL SOCIETY

Physical Theory of Voltage Fade in Lithium- and Manganese-Rich Transition Metal Oxides

(2015) S. G. Rinaldo et al.   JOURNAL OF THE ELECTROCHEMICAL SOCIETY

Electrochemical Modeling and Performance of a Lithium- and Manganese-Rich Layered Transition-Metal Oxide Positive Electrode

(2015) D. W. Dees et al.   JOURNAL OF THE ELECTROCHEMICAL SOCIETY

Review—Li-Rich Layered Oxide Cathodes for Next-Generation Li-Ion Batteries: Chances and Challenges

(2015) Patrick Rozier et al.   JOURNAL OF THE ELECTROCHEMICAL SOCIETY

Review—Lithium-Excess Layered Cathodes for Lithium Rechargeable Batteries

(2015) Jihyun Hong et al.   JOURNAL OF THE ELECTROCHEMICAL SOCIETY

A new active Li–Mn–O compound for high energy density Li-ion batteries

(2015) M. Freire et al.   NATURE MATERIALS

Visualization of O-O peroxo-like dimers in high-capacity layered oxides for Li-ion batteries

(2015) E. McCalla et al.   SCIENCE

Electron paramagnetic resonance imaging for real-time monitoring of Li-ion batteries

(2015) M. Sathiya et al.   Nature Communications

Probing the initiation of voltage decay in Li-rich layered cathode materials at the atomic scale

(2015) Yan Wu et al.   Journal of Materials Chemistry A

Origin of voltage decay in high-capacity layered oxide electrodes

(2014) M. Sathiya et al.   NATURE MATERIALS

Unlocking the Potential of Cation-Disordered Oxides for Rechargeable Lithium Batteries

(2014) J. Lee et al.   SCIENCE

A new electrode material for rechargeable sodium batteries: P2-type Na2/3[Mg0.28Mn0.72]O2 with anomalously high reversible capacity

(2014) Naoaki Yabuuchi et al.   Journal of Materials Chemistry A

Li4NiTeO6 as a positive electrode for Li-ion batteries

(2013) M. Sathiya et al.   CHEMICAL COMMUNICATIONS

High Performance Li2Ru1–yMnyO3 (0.2 ≤ y ≤ 0.8) Cathode Materials for Rechargeable Lithium-Ion Batteries: Their Understanding

(2013) M. Sathiya et al.   CHEMISTRY OF MATERIALS

Examining Hysteresis in Composite xLi2MnO3·(1–x)LiMO2 Cathode Structures

(2013) Jason R. Croy et al.   Journal of Physical Chemistry C

Different oxygen redox participation for bulk and surface: A possible global explanation for the cycling mechanism of Li1.20Mn0.54Co0.13Ni0.13O2

(2013) Hideyuki Koga et al.   JOURNAL OF POWER SOURCES

Comparison of the structural and electrochemical properties of layered Li[NixCoyMnz]O2 (x = 1/3, 0.5, 0.6, 0.7, 0.8 and 0.85) cathode material for lithium-ion batteries

(2013) Hyung-Joo Noh et al.   JOURNAL OF POWER SOURCES

Direct In situ Observation of Li2O Evolution on Li-Rich High-Capacity Cathode Material, Li[NixLi(1–2x)/3Mn(2–x)/3]O2 (0 ≤ x ≤0.5)

(2013) Sunny Hy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrochemical Kinetics and Performance of Layered Composite Cathode Material Li[Li0.2Ni0.2Mn0.6]O2

(2013) Jianming Zheng et al.   JOURNAL OF THE ELECTROCHEMICAL SOCIETY

Voltage Fade of Layered Oxides: Its Measurement and Impact on Energy Density

(2013) Martin Bettge et al.   JOURNAL OF THE ELECTROCHEMICAL SOCIETY

Reversible Oxygen Participation to the Redox Processes Revealed for Li1.20Mn0.54Co0.13Ni0.13O2

(2013) Hideyuki Koga et al.   JOURNAL OF THE ELECTROCHEMICAL SOCIETY

First Evidence of Manganese–Nickel Segregation and Densification upon Cycling in Li-Rich Layered Oxides for Lithium Batteries

(2013) Adrien Boulineau et al.   NANO LETTERS

Reversible anionic redox chemistry in high-capacity layered-oxide electrodes

(2013) M. Sathiya et al.   NATURE MATERIALS

Electrochemical and rate performance study of high-voltage lithium-rich composition: Li1.2Mn0.525Ni0.175Co0.1O2

(2011) Surendra K. Martha et al.   JOURNAL OF POWER SOURCES

Detailed Studies of a High-Capacity Electrode Material for Rechargeable Batteries, Li2MnO3−LiCo1/3Ni1/3Mn1/3O2

(2011) Naoaki Yabuuchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Challenges for Rechargeable Li Batteries†

(2009) John B. Goodenough et al.   CHEMISTRY OF MATERIALS

Electrochemical Activities in Li[sub 2]MnO[sub 3]

(2009) Denis Y. W. Yu et al.   JOURNAL OF THE ELECTROCHEMICAL SOCIETY

Mechanisms Associated with the “Plateau” Observed at High Voltage for the Overlithiated Li1.12(Ni0.425Mn0.425Co0.15)0.88O2System

(2008) N. Tran et al.   CHEMISTRY OF MATERIALS

Electron Transfer Mechanisms upon Lithium Deintercalation from LiCoO2to CoO2Investigated by XPS

(2007) L. Dahéron et al.   CHEMISTRY OF MATERIALS