An isolable, crystalline complex of square-planar silicon(IV)

Planar Hypercoordinate Motifs in Two-Dimensional Materials

(2020) Yu Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

An Isolable Tetrasilicon Analogue of a Planar Bicyclo[1.1.0]butane with π-Type Single-Bonding Character

(2020) Takumi Nukazawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A mono‐substituted silicon(II) cation – A crystalline “supersilylene”

(2020) Alexander Hinz   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Element-Ligand Cooperativity with p-Block Elements

(2020) Lutz Greb et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Planar Tetracoordinate Silicons in Organic Molecules As Carbenoid‐Type Amphoteric Centers: A Computational Study

(2020) Yuwei Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Planar Tetracoordinated Silicon (ptSi): Room-Temperature Stable Compounds Containing Anti-van’t Hoff/Le Bel Silicon

(2020) Priyabrata Ghana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Redox-Confused Bismuth(I/III) Triamide with a T-Shaped Planar Ground State

(2019) Marcus B. Kindervater et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structural Characterization of a Boron(III) η2-σ-Silane-Complex

(2019) Yizhen Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pushing the Lewis Acidity Boundaries of Boron Compounds With Non-Planar Triarylboranes Derived from Triptycenes

(2019) Ali Ben Saida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Calix[4]pyrrole Aluminate: A Planar Tetracoordinate Aluminum(III) Anion and Its Unusual Lewis Acidity

(2019) Fabian Ebner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formation of Agostic Structures Driven by London Dispersion

(2018) Qing Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ambiphilic geometrically constrained phosphenium cation

(2018) Solomon Volodarsky et al.   CHEMICAL COMMUNICATIONS

Stabilization of planar tetra-coordinate silicon in a 2D-layered extended system and design of a high-capacity anode material for Li-ion batteries

(2018) Ming-Jun Sun et al.   Nanoscale

Calix[4]pyrrole Hydridosilicate: The Elusive Planar Tetracoordinate Silicon Imparts Striking Stability to Its Anionic Silicon Hydride

(2018) Fabian Ebner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Arylation of hydrocarbons enabled by organosilicon reagents and weakly coordinating anions

(2017) Brian Shao et al.   SCIENCE

Hydrogen atoms can be located accurately and precisely by x-ray crystallography

(2016) M. Woinska et al.   Science Advances

Four Decades of the Chemistry of Planar Hypercoordinate Compounds

(2015) Li-Ming Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

E-H Bond Activation of Ammonia and Water by a Geometrically Constrained Phosphorus(III) Compound

(2015) Thomas P. Robinson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Square-Planar Aluminum(III) Complexes

(2014) Emily J. Thompson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Donor-Acceptor Adducts of a 1,3-Disila-2-oxyallyl Zwitterion

(2014) Michael J. Cowley et al.   CHEMISTRY-A EUROPEAN JOURNAL

Direct observation of a borane–silane complex involved in frustrated Lewis-pair-mediated hydrosilylations

(2014) Adrian Y. Houghton et al.   Nature Chemistry

Silicon(II) Coordination Chemistry: N-Heterocyclic Carbene Complexes of Si2+and SiI+

(2013) Alexander C. Filippou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Cyclic Silylone (“Siladicarbene”) with an Electron-Rich Silicon(0) Atom

(2013) Yun Xiong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Stable Singlet Biradicaloid Siladicarbene: (L:)2Si

(2013) Kartik Chandra Mondal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Elusive Silyliumylidene [ClSi:]+and Silathionium [ClSiS]+Cations Stabilized by Bis(Iminophosphorane) Chelate Ligand

(2012) Yun Xiong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Exploring the fate of the tris(pentafluorophenyl)borane radical anion in weakly coordinating solvents

(2012) Elliot J. Lawrence et al.   DALTON TRANSACTIONS

A Stable Two-Coordinate Acyclic Silylene

(2012) Andrey V. Protchenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Main Group Redox Catalysis: Reversible PIII/PV Redox Cycling at a Phosphorus Platform

(2012) Nicole L. Dunn et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Proton-Catalyzed, Silane-Fueled Friedel-Crafts Coupling of Fluoroarenes

(2011) O. Allemann et al.   SCIENCE

SiC2Silagraphene and Its One-Dimensional Derivatives: Where Planar Tetracoordinate Silicon Happens

(2010) Yafei Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Main-group elements as transition metals

(2010) Philip P. Power   NATURE

Lewis Base Stabilized Dichlorosilylene

(2009) Rajendra S. Ghadwal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

π-Metal complexes of tetrapyrrolic systems. A novel coordination mode in “porphyrin-like” chemistry

(2009) Luciano Cuesta et al.   CHEMICAL SOCIETY REVIEWS

R3C−H→SiFR3Agostic Interaction

(2008) Christopher L. Dorsey et al.   ORGANOMETALLICS