Mechanistic Origins of Stereodivergence in Asymmetric Cascade Allylation and Cyclization Reactions Enabled by Synergistic Cu/Ir Catalysis

­­­­Cooperative Bond Activation and Facile Intramolecular Aryl Transfer of Nickel‐Aluminum Pincer‐type Complexes

(2021) Connie C. Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand Conformational Flexibility Enables Enantioselective Tertiary C–B Bond Formation in the Phosphonate-Directed Catalytic Asymmetric Alkene Hydroboration

(2021) Huiling Shao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Challenges and Opportunities in Multicatalysis

(2021) Sebastián Martínez et al.   ACS Catalysis

Post-Transition State Bifurcation in Iron-Catalyzed Arene Aminations

(2021) Bo Li et al.   ACS Catalysis

Mechanistic Study of Ni and Cu Dual Catalyst for Asymmetric C–C Bond Formation; Asymmetric Coupling of 1,3-Dienes with C-nucleophiles to Construct Vicinal Stereocenters

(2021) Jingzhao Xia et al.   ACS Catalysis

Catalytic Asymmetric Reactions with N-Metallated Azomethine Ylides

(2020) Liang Wei et al.   ACCOUNTS OF CHEMICAL RESEARCH

Stereodivergent Pd/Cu Catalysis for the Dynamic Kinetic Asymmetric Transformation of Racemic Unsymmetrical 1,3-Disubstituted Allyl Acetates

(2020) Rui He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Insights on Absolute and Relative Stereocontrol in Stereodivergent Cooperative Catalysis

(2020) Avtar Changotra et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synergistic Catalysis with Azomethine Ylides

(2020) Liang Wei et al.   CHINESE JOURNAL OF CHEMISTRY

Reaction Mechanism, Origins of Enantioselectivity, and Reactivity Trends in Asymmetric Allylic Alkylation: A Comprehensive Quantum Mechanics Investigation of a C(sp3)–C(sp3) Cross-Coupling

(2020) Alexander Q. Cusumano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereodivergent Synthesis of α-Quaternary Serine and Cysteine Derivatives Containing Two Contiguous Stereogenic Centers via Synergistic Cu/Ir Catalysis

(2020) Hui-Min Wu et al.   ORGANIC LETTERS

Stereodivergent catalytic asymmetric allylic alkylation (AAA)

(2020) Subarna Jyoti Kalita et al.   Science Bulletin

Diastereodivergent Synthesis of β‐Amino Alcohols through Dual‐Metal‐Catalyzed Coupling of Alkoxyallenes with Aldimine Esters

(2020) Weiwei Zi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synergistic Dual Transition Metal Catalysis

(2020) U Bin Kim et al.   CHEMICAL REVIEWS

Stereodivergent Carbon–Carbon Bond Formation between Iminium and Enolate Intermediates by Synergistic Organocatalysis

(2020) Byungjun Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Studies of Copper(I)-Catalyzed Stereoselective [2,3]-Sigmatropic Rearrangements of Diazoesters with Allylic Iodides/Sulfides

(2020) Zheyuan Liu et al.   ACS Catalysis

Theoretical Study of the Addition of Cu–Carbenes to Acetylenes to Form Chiral Allenes

(2019) Kangbao Zhong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synergistic Cu/Pd Catalyzed Asymmetric Allenylic Alkylation of Azomethine Ylides for the Construction of α‐Allenylic Substituted Nonproteinogenic α‐Amino Acids

(2019) Chun-Jiang Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iridium-Catalyzed Asymmetric Synthesis of Functionally Rich Molecules Enabled by (Phosphoramidite,Olefin) Ligands

(2019) Simon L. Rössler et al.   ACCOUNTS OF CHEMICAL RESEARCH

Stereodivergent Construction of Tertiary Fluorides in Vicinal Stereogenic Pairs by Allylic Substitution with Iridium and Copper Catalysts

(2019) Zhi-Tao He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Energy Decomposition Analyses Reveal the Origins of Catalyst and Nucleophile Effects on Regioselectivity in Nucleopalladation of Alkenes

(2019) Xiaotian Qi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synergistic catalysis for cascade allylation and 2-aza-cope rearrangement of azomethine ylides

(2019) Liang Wei et al.   Nature Communications

Stereodivergent Coupling of 1,3-Dienes with Aldimine Esters Enabled by Synergistic Pd and Cu Catalysis

(2019) Qinglong Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Towards the online computer-aided design of catalytic pockets

(2019) Laura Falivene et al.   Nature Chemistry

Synergistic Pd/Cu Catalysis in Organic Synthesis

(2019) Yue Wu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stereodivergent assembly of tetrahydro-γ-carbolines via synergistic catalytic asymmetric cascade reaction

(2019) Shi-Ming Xu et al.   Nature Communications

Stereodivergent Catalysis

(2018) Irina P. Beletskaya et al.   CHEMICAL REVIEWS

Computational Characterization of the Mechanism for the Oxidative Coupling of Benzoic Acid and Alkynes by Rhodium/Copper and Rhodium/Silver Systems

(2018) Ignacio Funes-Ardoiz et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stereodivergent Synthesis of α,α-Disubstituted α-Amino Acids via Synergistic Cu/Ir Catalysis

(2018) Liang Wei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Regiodivergent Synthesis of Chiral Pyrrolidines with Two Quaternary Stereocenters via Ligand-Controlled Copper(I)-Catalyzed Asymmetric 1,3-Dipolar Cycloadditions

(2018) Shan Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereodivergent Allylation of Azaaryl Acetamides and Acetates by Synergistic Iridium and Copper Catalysis

(2018) Xingyu Jiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ir/Cu Dual Catalysis: Enantio- and Diastereodivergent Access to α,α-Disubstituted α-Amino Acids Bearing Vicinal Stereocenters

(2018) Xiaohong Huo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The role of the metal in the dual-metal catalysed hydrophenoxylation of diphenylacetylene

(2018) Oscar F. González-Belman et al.   Catalysis Science & Technology

Synergistic Cu/Pd Catalysis for Enantioselective Allylation of Ketimine Esters: The Direct Synthesis of α-Substituted α-Amino Acids and 2H- Pyrrols

(2018) Liang Wei et al.   ADVANCED SYNTHESIS & CATALYSIS

Enantioselective and Diastereodivergent Access to α-Substituted α-Amino Acids via Dual Iridium and Copper Catalysis

(2018) Jiacheng Zhang et al.   ADVANCED SYNTHESIS & CATALYSIS

Iridium-Catalyzed Asymmetric Allylic Substitution Reactions

(2018) Qiang Cheng et al.   CHEMICAL REVIEWS

Stereoselective and Site-Specific Allylic Alkylation of Amino Acids and Small Peptides via a Pd/Cu Dual Catalysis

(2017) Xiaohong Huo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereodivergent Coupling of Aldehydes and Alkynes via Synergistic Catalysis Using Rh and Jacobsen’s Amine

(2017) Faben A. Cruz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereodivergence in Asymmetric Catalysis

(2017) Simon Krautwald et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cooperative bimetallic catalysis in asymmetric allylic substitution

(2017) Jingke Fu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Ir/Zn Dual Catalysis: Enantioselective and Diastereodivergent α-Allylation of Unprotected α-Hydroxy Indanones

(2017) Rui He et al.   ORGANIC LETTERS

Bimetallic catalysis for C–C and C–X coupling reactions

(2017) Dominic R. Pye et al.   Chemical Science

Asymmetric Dual Chiral Catalysis using Iridium Phosphoramidites and Diarylprolinol Silyl Ethers: Insights into Stereodivergence

(2017) Bangaru Bhaskararao et al.   ACS Catalysis

Cooperative Reductive Elimination: The Missing Piece in the Oxidative-Coupling Mechanistic Puzzle

(2016) Ignacio Funes-Ardoiz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Combinations of Aminocatalysts and Metal Catalysts: A Powerful Cooperative Approach in Selective Organic Synthesis

(2016) Samson Afewerki et al.   CHEMICAL REVIEWS

A Switchable Gold Catalyst by Encapsulation in a Self-Assembled Cage

(2016) Anne C. H. Jans et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Ir/Zn Dual Catalysis for Enantio- and Diastereodivergent α-Allylation of α-Hydroxyketones

(2016) Xiaohong Huo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereodivergent Allylic Substitutions with Aryl Acetic Acid Esters by Synergistic Iridium and Lewis Base Catalysis

(2016) Xingyu Jiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic activation of carbon–carbon bonds in cyclopentanones

(2016) Ying Xia et al.   NATURE

Mechanism and Origins of Ligand-Controlled Linear Versus Branched Selectivity of Iridium-Catalyzed Hydroarylation of Alkenes

(2016) Genping Huang et al.   ACS Catalysis

Stereodivergent Dual Catalytic α-Allylation of Protected α-Amino- and α-Hydroxyacetaldehydes

(2015) Tobias Sandmeier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

On the Mechanism of the Digold(I)-Hydroxide-Catalysed Hydrophenoxylation of Alkynes

(2015) Adrián Gómez-Suárez et al.   CHEMISTRY-A EUROPEAN JOURNAL

Computational Study of Rh-Catalyzed Carboacylation of Olefins: Ligand-Promoted Rhodacycle Isomerization Enables Regioselective C–C Bond Functionalization of Benzocyclobutenones

(2015) Gang Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Origin of Stereodivergence in Cooperative Asymmetric Catalysis with Simultaneous Involvement of Two Chiral Catalysts

(2015) Bangaru Bhaskararao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dual Gold Catalysis: Stepwise Catalyst Transfer via Dinuclear Clusters

(2015) Mie Højer Larsen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Computational Mechanistic Study of an Unprecedented Heck-Type Relay Reaction: Insight into the Origins of Regio- and Enantioselectivities

(2014) Yanfeng Dang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereodivergent α-Allylation of Linear Aldehydes with Dual Iridium and Amine Catalysis

(2014) Simon Krautwald et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dual Catalysis Becomes Diastereodivergent

(2013) Maria Teresa Oliveira et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A New Twist on Cooperative Catalysis

(2013) C. S. Schindler et al.   SCIENCE

Enantio- and Diastereodivergent Dual Catalysis:  -Allylation of Branched Aldehydes

(2013) S. Krautwald et al.   SCIENCE

Aromatic Interactions as Control Elements in Stereoselective Organic Reactions

(2012) Elizabeth H. Krenske et al.   ACCOUNTS OF CHEMICAL RESEARCH

Understanding Substituent Effects in Noncovalent Interactions Involving Aromatic Rings

(2012) Steven E. Wheeler   ACCOUNTS OF CHEMICAL RESEARCH

Iridium-Catalyzed Allylic Alkylation Reaction with N-Aryl Phosphoramidite Ligands: Scope and Mechanistic Studies

(2012) Wen-Bo Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand Effects on Rates and Regioselectivities of Rh(I)-Catalyzed (5 + 2) Cycloadditions: A Computational Study of Cyclooctadiene and Dinaphthocyclooctatetraene as Ligands

(2012) Xiufang Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multiwfn: A multifunctional wavefunction analyzer

(2011) Tian Lu et al.   JOURNAL OF COMPUTATIONAL CHEMISTRY

Ligand Steric Contours To Understand the Effects ofN-Heterocyclic Carbene Ligands on the Reversal of Regioselectivity in Ni-Catalyzed Reductive Couplings of Alkynes and Aldehydes

(2011) Peng Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Comparing the Enantioselective Power of Steric and Electrostatic Effects in Transition-Metal-Catalyzed Asymmetric Synthesis

(2010) Albert Poater et al.   CHEMISTRY-A EUROPEAN JOURNAL

Flexibility of N-Heterocyclic Carbene Ligands in Ruthenium Complexes Relevant to Olefin Metathesis and Their Impact in the First Coordination Sphere of the Metal

(2010) Francesco Ragone et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Revealing Noncovalent Interactions

(2010) Erin R. Johnson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Universal Solvation Model Based on Solute Electron Density and on a Continuum Model of the Solvent Defined by the Bulk Dielectric Constant and Atomic Surface Tensions

(2009) Aleksandr V. Marenich et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Density Functionals with Broad Applicability in Chemistry

(2008) Yan Zhao et al.   ACCOUNTS OF CHEMICAL RESEARCH

Revised Basis Sets for the LANL Effective Core Potentials

(2008) Lindsay E. Roy et al.   Journal of Chemical Theory and Computation

Gold-Catalyzed Cycloisomerization of 1,5-Allenynes via Dual Activation of an Ene Reaction

(2008) Paul Ha-Yeon Cheong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY