Enantioselective Synthesis of Axially Chiral Sulfonamides via Atroposelective Hydroamination of Allenes

Chiral Pd-Catalyzed Enantioselective Syntheses of Various N–C Axially Chiral Compounds and Their Synthetic Applications

(2021) Osamu Kitagawa   ACCOUNTS OF CHEMICAL RESEARCH

Enantioselective Construction of C–C Axially Chiral Quinazolinones via Chirality Exchange and Phase-Transfer Catalysis

(2021) Zeng Gao et al.   ORGANIC LETTERS

Enantioselective Construction of Quinoxaline-Based Heterobiaryls and P,N-Ligands via Chirality Transfer Strategy

(2021) Zeng Gao et al.   ORGANIC LETTERS

Asymmetric Synthesis of Axially Chiral Anilides via Organocatalytic Atroposelective N-Acylation

(2020) Dawei Li et al.   ORGANIC LETTERS

Isothiourea-Catalyzed Atroposelective N-Acylation of Sulfonamides

(2020) Jun-Yang Ong et al.   ORGANIC LETTERS

Enantioselective Synthesis of Atropisomeric Anilides via Pd(II)-Catalyzed Asymmetric C–H Olefination

(2020) Qi-Jun Yao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Atropselective Dibrominations of a 1,1’-Disubstituted 2,2’-Biindolyl With Diverging Point-to-Axial Asymmetric Inductions. Deriving Diphosphane Ligands for Asymmetric Catalysis

(2019) Reinhard Brückner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Atropisomeric Anilides Synthesis via Cu-Catalyzed Intramolecular Adjacent C–N Coupling

(2019) Xiaozhong Fan et al.   ACS Catalysis

Enantioselective Synthesis of Atropisomers Featuring Pentatomic Heteroaromatics by Pd-Catalyzed C–H Alkynylation

(2019) Shuo Zhang et al.   ACS Catalysis

Enantioselective Synthesis of Biaryl Atropisomers via Pd-Catalyzed C-H Olefination using Chiral Spiro Phosphoric Acid Ligands

(2019) Jun Luo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Synthesis of N-C Axially Chiral Sulfonamides through Chiral Palladium-catalyzed N-Allylation

(2019) Yuki Kikuchi et al.   JOURNAL OF ORGANIC CHEMISTRY

Practical access to axially chiral sulfonamides and biaryl amino phenols via organocatalytic atroposelective N-alkylation

(2019) Shenci Lu et al.   Nature Communications

Construction of Axially Chiral Compounds via Asymmetric Organocatalysis

(2018) Yong-Bin Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Axially Chiral Dibenzazepinones via a Pd(0)-Catalyzed Atropo-enantioselective C-H Arylation

(2018) Nicolai Cramer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Atroposelective Intramolecular [4+2] Cycloaddition: Synthesis of Axially Chiral Heterobiaryls

(2018) Yidong Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of Axially Chiral 2-Aminobiaryls by Rhodium-Catalyzed Benzannulation of 1-Arylalkynes with 2-(Cyanomethyl)phenylboronates

(2018) Fei Xue et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N−C Axially Chiral Anilines: Electronic Effect on Barrier to Rotation and A Remote Proton Brake

(2018) Yumiko Iwasaki et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Asymmetric Nitrogen-Selective Addition Reaction of Indoles to Alkoxyallenes

(2018) Seok Hyeon Jang et al.   ORGANIC LETTERS

Catalyst-Controlled Stereoselective Synthesis of Atropisomers

(2018) Bouthayna Zilate et al.   ACS Catalysis

Dynamic Kinetic Asymmetric Heck Reaction for the Simultaneous Generation of Central and Axial Chirality

(2018) José A. Carmona et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Atroposelective Catalytic Asymmetric Allylic Alkylation Reaction for Axially Chiral Anilides with Achiral Morita–Baylis–Hillman Carbonates

(2018) Shou-Lei Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Remote Control of Axial Chirality: Synthesis of Spirooxindole–Urazoles via Desymmetrization of ATAD

(2018) Lin-Lin Zhang et al.   ORGANIC LETTERS

Peptide-Based Catalysts Reach the Outer Sphere through Remote Desymmetrization and Atroposelectivity

(2018) Anthony J. Metrano et al.   ACCOUNTS OF CHEMICAL RESEARCH

Pd-Catalyzed Atroposelective C−H Allylation through β-O Elimination: Diverse Synthesis of Axially Chiral Biaryls

(2018) Gang Liao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Design and Catalytic Asymmetric Construction of Axially Chiral 3,3′-Bisindole Skeletons

(2018) Chun Ma et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tolvaptan-Type Vasopressin Receptor Ligands: Important Role of Axial Chirality in the Active Form

(2017) Hidetsugu Tabata et al.   JOURNAL OF MEDICINAL CHEMISTRY

Organocatalytic asymmetric arylation of indoles enabled by azo groups

(2017) Liang-Wen Qi et al.   Nature Chemistry

Pd-Catalyzed Hydroamination of Alkoxyallenes with Azole Heterocycles: Examples and Mechanistic Proposal

(2017) Ivan Bernar et al.   ORGANIC LETTERS

From Palladium to Brønsted Acid Catalysis: Highly Enantioselective Regiodivergent Addition of Alkoxyallenes to Pyrazolones

(2016) Hui Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Discovery and enantiocontrol of axially chiral urazoles via organocatalytic tyrosine click reaction

(2016) Ji-Wei Zhang et al.   Nature Communications

Chiral Monophosphorus Ligands for Asymmetric Catalytic Reactions

(2016) Wenzhen Fu et al.   ACS Catalysis

The synthesis of optically active N–C axially chiral tetrahydroquinoline and its response to an acid-accelerated molecular rotor

(2015) Yuya Suzuki et al.   CHEMICAL COMMUNICATIONS

Nonbiaryl and Heterobiaryl Atropisomers: Molecular Templates with Promise for Atropselective Chemical Transformations

(2015) Elango Kumarasamy et al.   CHEMICAL REVIEWS

Stronger Brønsted Acids: Recent Progress

(2015) Takahiko Akiyama et al.   CHEMICAL REVIEWS

Recent advances and new concepts for the synthesis of axially stereoenriched biaryls

(2015) J. Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Pd-Catalyzed Enantioselective Hydroalkoxylation of Alkoxyallenes with Phenol for Construction of Acyclic O,O-Acetals

(2015) Liyin Jiang et al.   ORGANIC LETTERS

Organocatalytic Atroposelective Formal Diels–Alder Desymmetrization of N-Arylmaleimides

(2015) Florine Eudier et al.   ORGANIC LETTERS

Asymmetric synthesis of heteroaryl atropisomers via a gold-catalyzed cycloisomerization–amination cascade reaction

(2014) Rui Guo et al.   CHEMICAL COMMUNICATIONS

Alkoxyallenes as building blocks for organic synthesis

(2014) Reinhold Zimmer et al.   CHEMICAL SOCIETY REVIEWS

Pd-Catalyzed Asymmetric Intermolecular Hydroalkoxylation of Allene: An Entry to Cyclic Acetals with Activating Group-Free and Flexible Anomeric Control

(2014) Wontaeck Lim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Remote Control of Axial Chirality: Aminocatalytic Desymmetrization of N-Arylmaleimides via Vinylogous Michael Addition

(2014) Nicola Di Iorio et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

P,N ligands in asymmetric catalysis

(2013) Michael P. Carroll et al.   CHEMICAL SOCIETY REVIEWS

Highly Enantioselective Synthesis of 3-Substituted Furanones by Palladium-Catalyzed Kinetic Resolution of Unsymmetrical Allyl Acetates

(2012) Bin Mao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthetic Strategy for Cyclic Amines: A Stereodefined Cyclic N,O-Acetal as a Stereocontrol and Diversity-Generating Element

(2012) Haejin Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Proton Grease: An Acid Accelerated Molecular Rotor

(2012) Brent E. Dial et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereodefined N,O-Acetals: Pd-Catalyzed Synthesis from Homopropargylic Amines and Utility in the Flexible Synthesis of 2,6-Substituted Piperidines

(2012) Haejin Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Low-loading asymmetric organocatalysis

(2011) Francesco Giacalone et al.   CHEMICAL SOCIETY REVIEWS

Catalytic Asymmetric Synthesis of Axially Chiral o-Iodoanilides by Phase-Transfer Catalyzed Alkylations

(2011) Seiji Shirakawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Peptoid Atropisomers

(2011) Bishwajit Paul et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Palladium Catalyzed Asymmetric Addition of Oxindoles and Allenes: An Atom-Economical Versatile Method for the Construction of Chiral Indole Alkaloids

(2011) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

2-Substituted-2,3-dihydro-1H-quinolin-4-ones via Acid-Catalyzed Tandem Rupe Rearrangement-Donnelly-Farrell Ring Closure of 2-(3′-Hydroxy­propynyl)anilines

(2011) Federica Pisaneschi et al.   SYNLETT

Atroposelective Total Synthesis of Axially Chiral Biaryl Natural Products

(2010) Gerhard Bringmann et al.   CHEMICAL REVIEWS

Total synthesis of chiral biaryl natural products by asymmetric biaryl coupling

(2009) Marisa C. Kozlowski et al.   CHEMICAL SOCIETY REVIEWS

Enantioselective Protonation of Itaconimides with Thiols and the Rotational Kinetics of the Axially Chiral CN Bond

(2009) Shishi Lin et al.   Chemistry-An Asian Journal

Structure-Based Rationale for Selectivity in the Asymmetric Allylic Alkylation of Cycloalkenyl Esters Employing the Trost ‘Standard Ligand’ (TSL): Isolation, Analysis and Alkylation of the Monomeric form of the Cationic η3-Cyclohexenyl Complex [(η3-c-C6H9)Pd(TSL)]+

(2009) Craig P. Butts et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Sugars, Alkaloids, and Heteroaromatics: Exploring Heterocyclic Chemistry with Alkoxyallenes†

(2008) Malte Brasholz et al.   ACCOUNTS OF CHEMICAL RESEARCH