In Situ Infrared Spectroscopy for the Analysis of Gas-processing Metalloenzymes

Exploring Structure and Function of Redox Intermediates in [NiFe]‐Hydrogenases by an Advanced Experimental Approach for Solvated, Lyophilized and Crystallized Metalloenzymes

(2021) Christian Lorent et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Quantification of Local Electric Field Changes at the Active Site of Cytochrome c Oxidase by Fourier Transform Infrared Spectroelectrochemical Titrations

(2021) Federico Baserga et al.   Frontiers in Chemistry

Reactivity, Mechanism, and Assembly of the Alternative Nitrogenases

(2020) Andrew J. Jasniewski et al.   CHEMICAL REVIEWS

Shedding light on proton and electron dynamics in [FeFe] hydrogenases

(2020) Christian Lorent et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Methanogenesis involves direct hydride transfer from H2 to an organic substrate

(2020) Gangfeng Huang et al.   Nature Reviews Chemistry

The Spectroscopy of Nitrogenases

(2020) Casey Van Stappen et al.   CHEMICAL REVIEWS

Infrared Difference Spectroscopy of Proteins: From Bands to Bonds

(2020) Victor A. Lorenz-Fonfria   CHEMICAL REVIEWS

Current State of [FeFe]-hydrogenase Research - Biodiversity and Spectroscopic Investigations

(2020) Henrik Land et al.   ACS Catalysis

Structural Enzymology of Nitrogenase Enzymes

(2020) Oliver Einsle et al.   CHEMICAL REVIEWS

In-cell infrared difference spectroscopy of LOV photoreceptors reveals structural responses to light altered in living cells

(2020) Lukas Goett-Zink et al.   JOURNAL OF BIOLOGICAL CHEMISTRY

CO Binding to the FeV Cofactor of CO‐Reducing Vanadium Nitrogenase at Atomic Resolution

(2020) Michael Rohde et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Laser-Induced Potential Jump: A Method for Rapid Electron Injection into Oxidoreductase Enzymes

(2020) Monica L. K. Sanchez et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Using nature’s blueprint to expand catalysis with Earth-abundant metals

(2020) R. Morris Bullock et al.   SCIENCE

Proton Transfer Mechanisms in Bimetallic Hydrogenases

(2020) Hulin Tai et al.   ACCOUNTS OF CHEMICAL RESEARCH

Structural Characterization of Two CO Molecules Bound to the Nitrogenase Active Site

(2020) Trixia M. Buscagan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A catalytically active [Mn]-hydrogenase incorporating a non-native metal cofactor

(2019) Hui-Jie Pan et al.   Nature Chemistry

Cysteine SH and glutamate COOH contributions to [NiFe] hydrogenase proton transfer revealed by highly sensitive FT-IR spectroscopy

(2019) Hulin Tai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structural and Mechanistic Insights into CO 2 Activation by Nitrogenase Iron Protein

(2019) Lee A. Rettberg et al.   CHEMISTRY-A EUROPEAN JOURNAL

Investigating the Kinetic Competency of CrHydA1 [FeFe] Hydrogenase Intermediate States via Time-Resolved Infrared Spectroscopy

(2019) Monica L. K. Sanchez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Geometry of the Catalytic Active Site in [FeFe]-Hydrogenase Is Determined by Hydrogen Bonding and Proton Transfer

(2019) Jifu Duan et al.   ACS Catalysis

How [FeFe]-Hydrogenase Facilitates Bidirectional Proton Transfer

(2019) Moritz Senger et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Spectroscopic and Computational Evidence that [FeFe] Hydrogenases Operate Exclusively with CO-Bridged Intermediates

(2019) James A. Birrell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A [RuRu] Analogue of an [FeFe]-Hydrogenase Traps the Key Hydride Intermediate of the Catalytic Cycle

(2018) Constanze Sommer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Comparison of redox and ligand binding behaviour of yeast and bovine cytochrome c oxidases using FTIR spectroscopy

(2018) Amandine Maréchal et al.   BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS

Oxygen Activation and Energy Conservation by Cytochrome c Oxidase

(2018) Mårten Wikström et al.   CHEMICAL REVIEWS

Comprehensive reaction mechanisms at and near the Ni–Fe active sites of [NiFe] hydrogenases

(2018) Hulin Tai et al.   DALTON TRANSACTIONS

Methods of reconstitution to investigate membrane protein function

(2018) Ruth Skrzypek et al.   METHODS

Protonation/reduction dynamics at the [4Fe–4S] cluster of the hydrogen-forming cofactor in [FeFe]-hydrogenases

(2018) Moritz Senger et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Mechanistic Exploitation of a Self-Repairing, Blocked Proton Transfer Pathway in an O2-Tolerant [NiFe]-Hydrogenase

(2018) Rhiannon M. Evans et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Infrared Characterization of the Bidirectional Oxygen-Sensitive [NiFe]-Hydrogenase from E. coli

(2018) Moritz Senger et al.   Catalysts

Balancing electron transfer rate and driving force for efficient photocatalytic hydrogen production in CdSe/CdS nanorod–[NiFe] hydrogenase assemblies

(2017) Bryant Chica et al.   Energy & Environmental Science

Proteolytic cleavage orchestrates cofactor insertion and protein assembly in [NiFe]-hydrogenase biosynthesis

(2017) Moritz Senger et al.   JOURNAL OF BIOLOGICAL CHEMISTRY

Bridging Hydride at Reduced H-Cluster Species in [FeFe]-Hydrogenases Revealed by Infrared Spectroscopy, Isotope Editing, and Quantum Chemistry

(2017) Stefan Mebs et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Proton Coupled Electronic Rearrangement within the H-Cluster as an Essential Step in the Catalytic Cycle of [FeFe] Hydrogenases

(2017) Constanze Sommer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Crystal structure of CO-bound cytochromecoxidase determined by serial femtosecond X-ray crystallography at room temperature

(2017) Izumi Ishigami et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Infrared spectroscopy of the nitrogenase MoFe protein under electrochemical control: potential-triggered CO binding

(2017) P. Paengnakorn et al.   Chemical Science

Accumulating the hydride state in the catalytic cycle of [FeFe]-hydrogenases

(2017) Martin Winkler et al.   Nature Communications

Proton Transfer in the Catalytic Cycle of [NiFe] Hydrogenases: Insight from Vibrational Spectroscopy

(2017) Philip A. Ash et al.   ACS Catalysis

Pre-Steady-State Kinetics of Catalytic Intermediates of an [FeFe]-Hydrogenase

(2017) Brandon L. Greene et al.   ACS Catalysis

[FeFe]-Hydrogenase with Chalcogenide Substitutions at the H-Cluster Maintains Full H2 Evolution Activity

(2016) Jens Noth et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Grateful Infrared: Sequential Protein Structural Changes Resolved by Infrared Difference Spectroscopy

(2016) Tilman Kottke et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Stepwise isotope editing of [FeFe]-hydrogenases exposes cofactor dynamics

(2016) Moritz Senger et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Vibrational spectroscopy reveals the initial steps of biological hydrogen evolution

(2016) S. Katz et al.   Chemical Science

Measuring Electric Fields and Noncovalent Interactions Using the Vibrational Stark Effect

(2015) Stephen D. Fried et al.   ACCOUNTS OF CHEMICAL RESEARCH

Infrared Spectroscopy During Electrocatalytic Turnover Reveals the Ni-L Active Site State During H2Oxidation by a NiFe Hydrogenase

(2015) Ricardo Hidalgo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hybrid [FeFe]-Hydrogenases with Modified Active Sites Show Remarkable Residual Enzymatic Activity

(2015) Judith F. Siebel et al.   BIOCHEMISTRY

Infrared and Raman spectroscopic investigation of the reaction mechanism of cytochrome c oxidase

(2015) Satoru Nakashima et al.   BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS

FTIR studies of metal ligands, networks of hydrogen bonds, and water molecules near the active site Mn 4 CaO 5 cluster in Photosystem II

(2015) Richard J. Debus   BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS

Reaction Mechanism of Cytochrome c Oxidase

(2015) Shinya Yoshikawa et al.   CHEMICAL REVIEWS

Light-driven hydrogen production from Photosystem I-catalyst hybrids

(2015) Lisa M Utschig et al.   CURRENT OPINION IN CHEMICAL BIOLOGY

FT-IR Characterization of the Light-Induced Ni-L2 and Ni-L3 States of [NiFe] Hydrogenase from Desulfovibrio vulgaris Miyazaki F

(2015) Hulin Tai et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Electrochemical and Infrared Spectroscopic Studies Provide Insight into Reactions of the NiFe Regulatory Hydrogenase from Ralstonia eutropha with O2 and CO

(2015) Philip A. Ash et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Proton-Coupled Electron Transfer Dynamics in the Catalytic Mechanism of a [NiFe]-Hydrogenase

(2015) Brandon L. Greene et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogens detected by subatomic resolution protein crystallography in a [NiFe] hydrogenase

(2015) Hideaki Ogata et al.   NATURE

Key bioactive reaction products of the NO/H2S interaction are S/N-hybrid species, polysulfides, and nitroxyl

(2015) Miriam M. Cortese-Krott et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage

(2014) Brian M. Hoffman et al.   CHEMICAL REVIEWS

Hydrogenases

(2014) Wolfgang Lubitz et al.   CHEMICAL REVIEWS

Proton Transfer and Protein Conformation Dynamics in Photosensitive Proteins by Time-resolved Step-scan Fourier-transform Infrared Spectroscopy

(2014) Víctor A. Lórenz-Fonfría et al.   Jove-Journal of Visualized Experiments

IR signatures of the metal centres of bovine cytochromecoxidase: assignments and redox-linkage

(2013) Raksha Dodia et al.   BIOCHEMICAL SOCIETY TRANSACTIONS

Surface-enhanced infrared absorption spectroscopy (SEIRAS) to probe monolayers of membrane proteins

(2013) Kenichi Ataka et al.   BIOCHIMICA ET BIOPHYSICA ACTA-BIOMEMBRANES

Recent applications of ATR FTIR spectroscopy and imaging to proteins

(2013) Stefanie E. Glassford et al.   BIOCHIMICA ET BIOPHYSICA ACTA-PROTEINS AND PROTEOMICS

Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO2 Fixation

(2013) Aaron M. Appel et al.   CHEMICAL REVIEWS

The [NiFe]-hydrogenase accessory chaperones HypC and HybG ofEscherichia coliare iron- and carbon dioxide-binding proteins

(2013) Basem Soboh et al.   FEBS LETTERS

Biomimetic assembly and activation of [FeFe]-hydrogenases

(2013) G. Berggren et al.   NATURE

Spontaneous activation of [FeFe]-hydrogenases by an inorganic [2Fe] active site mimic

(2013) Julian Esselborn et al.   Nature Chemical Biology

Attenuated total reflectance infrared spectroelectrochemistry at a carbon particle electrode; unmediated redox control of a [NiFe]-hydrogenase solution

(2013) Adam J. Healy et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Structure and function of bacterial nitric oxide reductases

(2012) Yoshitsugu Shiro   BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS

Photolysis of Hi-CO Nitrogenase - Observation of a Plethora of Distinct CO Species Using Infrared Spectroscopy

(2011) Lifen Yan et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

The crystal structure of an oxygen-tolerant hydrogenase uncovers a novel iron-sulphur centre

(2011) Johannes Fritsch et al.   NATURE

Water molecule reorganization in cytochrome c oxidase revealed by FTIR spectroscopy

(2011) A. Marechal et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Solar hydrogen-producing bionanodevice outperforms natural photosynthesis

(2011) C. E. Lubner et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Steric Control of the Hi-CO MoFe Nitrogenase Complex Revealed by Stopped-Flow Infrared Spectroscopy

(2010) Zhi-Yong Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Initiation of the proton pump of cytochrome c oxidase

(2010) I. Belevich et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

The Protonation State of the Cross-linked Tyrosine during the Catalytic Cycle of CytochromecOxidase

(2008) Elena A. Gorbikova et al.   JOURNAL OF BIOLOGICAL CHEMISTRY

The proton donor for OO bond scission by cytochrome c oxidase

(2008) E. A. Gorbikova et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA