Beyond the Active Site: Mechanistic Investigations of the Role of the Secondary Coordination Sphere and Beyond in Multi-electron Electrocatalytic Reactions

Combining scaling relationships overcomes rate versus overpotential trade-offs in O2 molecular electrocatalysis

(2020) Daniel J. Martin et al.   Science Advances

Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes

(2019) Kristian E. Dalle et al.   CHEMICAL REVIEWS

Mechanism of Catalytic O2 Reduction by Iron Tetraphenylporphyrin

(2019) Michael L. Pegis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Interpreting the Electrocatalytic Voltammetry of Homogeneous Catalysts by the Foot of the Wave Analysis and Its Wider Implications

(2019) Vincent C.-C. Wang et al.   ACS Catalysis

Reversing the Tradeoff between Rate and Overpotential in Molecular Electrocatalysts for H2 Production

(2018) Christina M. Klug et al.   ACS Catalysis

Oxygen Reduction Reaction Promoted by Manganese Porphyrins

(2018) Guillaume Passard et al.   ACS Catalysis

Homogeneous Molecular Catalysis of Electrochemical Reactions: Manipulating Intrinsic and Operational Factors for Catalyst Improvement

(2018) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Identifying and Breaking Scaling Relations in Molecular Catalysis of Electrochemical Reactions

(2017) Michael L. Pegis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structure- and Potential-Dependent Cation Effects on CO Reduction at Copper Single-Crystal Electrodes

(2017) Elena Pérez-Gallent et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Combining theory and experiment in electrocatalysis: Insights into materials design

(2017) Zhi Wei Seh et al.   SCIENCE

Towards an intelligent design of molecular electrocatalysts

(2017) Cyrille Costentin et al.   Nature Reviews Chemistry

Controlling Proton Delivery through Catalyst Structural Dynamics

(2016) Allan Jay P. Cardenas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dissection of Electronic Substituent Effects in Multielectron–Multistep Molecular Catalysis. Electrochemical CO2-to-CO Conversion Catalyzed by Iron Porphyrins

(2016) Iban Azcarate et al.   Journal of Physical Chemistry C

Kinetic Analysis of Competitive Electrocatalytic Pathways: New Insights into Hydrogen Production with Nickel Electrocatalysts

(2016) Eric S. Wiedner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrolysis of Electrolyte Cations Enhances the Electrochemical Reduction of CO2 over Ag and Cu

(2016) Meenesh R. Singh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Through-Space Charge Interaction Substituent Effects in Molecular Catalysis Leading to the Design of the Most Efficient Catalyst of CO2-to-CO Electrochemical Conversion

(2016) Iban Azcarate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration

(2016) Min Liu et al.   NATURE

Exploring the kinetic and thermodynamic aspects of four-electron electrochemical reactions: electrocatalysis of oxygen evolution by metal oxides and biological systems

(2016) Vincent C.-C. Wang   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Homogenous Electrocatalytic Oxygen Reduction Rates Correlate with Reaction Overpotential in Acidic Organic Solutions

(2016) Michael L. Pegis et al.   ACS Central Science

Ab Initio-Based Kinetic Modeling for the Design of Molecular Catalysts: The Case of H2 Production Electrocatalysts

(2015) Ming-Hsun Ho et al.   ACS Catalysis

Evaluation of Homogeneous Electrocatalysts by Cyclic Voltammetry

(2014) Eric S. Rountree et al.   INORGANIC CHEMISTRY

Direct Comparison of Electrochemical and Spectrochemical Kinetics for Catalytic Oxygen Reduction

(2014) Derek J. Wasylenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pendant Acid–Base Groups in Molecular Catalysts: H-Bond Promoters or Proton Relays? Mechanisms of the Conversion of CO2 to CO by Electrogenerated Iron(0)Porphyrins Bearing Prepositioned Phenol Functionalities

(2014) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ultraefficient homogeneous catalyst for the CO2-to-CO electrochemical conversion

(2014) Cyrille Costentin et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Multielectron, Multistep Molecular Catalysis of Electrochemical Reactions: Benchmarking of Homogeneous Catalysts

(2014) Cyrille Costentin et al.   ChemElectroChem

A modular, energy-based approach to the development of nickel containing molecular electrocatalysts for hydrogen production and oxidation

(2013) Wendy J. Shaw et al.   BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS

Understanding Trends in the Electrocatalytic Activity of Metals and Enzymes for CO2 Reduction to CO

(2013) Heine A. Hansen et al.   Journal of Physical Chemistry Letters

Proton-Coupled Electron Transfer Cleavage of Heavy-Atom Bonds in Electrocatalytic Processes. Cleavage of a C–O Bond in the Catalyzed Electrochemical Reduction of CO2

(2013) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct observation of intermediates formed during steady-state electrocatalytic O2 reduction by iron porphyrins

(2013) K. Sengupta et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Determining the Overpotential for a Molecular Electrocatalyst

(2013) Aaron M. Appel et al.   ACS Catalysis

Proton Delivery and Removal in [Ni(PR2NR′2)2]2+ Hydrogen Production and Oxidation Catalysts

(2012) Molly O’Hagan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Turnover Numbers, Turnover Frequencies, and Overpotential in Molecular Catalysis of Electrochemical Reactions. Cyclic Voltammetry and Preparative-Scale Electrolysis

(2012) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Local Proton Source Enhances CO2 Electroreduction to CO by a Molecular Fe Catalyst

(2012) C. Costentin et al.   SCIENCE

[Ni(PMe2NPh2)2](BF4)2 as an Electrocatalyst for H2 Production

(2012) Stefan Wiese et al.   ACS Catalysis

Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces

(2011) Isabela C. Man et al.   ChemCatChem

Studies of a Series of [Ni(PR2NPh2)2(CH3CN)]2+Complexes as Electrocatalysts for H2Production: Substituent Variation at the Phosphorus Atom of the P2N2Ligand

(2011) Uriah J. Kilgore et al.   INORGANIC CHEMISTRY

[Ni(PPh2NC6H4X2)2]2+Complexes as Electrocatalysts for H2Production: Effect of Substituents, Acids, and Water on Catalytic Rates

(2011) Uriah J. Kilgore et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversibility and efficiency in electrocatalytic energy conversion and lessons from enzymes

(2011) F. A. Armstrong et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA