Combining scaling relationships overcomes rate versus overpotential trade-offs in O2 molecular electrocatalysis

Dioxygen Reduction to Hydrogen Peroxide by a Molecular Mn Complex: Mechanistic Divergence between Homogeneous and Heterogeneous Reductants

(2019) Shelby L. Hooe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Homogeneous, Heterogeneous, and Biological Catalysts for Electrochemical N2 Reduction toward NH3 under Ambient Conditions

(2019) Huimin Liu et al.   ACS Catalysis

Brønsted Acid Scaling Relationships Enable Control Over Product Selectivity from O2 Reduction with a Mononuclear Cobalt Porphyrin Catalyst

(2019) Yu-Heng Wang et al.   ACS Central Science

Introduction: Oxygen Reduction and Activation in Catalysis

(2018) Edward I. Solomon et al.   CHEMICAL REVIEWS

Oxygen Reduction by Homogeneous Molecular Catalysts and Electrocatalysts

(2018) Michael L. Pegis et al.   CHEMICAL REVIEWS

Nonprecious Metal Catalysts for Oxygen Reduction in Heterogeneous Aqueous Systems

(2018) Andrew A. Gewirth et al.   CHEMICAL REVIEWS

Understanding Catalytic Activity Trends in the Oxygen Reduction Reaction

(2018) Ambarish Kulkarni et al.   CHEMICAL REVIEWS

Reversing the Tradeoff between Rate and Overpotential in Molecular Electrocatalysts for H2 Production

(2018) Christina M. Klug et al.   ACS Catalysis

Understanding the apparent fractional charge of protons in the aqueous electrochemical double layer

(2018) Leanne D. Chen et al.   Nature Communications

Oxygen Reduction Reaction Promoted by Manganese Porphyrins

(2018) Guillaume Passard et al.   ACS Catalysis

Homogeneous Molecular Catalysis of Electrochemical Reactions: Manipulating Intrinsic and Operational Factors for Catalyst Improvement

(2018) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Decoding Proton-Coupled Electron Transfer with Potential–pKa Diagrams

(2017) Brian D. McCarthy et al.   INORGANIC CHEMISTRY

A Practical Beginner’s Guide to Cyclic Voltammetry

(2017) Noémie Elgrishi et al.   JOURNAL OF CHEMICAL EDUCATION

Identifying and Breaking Scaling Relations in Molecular Catalysis of Electrochemical Reactions

(2017) Michael L. Pegis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Molecular Cobalt Catalysts for O2 Reduction: Low-Overpotential Production of H2O2 and Comparison with Iron-Based Catalysts

(2017) Yu-Heng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxygen Reduction Catalysis at a Dicobalt Center: The Relationship of Faradaic Efficiency to Overpotential

(2016) Guillaume Passard et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Through-Space Charge Interaction Substituent Effects in Molecular Catalysis Leading to the Design of the Most Efficient Catalyst of CO2-to-CO Electrochemical Conversion

(2016) Iban Azcarate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Homogenous Electrocatalytic Oxygen Reduction Rates Correlate with Reaction Overpotential in Acidic Organic Solutions

(2016) Michael L. Pegis et al.   ACS Central Science

Standard Reduction Potentials for Oxygen and Carbon Dioxide Couples in Acetonitrile and N,N-Dimethylformamide

(2015) Michael L. Pegis et al.   INORGANIC CHEMISTRY

Benchmarking of Homogeneous Electrocatalysts: Overpotential, Turnover Frequency, Limiting Turnover Number

(2015) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Toward the rational benchmarking of homogeneous H2-evolving catalysts

(2014) Vincent Artero et al.   Energy & Environmental Science

Electrochemical Reduction of Brønsted Acids by Glassy Carbon in Acetonitrile—Implications for Electrocatalytic Hydrogen Evolution

(2014) Brian D. McCarthy et al.   INORGANIC CHEMISTRY

Evaluation of Homogeneous Electrocatalysts by Cyclic Voltammetry

(2014) Eric S. Rountree et al.   INORGANIC CHEMISTRY

Multielectron, Multistep Molecular Catalysis of Electrochemical Reactions: Benchmarking of Homogeneous Catalysts

(2014) Cyrille Costentin et al.   ChemElectroChem

Direct Determination of Equilibrium Potentials for Hydrogen Oxidation/Production by Open Circuit Potential Measurements in Acetonitrile

(2013) John A. S. Roberts et al.   INORGANIC CHEMISTRY

High Catalytic Rates for Hydrogen Production Using Nickel Electrocatalysts with Seven-Membered Cyclic Diphosphine Ligands Containing One Pendant Amine

(2013) Michael P. Stewart et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrodeposition from Acidic Solutions of Nickel Bis(benzenedithiolate) Produces a Hydrogen-Evolving Ni–S Film on Glassy Carbon

(2013) Ming Fang et al.   ACS Catalysis

Determining the Overpotential for a Molecular Electrocatalyst

(2013) Aaron M. Appel et al.   ACS Catalysis

Solar fuels generation and molecular systems: is it homogeneous or heterogeneous catalysis?

(2012) Vincent Artero et al.   CHEMICAL SOCIETY REVIEWS

Electrocatalytic Oxygen Reduction by Iron Tetra-arylporphyrins Bearing Pendant Proton Relays

(2012) Colin T. Carver et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Turnover Numbers, Turnover Frequencies, and Overpotential in Molecular Catalysis of Electrochemical Reactions. Cyclic Voltammetry and Preparative-Scale Electrolysis

(2012) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s-1 for H2 Production

(2011) M. L. Helm et al.   SCIENCE

H2Evolution and Molecular Electrocatalysts: Determination of Overpotentials and Effect of Homoconjugation

(2010) Vincent Fourmond et al.   INORGANIC CHEMISTRY