Atomic Layer Deposition of Textured Li4Ti5O12: A High-Power and Long-Cycle Life Anode for Lithium-Ion Thin-Film Batteries

The zero-strain Li4Ti5O12 is an attractive anode material for 3D solid-state thin-film batteries (TFB) to power upcoming autonomous sensor systems. Herein, Li4Ti5O12 thin films fabricated by atomic layer deposition (ALD) are electrochemically evaluated for the first time. The developed ALD process with a growth per cycle of 0.6 angstrom cycle(-1) at 300 degrees C enables high-quality and dense spinel films with superior adhesion after annealing. The short lithium-ion diffusion pathways of the nanostructured 30 nm films result in excellent electrochemical properties. Planar films reveal 98% of the theoretical capacity with 588 mAh cm(-3) at 1 C. Substrate-dependent film texture is identified as a key tuning parameter for exceptional C-rate performance. The highly parallel grains of a strong out-of-plane (111)-texture allow capacities of 278 mAh cm(-3) at extreme rates of 200 C. Outstanding cycle performance is demonstrated, resulting in 97.9% capacity retention of the initial 366 mAh cm(-3) after 1000 cycles at 100 C. Compared to other deposition techniques, the superior performance of ALD Li4Ti5O12 is a breakthrough towards scalable high-power 3D TFBs.

Automated summary

The zero-strain Li4Ti5O12 thin films fabricated by atomic layer deposition show excellent electrochemical properties, high capacity retention at extreme rates, and superior performance compared to other deposition techniques, making them a breakthrough in the development of scalable high-power 3D solid-state thin-film batteries.