Functional Group Directed B–H Activation of Polyhedral Boron Hydrides by Transition Metal Complexes (Review)

Fused 1,2-Diboraoxazoles Based on closo-Decaborate Anion–Novel Members of Diboroheterocycle Class

(2021) Vera V. Voinova et al.   MOLECULES

Selective B(5,8,9)-Triarylation Reaction of o-Carboranes through Determination of the Order of Introduction of Aryl Groups into B(4)-Acylamino-o-carboranes

(2021) Yonghyeon Baek et al.   ORGANIC LETTERS

Steric-Effects-Directed B–H Bond Activation of para-Carboranes

(2021) Peng-Fei Cui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition metal complexes with carboranylphosphine ligands

(2021) Igor B. Sivaev et al.   COORDINATION CHEMISTRY REVIEWS

Transition‐Metal‐Catalyzed Regioselective Functionalization of Monophosphino o‐Carboranes

(2020) Guang-Ao Yu et al.   CHEMISTRY-A EUROPEAN JOURNAL

One‐Pot Process to Carborano‐Coumarin via Catalytic CascadeDehydrogenative Cross‐Coupling

(2020) Yik Ki Au et al.   CHINESE JOURNAL OF CHEMISTRY

Chemistry of Carba-closo-decaborate Anions [CB9H10]– (Review)

(2020) A. V. Shmal’ko et al.   RUSSIAN JOURNAL OF INORGANIC CHEMISTRY

Iridium-Catalyzed Cyclative Indenylation and Dienylation through Sequential B(4)–C Bond Formation, Cyclization, and Elimination from o-Carboranes and Propargyl Alcohols

(2020) Yonghyeon Baek et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Electrochemical Selective B–H Oxygenation of o-Carboranes at Room Temperature

(2020) Yik Ki Au et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dihydrogen Bond Interaction Induced Separation of Hexane Isomers by Self-Assembled Carborane Metallacycles

(2020) Peng-Fei Cui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh‐catalyzed decarbonylative cross‐coupling between o‐carboranes and twisted amides: a regioselective, additive‐free and concise late‐stage carboranylation

(2020) Hong Yan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Strategic evolution in transition metal-catalyzed directed C–H bond activation and future directions

(2020) Supriya Rej et al.   COORDINATION CHEMISTRY REVIEWS

Palladium Catalyzed Selective B(3)–H Activation/Oxidative Dehydrogenative Coupling for the Synthesis of Bis(o-carborane)s

(2020) Ji Wu et al.   INORGANIC CHEMISTRY

Bis(dicarbollide) Complexes of Transition Metals as a Platform for Molecular Switches. Study of Complexation of 8,8′-Bis(methylsulfanyl) Derivatives of Cobalt and Iron Bis(dicarbollides)

(2020) Sergey A. Anufriev et al.   MOLECULES

Iridium-Catalyzed Cage B(4)-Amidation Reaction of o-Carboranes with Dioxazolones: Selective Synthesis of Amidated o-Carboranes and Amidated and Methoxycarbonylated nido-Carboranes

(2020) Gi Uk Han et al.   ORGANIC LETTERS

Catalytic Regioselective Cage B(8)–H Arylation of o-Carboranes via “Cage-Walking” Strategy

(2019) Hairong Lyu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Oxidative Dehydrogenative Coupling of Cage B–H/B–H Bonds for Synthesis of Bis(o-carborane)s

(2019) Ji Wu et al.   ORGANIC LETTERS

Rh-Catalyzed Regioselective Dialkylation of Cage B–H bonds in o-Carboranes: Oxidative Heck Reactions via an Enol Isomerization

(2019) Qian Wang et al.   ORGANIC LETTERS

Rhodium-Catalyzed Amidation of the Cage B(4)−H Bond in o-Carboranes with Dioxazolones by Carboxylic Acid-Assisted B(4)−H Bond Activation

(2019) Yonghyeon Baek et al.   ACS Catalysis

Iridium-Induced Regioselective B−H and C−C Activations at Azo-Substituted o -Carboranes

(2018) Yang Gao et al.   CHEMISTRY-A EUROPEAN JOURNAL

The closo -Dodecaborate Dianion Fused with Oxazoles Provides 3D Diboraheterocycles with Selective Antimicrobial Activity

(2018) Yuji Sun et al.   CHEMISTRY-A EUROPEAN JOURNAL

Triazole vs. triazolium carbene ligands in the site-selective cyclometallation of o-carboranes by M(iii) (M = Ir, Rh) complexes

(2018) María Frutos et al.   DALTON TRANSACTIONS

Expansion of the (BB)Ru metallacycle with coinage metal cations: formation of B–M–Ru–B (M = Cu, Ag, Au) dimetalacyclodiboryls

(2018) Bennett J. Eleazer et al.   Chemical Science

Pd(ii)-catalyzed synthesis of bifunctionalized carboranes via cage B–H activation of 1-CH2NH2-o-carboranes

(2018) Xiaolei Zhang et al.   Chemical Science

Rhodium(iii)-catalyzed dehydrogenative dialkenylation of the monocarba-closo-decaborate cluster by regioselective B–H activation

(2018) Xuewei Liang et al.   CHEMICAL COMMUNICATIONS

A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

(2018) Carlo Sambiagio et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Selective Five-Fold Cascade Arylation of the 12-Vertex Monocarborane Anion by B–H Activation

(2018) Furong Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper catalyzed/mediated direct B–H alkenylation/alkynylation in carboranes

(2018) Yu Chen et al.   Science China-Chemistry

Methylsulfanyl-Stabilized Rotamers of Cobalt Bis(dicarbollide)

(2017) Sergey A. Anufriev et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

POBOP pincer complexes of nickel(II): Synthesis and B H activation of the carborane ligand upon oxidation with iodine

(2017) Bennett J. Eleazer et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Selective Catalytic B–H Arylation of o-Carboranyl Aldehydes by a Transient Directing Strategy

(2017) Xiaolei Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pyridyl-Directed Cp*Rh(III)-Catalyzed B(3)–H Acyloxylation of o-Carborane

(2017) Chun-Xiao Li et al.   ORGANIC LETTERS

Rapid reversible borane to boryl hydride exchange by metal shuttling on the carborane cluster surface

(2017) Bennett J. Eleazer et al.   Chemical Science

Rhodium-Catalyzed Regioselective Hydroxylation of Cage B−H Bonds ofo-Carboranes with O2or Air

(2016) Hairong Lyu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Alkenylation-Annulation ofcloso-Dodecaborate Anions through Double B−H Activation at Room Temperature

(2016) Yuanbin Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Inductive effects of 10 and 12-vertex closo-carborane anions: cluster size and charge make a difference

(2016) Jess Estrada et al.   CHEMICAL COMMUNICATIONS

Synthesis, Reactivity and Application of Diverse Carboranylphosphine-Based Ligands

(2016) Kuan Li et al.   CURRENT ORGANIC SYNTHESIS

Transition Metal Catalyzed Direct Amination of the Cage B(4)–H Bond in o-Carboranes: Synthesis of Tertiary, Secondary, and Primary o-Carboranyl Amines

(2016) Hairong Lyu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

(BB)-Carboryne Complex of Ruthenium: Synthesis by Double B–H Activation at a Single Metal Center

(2016) Bennett J. Eleazer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Changing the Charge: Electrostatic Effects in Pd-Catalyzed Cross-Coupling

(2016) Allen L. Chan et al.   ORGANOMETALLICS

Metal- and Ligand-Centered Reactivity of meta-Carboranyl-Backbone Pincer Complexes of Rhodium

(2016) Bennett J. Eleazer et al.   ORGANOMETALLICS

Palladium catalyzed regioselective B–C(sp) coupling via direct cage B–H activation: synthesis of B(4)-alkynylated o-carboranes

(2016) Yangjian Quan et al.   Chemical Science

Palladium-Catalyzed Regioselective Diarylation of o -Carboranes By Direct Cage B−H Activation

(2015) Yangjian Quan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Direct Dialkenylation of Cage BH Bonds in o -Carboranes through Cross-Coupling Reactions

(2015) Hairong Lyu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of a Hybrid m-Terphenyl/o-Carborane Building Block: Applications in Phosphine Ligand Design

(2015) Christopher A. Lugo et al.   INORGANIC CHEMISTRY

Synthesis, characterization, and preliminary fluorescence study of a mixed-ligand bis(dicarbollyl)nickel complex bearing a tryptophan-BODIPY FRET couple

(2015) Natalia I. Shlyakhtina et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Resisting B–H oxidative addition: The divergent reactivity of the o -carborane and carba- closo -dodecaborate ligand substituents

(2015) Jess Estrada et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Metal promoted charge and hapticities of phosphines: The uniqueness of carboranylphosphines

(2014) Adrian R. Popescu et al.   COORDINATION CHEMISTRY REVIEWS

Direct Observation of Bis(dicarbollyl)nickel Conformers in Solution by Fluorescence Spectroscopy: An Approach to Redox-Controlled Metallacarborane Molecular Motors

(2014) Alexander V. Safronov et al.   INORGANIC CHEMISTRY

Iridium Catalyzed Regioselective Cage Boron Alkenylation of o-Carboranes via Direct Cage B–H Activation

(2014) Yangjian Quan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Mediated Regioselective B–H/C–H Activation of Carborane Cage: A Facile Synthetic Route to Metallacycles with a Carborane Backbone

(2014) Zi-Jian Yao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Update 1 of: Chemistry of the Carba-closo-dodecaborate(−) Anion, CB11H12–

(2013) Christos Douvris et al.   CHEMICAL REVIEWS

Structure and Bonding of a Zwitterionic Iridium Complex Supported by a Phosphine with the Parent Carba-closo-dodecaborate CB11H11– Ligand Substituent

(2013) Ahmad El-Hellani et al.   ORGANOMETALLICS

Regioselective B-Cyclometalation of a Bulky o-Carboranyl Phosphine and the Unexpected Formation of a Dirhodium(II) Complex

(2012) Natalie Fey et al.   ORGANOMETALLICS

Derivatives of closo-decaborate anion [B10H10]2− with exo-polyhedral substituents

(2011) K. Yu. Zhizhin et al.   RUSSIAN JOURNAL OF INORGANIC CHEMISTRY

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

The Versatile Coordination Modes of Monophosphine-o-Carborane in the Formation of Iridium and Rhodium Complexes: Synthesis, Reactivity, and Characterization

(2010) Xian-Kuan Huo et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cyclometalation Using d-Block Transition Metals: Fundamental Aspects and Recent Trends

(2009) Martin Albrecht   CHEMICAL REVIEWS