Enantioselective Reductive Homocoupling of Allylic Acetates Enabled by Dual Photoredox/Palladium Catalysis: Access to C2-Symmetrical 1,5-Dienes

Palladium-Catalyzed Allyl–Allyl Reductive Coupling of Allylamines or Allylic Alcohols with H2 as Sole Reductant

(2021) Xibing Zhou et al.   ORGANIC LETTERS

Dual Ni/photoredox-catalyzed asymmetric cross-coupling to access chiral benzylic boronic esters

(2021) Purui Zheng et al.   Nature Communications

Dual Palladium/Photoredox-Catalyzed Enantioselective and Regioselective Decarboxylative Hydroaminoalkylation of Allenes

(2021) Jun Zheng et al.   ACS Catalysis

Nickel/Photoredox-Catalyzed Asymmetric Reductive Cross-Coupling of Racemic α-Chloro Esters with Aryl Iodides

(2020) Haixing Guan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Alkyl–Alkyl Cross-Electrophile Coupling Reaction of 1,3-Dimesylates for the Synthesis of Alkylcyclopropanes

(2020) Amberly B. Sanford et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoredox/Nickel Dual-Catalyzed Reductive Cross Coupling of Aryl Halides Using an Organic Reducing Agent

(2020) Abhishek Dewanji et al.   ORGANIC LETTERS

Catalyst-controlled doubly enantioconvergent coupling of racemic alkyl nucleophiles and electrophiles

(2020) Haohua Huo et al.   SCIENCE

Synthesis of β-Phenethylamines via Ni/Photoredox Cross-Electrophile Coupling of Aliphatic Aziridines and Aryl Iodides

(2020) Talia J. Steiman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereodivergent Pd/Cu Catalysis for the Dynamic Kinetic Asymmetric Transformation of Racemic Unsymmetrical 1,3-Disubstituted Allyl Acetates

(2020) Rui He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Homo- and Cross-Coupling of Allyl Alcohols via Allyl Boronates

(2020) Yi Gan et al.   ORGANIC LETTERS

Dehydrative Allylation of α C(sp3)–H Bonds of Alkylamines with Allylic Alcohols

(2020) Yusuke Masuda et al.   ORGANIC LETTERS

A review of enantioselective dual transition metal/photoredox catalysis

(2020) Hong-Hao Zhang et al.   Science China-Chemistry

Photoredox/palladium-cocatalyzed enantioselective alkylation of secondary benzyl carbonates with 4-alkyl-1,4-dihydropyridines

(2020) Xu Shen et al.   Science China-Chemistry

Enantioselective α-Allylation of Anilines Enabled by a Combined Palladium and Photoredox Catalytic System

(2020) Hong-Hao Zhang et al.   ACS Catalysis

Regioselective Cross-Electrophile Coupling of Epoxides and (Hetero)aryl Iodides via Ni/Ti/Photoredox Catalysis

(2020) Marvin Parasram et al.   ACS Catalysis

Stereoinduction in Metallaphotoredox Catalysis

(2020) Alexander Lipp et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Enantioselective Reductive Cross-Coupling Reactions

(2020) Kelsey E. Poremba et al.   ACS Catalysis

Highly Enantioselective Cross-Electrophile Aryl-Alkenylation of Unactivated Alkenes

(2019) Zhi-Xiong Tian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Deaminative Reductive Arylation Enabled by Nickel/Photoredox Dual Catalysis

(2019) Jun Yi et al.   ORGANIC LETTERS

Visible-Light-Enabled Stereodivergent Synthesis of E - and Z -Configured 1,4-Dienes by Photoredox/Nickel Dual Catalysis

(2019) Fan Song et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synergistic Photoredox/Transition-Metal Catalysis for Carbon-Carbon Bond Formation Reactions

(2019) Maxime De Abreu et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Continuous Flow Enables Metallaphotoredox Catalysis in a Medicinal Chemistry Setting: Accelerated Optimization and Library Execution of a Reductive Coupling between Benzylic Chlorides and Aryl Bromides

(2019) Zachary G. Brill et al.   ORGANIC LETTERS

Cis-Selective Decarboxylative Alkenylation of Aliphatic Carboxylic Acids with Vinyl Arenes Enabled by Photoredox/Palladium/Uphill Triple Catalysis

(2018) Chao Zheng et al.   ORGANIC LETTERS

Nickel-Catalyzed Desymmetrizing Cross-Electrophile Coupling of Cyclic Meso-Anhydrides

(2018) Tingzhi Lin et al.   ORGANIC LETTERS

Photochemical Nickel-Catalyzed Reductive Migratory Cross-Coupling of Alkyl Bromides with Aryl Bromides

(2018) Long Peng et al.   ORGANIC LETTERS

Dual nickel and Lewis acid catalysis for cross-electrophile coupling: the allylation of aryl halides with allylic alcohols

(2018) Xue-Gong Jia et al.   Chemical Science

Recent Advances in Alkyl Carbon-Carbon Bond Formation by Nickel/Photoredox Cross-Coupling

(2018) Gary Molander et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metallaphotoredox-Catalyzed Cross-Electrophile Csp3–Csp3 Coupling of Aliphatic Bromides

(2018) Russell T. Smith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Allylic Alkylation with 4-Alkyl-1,4-dihydro-pyridines Enabled by Photoredox/Palladium Cocatalysis

(2018) Hong-Hao Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Enantioselective Allyl–Allyl Cross-Coupling of Racemic Allylic Alcohols with Allylboronates

(2018) Yu Zheng et al.   ORGANIC LETTERS

Photoredox-Assisted Reductive Cross-Coupling: Mechanistic Insight into Catalytic Aryl–Alkyl Cross-Couplings

(2017) Avishek Paul et al.   JOURNAL OF ORGANIC CHEMISTRY

Visible-Light-Driven Carboxylation of Aryl Halides by the Combined Use of Palladium and Photoredox Catalysts

(2017) Katsuya Shimomaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Asymmetric Reductive Cross-Coupling To Access 1,1-Diarylalkanes

(2017) Kelsey E. Poremba et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition metal–catalyzed alkyl-alkyl bond formation: Another dimension in cross-coupling chemistry

(2017) Junwon Choi et al.   SCIENCE

Merger of Visible-Light Photoredox Catalysis and C–H Activation for the Room-Temperature C-2 Acylation of Indoles in Batch and Flow

(2017) Upendra K. Sharma et al.   ACS Catalysis

Stereospecific and stereoconvergent cross-couplings between alkyl electrophiles

(2017) Erika L. Lucas et al.   Nature Reviews Chemistry

The merger of transition metal and photocatalysis

(2017) Jack Twilton et al.   Nature Reviews Chemistry

Single-Electron Transmetalation via Photoredox/Nickel Dual Catalysis: Unlocking a New Paradigm for sp3–sp2 Cross-Coupling

(2016) John C. Tellis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-Catalyzed Asymmetric Benzylic Alkylation of Active Methylene Compounds with α-Naphthylbenzyl Carbonates and Pivalates

(2016) Sho Tabuchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Enantioselective Allyl-Allyl Coupling between Allylic Boronates and Phosphates with a Phenol/N-Heterocyclic Carbene Chiral Ligand

(2016) Yuto Yasuda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organic Photoredox Catalysis

(2016) Nathan A. Romero et al.   CHEMICAL REVIEWS

Dual Catalysis Strategies in Photochemical Synthesis

(2016) Kazimer L. Skubi et al.   CHEMICAL REVIEWS

Aryl Ketones as Single-Electron-Transfer Photoredox Catalysts in the Nickel-Catalyzed Homocoupling of Aryl Halides

(2016) Yusuke Masuda et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Nickel-Catalyzed Cross-Electrophile Coupling of Alkyl Fluorides: Stereospecific Synthesis of Vinylcyclopropanes

(2016) Lucas W. Erickson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silyl Radical Activation of Alkyl Halides in Metallaphotoredox Catalysis: A Unique Pathway for Cross-Electrophile Coupling

(2016) Patricia Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Reductive Cross-Coupling of Aryl Bromides with Alkyl Bromides: Et3N as the Terminal Reductant

(2016) Zhengli Duan et al.   ORGANIC LETTERS

A general, modular method for the catalytic asymmetric synthesis of alkylboronate esters

(2016) J. Schmidt et al.   SCIENCE

Nickel-Catalyzed Reductive Couplings

(2016) Xuan Wang et al.   Topics in Current Chemistry

Methods and Mechanisms for Cross-Electrophile Coupling of Csp2 Halides with Alkyl Electrophiles

(2015) Daniel J. Weix   ACCOUNTS OF CHEMICAL RESEARCH

Amine Functionalization via Oxidative Photoredox Catalysis: Methodology Development and Complex Molecule Synthesis

(2015) Joel W. Beatty et al.   ACCOUNTS OF CHEMICAL RESEARCH

Enantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C–C Bonds

(2015) Alan H. Cherney et al.   CHEMICAL REVIEWS

Dual Catalytic Decarboxylative Allylations of α-Amino Acids and Their Divergent Mechanisms

(2015) Simon B. Lang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Room-Temperature Decarboxylative Couplings of α-Oxocarboxylates with Aryl Halides by Merging Photoredox with Palladium Catalysis

(2015) Wan-Min Cheng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of 2,5-Diaryl-1,5-dienes from Allylic Bromides Using Visible-Light Photoredox Catalysis

(2015) Gerald Pratsch et al.   JOURNAL OF ORGANIC CHEMISTRY

Stereospecific Intramolecular Reductive Cross-Electrophile Coupling Reactions for Cyclopropane Synthesis

(2015) Emily J. Tollefson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Asymmetric Reductive Cross-Coupling between Heteroaryl Iodides and α-Chloronitriles

(2015) Nathaniel T. Kadunce et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Reductive Coupling of Aryl Bromides with Tertiary Alkyl Halides

(2015) Xuan Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multimetallic catalysed cross-coupling of aryl bromides with aryl triflates

(2015) Laura K. G. Ackerman et al.   NATURE

Merging Photoredox with Palladium Catalysis: Decarboxylative ortho-Acylation of Acetanilides with α-Oxocarboxylic Acids under Mild Reaction Conditions

(2015) Chao Zhou et al.   ORGANIC LETTERS

Synthesis of Carbazoles by a Merged Visible Light Photoredox and Palladium-Catalyzed Process

(2015) Sungkyu Choi et al.   ACS Catalysis

Nickel-catalyzed reductive coupling of alkyl halides with other electrophiles: concept and mechanistic considerations

(2015) Jun Gu et al.   Organic Chemistry Frontiers

Iridium-Catalyzed Enantioselective Allyl-Allylsilane Cross-Coupling

(2014) James Y. Hamilton et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox-Neutral α-Allylation of Amines by Combining Palladium Catalysis and Visible-Light Photoredox Catalysis

(2014) Jun Xuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reductive Cross-Coupling Reactions between Two Electrophiles

(2014) Christiane E. I. Knappke et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metal-Catalyzed Reductive Coupling Reactions of Organic Halides with Carbonyl-Type Compounds

(2014) Toni Moragas et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nickel-Catalyzed Asymmetric Reductive Cross-Coupling Between Vinyl and Benzyl Electrophiles

(2014) Alan H. Cherney et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Congested C–C Bonds by Pd-Catalyzed Enantioselective Allyl–Allyl Cross-Coupling, a Mechanism-Guided Solution

(2014) Michael J. Ardolino et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Decarboxylative Allylation of Amino Alkanoic Acids and Esters via Dual Catalysis

(2014) Simon B. Lang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Stereospecific Allyl–Allyl Cross-Coupling of Internal Allyl Electrophiles with AllylB(pin)

(2014) Hai Le et al.   ORGANIC LETTERS

Enantioselective Allylic Amination of Trifluoromethyl Group Substituted Racemic and Unsymmetrical 1,3-Disubstituted Allylic Esters by Palladium Catalysts

(2014) Motoi Kawatsura et al.   ORGANIC LETTERS

Solar Synthesis: Prospects in Visible Light Photocatalysis

(2014) D. M. Schultz et al.   SCIENCE

Hydrogen-Bond-Promoted Palladium Catalysis: Allylic Alkylation of Indoles with Unsymmetrical 1,3-Disubstituted Allyl Acetates Using Chiral Bis(sulfoxide) Phosphine Ligands

(2013) Le Du et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The chemistry of amine radical cations produced by visible light photoredox catalysis

(2013) Jie Hu et al.   Beilstein Journal of Organic Chemistry

Radical Pd(iii)/Pd(i) reductive elimination in palladium sequences

(2013) Giovanni Maestri et al.   CHEMICAL COMMUNICATIONS

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

(2013) Christopher K. Prier et al.   CHEMICAL REVIEWS

Enantioconvergent Cross-Couplings of Racemic Alkylmetal Reagents with Unactivated Secondary Alkyl Electrophiles: Catalytic Asymmetric Negishi α-Alkylations of N-Boc-pyrrolidine

(2013) Christopher J. Cordier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism and Selectivity in Nickel-Catalyzed Cross-Electrophile Coupling of Aryl Halides with Alkyl Halides

(2013) Soumik Biswas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Reductive Acyl Cross-Coupling: Synthesis of Enantioenriched Acyclic α,α-Disubstituted Ketones

(2013) Alan H. Cherney et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Enantioselective Allyl–Allyl Cross-Coupling

(2013) Valentín Hornillos et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Combining Transition Metal Catalysis with Radical Chemistry: Dramatic Acceleration of Palladium-Catalyzed CH Arylation with Diaryliodonium Salts

(2012) Sharon R. Neufeldt et al.   ADVANCED SYNTHESIS & CATALYSIS

Visible-Light Photoredox Catalysis

(2012) Jun Xuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Cross-Couplings of Secondary Alkyl Electrophiles with Secondary Alkylmetal Nucleophiles: Negishi Reactions of Racemic Benzylic Bromides with Achiral Alkylzinc Reagents

(2012) Jörg T. Binder et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A gold-catalysed enantioselective Cope rearrangement of achiral 1,5-dienes

(2012) Ryan J. Felix et al.   Nature Chemistry

Nickel-Catalyzed Reductive Coupling of Aryl Halides with Secondary Alkyl Bromides and Allylic Acetate

(2012) Shulin Wang et al.   ORGANIC LETTERS

Synthesis of Chiral Olefin Ligands and their Application in Asymmetric Catalysis

(2012) Xiangqing Feng et al.   Asian Journal of Organic Chemistry

Catalytic intermolecular allyl–allyl cross-couplings between alcohols and boronates

(2011) Agustín Jiménez-Aquino et al.   CHEMICAL COMMUNICATIONS

Advances in Transition Metal (Pd,Ni,Fe)-Catalyzed Cross-Coupling Reactions Using Alkyl-organometallics as Reaction Partners

(2011) Ranjan Jana et al.   CHEMICAL REVIEWS

Diastereocontrol in Asymmetric Allyl–Allyl Cross-Coupling: Stereocontrolled Reaction of Prochiral Allylboronates with Prochiral Allyl Chlorides

(2011) Laura A. Brozek et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Construction of All-Carbon Quaternary Centers by Branch-Selective Pd-Catalyzed Allyl–Allyl Cross-Coupling

(2011) Ping Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Room-Temperature C–H Arylation: Merger of Pd-Catalyzed C–H Functionalization and Visible-Light Photocatalysis

(2011) Dipannita Kalyani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Reductive Cross-Coupling of Unactivated Alkyl Halides

(2011) Xiaolong Yu et al.   ORGANIC LETTERS

Development of Bicyclo[3.3.0]octadiene- or Dicyclopentadiene-Based Chiral Diene Ligands for Transition-Metal-Catalyzed Reactions

(2011) Guo-Qiang Lin et al.   SYNLETT

Nickel-catalyzed cross coupling of non-activated alkyl halides: a mechanistic perspective

(2011) Xile Hu   Chemical Science

Nickel-catalyzed, sodium iodide-promoted reductive dimerization of alkyl halides, alkyl pseudohalides, and allylic acetates

(2010) Michael R. Prinsell et al.   CHEMICAL COMMUNICATIONS

Visible light photoredox catalysis: applications in organic synthesis

(2010) Jagan M. R. Narayanam et al.   CHEMICAL SOCIETY REVIEWS

Pd-Catalyzed Enantioselective Allyl−Allyl Cross-Coupling

(2010) Ping Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Reductive Cross-Coupling of Aryl Halides with Alkyl Halides

(2010) Daniel A. Everson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Allylic Substitution of Simple Alkenes

(2010) Ryosuke Matsubara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bimetallic Reductive Elimination from Dinuclear Pd(III) Complexes

(2010) David C. Powers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Secondary Alkyl Halides in Transition-Metal-Catalyzed Cross-Coupling Reactions

(2009) Alena Rudolph et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(0) versus Nickel(0) Catalysis in Selective Functional-Group-Tolerant sp3-sp3Carbon-Carbon Bond Formations

(2009) Emmanuel Ferrer Flegeau et al.   CHEMISTRY-A EUROPEAN JOURNAL

Bimetallic Pd(III) complexes in palladium-catalysed carbon–heteroatom bond formation

(2009) David C. Powers et al.   Nature Chemistry

Asymmetric Cross-Coupling of Non-Activated Secondary Alkyl Halides

(2008) Frank Glorius   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold-Catalyzed Allyl–Allyl Coupling

(2008) Susana Porcel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Olefins as Steering Ligands in Asymmetric Catalysis

(2008) Christian Defieber et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Asymmetric Negishi Cross-Couplings of Secondary Allylic Chlorides with Alkylzincs

(2008) Sunghee Son et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Alkyl−Alkyl Suzuki Cross-Couplings of Unactivated Homobenzylic Halides

(2008) Bunnai Saito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY