Oriented Electrostatic Effects on O2 and CO2 Reduction by a Polycationic Iron Porphyrin

All Four Atropisomers of Iron Tetra(o-N,N,N-trimethylanilinium)porphyrin in Both the Ferric and Ferrous States

(2021) Daniel J. Martin et al.   INORGANIC CHEMISTRY

Double Hangman Iron Porphyrin and the Effect of Electrostatic Nonbonding Interactions on Carbon Dioxide Reduction

(2020) Charles G. Margarit et al.   Journal of Physical Chemistry Letters

Rare-Earth Supported Nickel Catalysts for Alkyne Semihydrogenation: Chemo- and Regioselectivity Impacted by the Lewis Acidity and Size of the Support

(2020) Bianca L. Ramirez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Developing Scaling Relationships for Molecular Electrocatalysis through Studies of Fe-Porphyrin-Catalyzed O2 Reduction

(2020) Daniel J. Martin et al.   ACCOUNTS OF CHEMICAL RESEARCH

Combining scaling relationships overcomes rate versus overpotential trade-offs in O2 molecular electrocatalysis

(2020) Daniel J. Martin et al.   Science Advances

Controlling the Oxygen Reduction Selectivity of Asymmetric Cobalt Porphyrins by Using Local Electrostatic Interactions

(2020) Rui Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular Electrostatic Effects on O2, CO2, and Acetate Binding to a Cationic Iron Porphyrin

(2020) Daniel J. Martin et al.   INORGANIC CHEMISTRY

Mechanism of Catalytic O2 Reduction by Iron Tetraphenylporphyrin

(2019) Michael L. Pegis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Harnessing electrostatic catalysis in single molecule, electrochemical and chemical systems: a rapidly growing experimental tool box

(2018) Simone Ciampi et al.   CHEMICAL SOCIETY REVIEWS

Incorporation of redox-inactive cations promotes iron catalyzed aerobic C–H oxidation at mild potentials

(2018) Teera Chantarojsiri et al.   Chemical Science

Cationic Charges Lead to Inverse Free Energy Relationship for N-N Bond Formation by Mn(VI) Nitrides

(2018) Teera Chantarojsiri et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Practical Beginner’s Guide to Cyclic Voltammetry

(2017) Noémie Elgrishi et al.   JOURNAL OF CHEMICAL EDUCATION

Identifying and Breaking Scaling Relations in Molecular Catalysis of Electrochemical Reactions

(2017) Michael L. Pegis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-light-driven methane formation from CO2 with a molecular iron catalyst

(2017) Heng Rao et al.   NATURE

Dissection of Electronic Substituent Effects in Multielectron–Multistep Molecular Catalysis. Electrochemical CO2-to-CO Conversion Catalyzed by Iron Porphyrins

(2016) Iban Azcarate et al.   Journal of Physical Chemistry C

Through-Space Charge Interaction Substituent Effects in Molecular Catalysis Leading to the Design of the Most Efficient Catalyst of CO2-to-CO Electrochemical Conversion

(2016) Iban Azcarate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactions triggered electrically

(2016) Limin Xiang et al.   NATURE

Oriented electric fields as future smart reagents in chemistry

(2016) Sason Shaik et al.   Nature Chemistry

Homogenous Electrocatalytic Oxygen Reduction Rates Correlate with Reaction Overpotential in Acidic Organic Solutions

(2016) Michael L. Pegis et al.   ACS Central Science

Current Issues in Molecular Catalysis Illustrated by Iron Porphyrins as Catalysts of the CO2-to-CO Electrochemical Conversion

(2015) Cyrille Costentin et al.   ACCOUNTS OF CHEMICAL RESEARCH

Tuning Nickel with Lewis Acidic Group 13 Metalloligands for Catalytic Olefin Hydrogenation

(2015) Ryan C. Cammarota et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrochemical Reduction of Brønsted Acids by Glassy Carbon in Acetonitrile—Implications for Electrocatalytic Hydrogen Evolution

(2014) Brian D. McCarthy et al.   INORGANIC CHEMISTRY

Evaluation of Homogeneous Electrocatalysts by Cyclic Voltammetry

(2014) Eric S. Rountree et al.   INORGANIC CHEMISTRY

Pendant Acid–Base Groups in Molecular Catalysts: H-Bond Promoters or Proton Relays? Mechanisms of the Conversion of CO2 to CO by Electrogenerated Iron(0)Porphyrins Bearing Prepositioned Phenol Functionalities

(2014) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multielectron, Multistep Molecular Catalysis of Electrochemical Reactions: Benchmarking of Homogeneous Catalysts

(2014) Cyrille Costentin et al.   ChemElectroChem

Redox-inactive metals modulate the reduction potential in heterometallic manganese–oxido clusters

(2013) Emily Y. Tsui et al.   Nature Chemistry

Turnover Numbers, Turnover Frequencies, and Overpotential in Molecular Catalysis of Electrochemical Reactions. Cyclic Voltammetry and Preparative-Scale Electrolysis

(2012) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Local Proton Source Enhances CO2 Electroreduction to CO by a Molecular Fe Catalyst

(2012) C. Costentin et al.   SCIENCE

Degree of Rate Control: How Much the Energies of Intermediates and Transition States Control Rates

(2009) Carsten Stegelmann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects

(2008) Jean-Michel Savéant   CHEMICAL REVIEWS

Kinetic-Quantum Chemical Model for Catalytic Cycles: The Haber−Bosch Process and the Effect of Reagent Concentration

(2008) Sebastian Kozuch et al.   JOURNAL OF PHYSICAL CHEMISTRY A