Cobalt-Catalyzed Diastereo- and Enantioselective Reductive Allyl Additions to Aldehydes with Allylic Alcohol Derivatives via Allyl Radical Intermediates

Enantioselective Formation of Quaternary Centers by Allylic Alkylation with First-Row Transition-Metal Catalysts

(2021) Lars Süsse et al.   CHEMICAL REVIEWS

Photocatalytic Umpolung Synthesis of Nucleophilic π-Allylcobalt Complexes for Allylation of Aldehydes

(2021) Caizhe Shi et al.   ACS Catalysis

Expedient Dual Co/Organophotoredox Catalyzed Stereoselective Synthesis of All‐Carbon Quaternary Centers

(2021) Alex Cristofol et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Advances in Enantioselective Pd-Catalyzed Allylic Substitution: From Design to Applications

(2021) Oscar Pàmies et al.   CHEMICAL REVIEWS

Mechanism of Cobalt-Catalyzed Heterodimerization of Acrylates and 1,3-Dienes. A Potential Role of Cationic Cobalt(I) Intermediates

(2020) Montgomery Gray et al.   ACS Catalysis

Chiral Phosphoric Acid Dual‐Function Catalysis: Asymmetric Allylation with α‐Vinyl Allylboron Reagents

(2020) Shang Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Catalytic Dual Isomerization/Allylboration Sequence for the Stereoselective Construction of Congested Secondary Homoallylic Alcohols

(2020) Yangbin Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Cobalt-Catalyzed Regio- and Enantioselective Allylic Alkylation of Malononitriles

(2020) Samir Ghorai et al.   ORGANIC LETTERS

Enantioselective Synthesis of cis ‐2,6‐Disubstituted‐4‐methylene Tetrahydropyrans via Chromium Catalysis

(2020) Jing Bai et al.   CHINESE JOURNAL OF CHEMISTRY

Catalytic Allylation of Aldehydes Using Unactivated Alkenes

(2020) Shun Tanabe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt‐Catalyzed Diastereo‐ and Enantioselective Hydroalkylation of Cyclopropenes with Cobalt‐Homoenolates

(2020) Wei Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bi(cyclopentyl)diol-Derived Boronates in Highly Enantioselective Chiral Phosphoric Acid-Catalyzed Allylation, Propargylation, and Crotylation of Aldehydes

(2020) Jinping Yuan et al.   JOURNAL OF ORGANIC CHEMISTRY

Nontoxic Cobalt(III) Schiff Base Complexes with Broad‐Spectrum Antifungal Activity

(2020) Angelo Frei et al.   CHEMISTRY-A EUROPEAN JOURNAL

Diastereo-, Enantio-, and anti-Selective Formation of Secondary Alcohol and Quaternary Carbon Stereocenters by Cu-Catalyzed Additions of B-Substituted Allyl Nucleophiles to Carbonyls

(2020) Emilie Wheatley et al.   ORGANIC LETTERS

Construction of Vicinal Quaternary Carbon Centers via Cobalt-Catalyzed Asymmetric Reverse Prenylation

(2019) Minghe Sun et al.   ORGANIC LETTERS

Iridium-Catalyzed Asymmetric Synthesis of Functionally Rich Molecules Enabled by (Phosphoramidite,Olefin) Ligands

(2019) Simon L. Rössler et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cobalt-Catalyzed Diastereo- and Enantioselective Hydroalkenylation of Cyclopropenes with Alkenylboronic Acids

(2019) Haiyan Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Feedstock Reagents in Metal-Catalyzed Carbonyl Reductive Coupling: Minimizing Preactivation for Efficiency in Target-Oriented Synthesis

(2019) Rosalie S. Doerksen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-Catalyzed Regio- and Enantioselective Allylic Amination

(2019) Samir Ghorai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Syntheses of 1,4-Pentadien-3-yl Carbinols via Brønsted Acid Catalysis

(2019) Shang Gao et al.   ORGANIC LETTERS

Intermolecular Metal-Catalyzed Reductive Coupling of Dienes, Allenes, and Enynes with Carbonyl Compounds and Imines

(2018) Michael Holmes et al.   CHEMICAL REVIEWS

Catalytic nucleophilic ‘umpoled’ π-allyl reagents

(2018) Kim Spielmann et al.   CHEMICAL SOCIETY REVIEWS

Enantioselective 1,2-Difunctionalization of 1,3-Butadiene by Sequential Alkylation and Carbonyl Allylation

(2018) Yang Xiong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-catalyzed reductive electrocarboxylation of allyl esters with carbon dioxide

(2018) Ke-Jin Jiao et al.   Organic Chemistry Frontiers

Iridium-Catalyzed Asymmetric Allylic Substitution Reactions

(2018) Qiang Cheng et al.   CHEMICAL REVIEWS

Natural-Products-Inspired Use of the gem-Dimethyl Group in Medicinal Chemistry

(2017) Tanaji T. Talele   JOURNAL OF MEDICINAL CHEMISTRY

Enantioselective Formation of CF3-Bearing All-Carbon Quaternary Stereocenters via C–H Functionalization of Methanol: Iridium Catalyzed Allene Hydrohydroxymethylation

(2017) Michael Holmes et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Toxicity of Metal Compounds: Knowledge and Myths

(2017) Ksenia S. Egorova et al.   ORGANOMETALLICS

Barbier-type anti-Diastereo- and Enantioselective Synthesis of β-Trimethylsilyl, Fluorinated Methyl, Phenylthio Homoallylic Alcohols

(2017) Rui Guo et al.   Scientific Reports

Enantioselective Formation of All-Carbon Quaternary Centers via C–H Functionalization of Methanol: Iridium-Catalyzed Diene Hydrohydroxymethylation

(2016) Khoa D. Nguyen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydroxymethylation beyond Carbonylation: Enantioselective Iridium-Catalyzed Reductive Coupling of Formaldehyde with Allylic Acetates via Enantiotopic π-Facial Discrimination

(2016) Victoria J. Garza et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Quaternary Stereocenters via Chromium Catalysis

(2016) Yang Xiong et al.   ORGANIC LETTERS

Polystyrene-Supported TRIP: A Highly Recyclable Catalyst for Batch and Flow Enantioselective Allylation of Aldehydes

(2016) Lidia Clot-Almenara et al.   ACS Catalysis

Cobalt-Catalyzed Allylation of Heterobicyclic Alkenes: Ligand-Induced Divergent Reactivities

(2015) Yuan Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Vitamin B12 catalysed reactions

(2015) Maciej Giedyk et al.   CHEMICAL SOCIETY REVIEWS

Diastereo- and Enantioselective Iridium Catalyzed Carbonyl (α-Cyclopropyl)allylation via Transfer Hydrogenation

(2015) Ryosuke Tsutsumi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Synthesis of α-exo-Methylene γ-Butyrolactones via Chromium Catalysis

(2015) Weiqiang Chen et al.   ORGANIC LETTERS

Ni-catalyzed asymmetric reductive allylation of aldehydes with allylic carbonates

(2014) Zhuozhen Tan et al.   CHEMICAL COMMUNICATIONS

Redox-Triggered C–C Coupling of Alcohols and Vinyl Epoxides: Diastereo- and Enantioselective Formation of All-Carbon Quaternary Centers via tert-(Hydroxy)-Prenylation

(2014) Jiajie Feng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydroxyl-Directed Stereoselective Diboration of Alkenes

(2014) Thomas P. Blaisdell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic asymmetric allylation of carbonyl compounds and imines with allylic boronates

(2014) Hua-Xing Huo et al.   Organic Chemistry Frontiers

Diastereoselective Allylation of Carbonyl Compounds and Imines: Application to the Synthesis of Natural Products

(2013) Miguel Yus et al.   CHEMICAL REVIEWS

Catalytic Enantioselective Allylation of Carbonyl Compounds and Imines

(2011) Miguel Yus et al.   CHEMICAL REVIEWS

Total Synthesis of Penostatin B

(2011) Kosuke Fujioka et al.   ORGANIC LETTERS

Highly enantioselective palladium-catalyzed umpolung allylation of aldehydes

(2011) Shou-Fei Zhu et al.   Chemical Science

anti-Diastereo- and Enantioselective Carbonyl (Hydroxymethyl)allylation from the Alcohol or Aldehyde Oxidation Level: Allyl Carbonates as Allylmetal Surrogates

(2010) Yong Jian Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diastereo- and Enantioselectiveanti-Alkoxyallylation Employing Allylicgem-Dicarboxylates as Allyl Donors via Iridium-Catalyzed Transfer Hydrogenation

(2010) Soo Bong Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-catalyzed asymmetric umpolung allylation of imines with allylic alcohols

(2010) Xiang-Chen Qiao et al.   TETRAHEDRON-ASYMMETRY

Enantioselective Carbonyl Reverse Prenylation from the Alcohol or Aldehyde Oxidation Level Employing 1,1-Dimethylallene as the Prenyl Donor

(2009) Soo Bong Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

anti-Diastereo- and Enantioselective Carbonyl Crotylation from the Alcohol or Aldehyde Oxidation Level Employing a Cyclometallated Iridium Catalyst: α-Methyl Allyl Acetate as a Surrogate to Preformed Crotylmetal Reagents

(2009) In Su Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

From allylic alcohols to chiral tertiary homoallylic alcohol: palladium-catalyzed asymmetric allylation of isatins

(2009) Xiang-Chen Qiao et al.   TETRAHEDRON-ASYMMETRY

Enantioselective Iridium-Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level Using Allyl Acetate as an Allyl Metal Surrogate

(2008) In Su Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY