Heterolytic Oxidative Addition of sp2 and sp3 C–H Bonds by Metal–Ligand Cooperation with an Electron-Deficient Cyclopentadienone Iridium Complex

Bifunctional beginnings

(2021) Rosie J. Somerville   Nature Reviews Chemistry

Umpolung of B−H Bonds by Metal–Ligand Cooperation with Cyclopentadienone Iridium Complexes

(2020) Takuya Higashi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal–Ligand Cooperative C–H Bond Formation by Cyclopentadienone Platinum Complexes

(2019) Takuya Higashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cleavage of Si–H, B–H, and C–H Bonds by Metal–Ligand Cooperation

(2019) Takuya Higashi et al.   CHEMICAL REVIEWS

Formal oxidative addition of a C–H bond by a 16e iridium(i) complex involves metal–ligand cooperation

(2018) Amit Kumar et al.   CHEMICAL COMMUNICATIONS

[2,2′-Bipyridin]-6(1H)-one, a Truly Cooperating Ligand in the Palladium-Mediated C–H Activation Step: Experimental Evidence in the Direct C-3 Arylation of Pyridine

(2018) Vanesa Salamanca et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Ligand Cooperation

(2015) Julia R. Khusnutdinova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium Pincer-Catalyzed Dehydrogenation of Ethers Featuring Ethylene as the Hydrogen Acceptor

(2015) Thomas W. Lyons et al.   ORGANOMETALLICS

C–H Activation Reactions of a Nucleophilic Palladium Carbene

(2015) Cezar C. Comanescu et al.   ORGANOMETALLICS

Selective Catalytic Transfer Dehydrogenation of Alkanes and Heterocycles by an Iridium Pincer Complex

(2014) Wubing Yao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of Water, Ammonia, and Other Small Molecules by PCcarbeneP Nickel Pincer Complexes

(2013) Dmitry V. Gutsulyak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Heterolytic H2 Cleavage and Catalytic Hydrogenation by an Iron Metallaboratrane

(2013) Henry Fong et al.   ORGANOMETALLICS

Catalytic Arene H/D Exchange with Novel Rhodium and Iridium Complexes

(2012) Jennifer L. Rhinehart et al.   ORGANOMETALLICS

Dehydrogenation and Related Reactions Catalyzed by Iridium Pincer Complexes

(2011) Jongwook Choi et al.   CHEMICAL REVIEWS

A Dearomatized Anionic PNP Pincer Rhodium Complex: C–H and H–H Bond Activation by Metal–Ligand Cooperation and Inhibition by Dinitrogen

(2011) Leonid Schwartsburd et al.   ORGANOMETALLICS

H/D Exchange Processes Catalyzed by an Iridium-Pincer Complex

(2011) Vlad M. Iluc et al.   ORGANOMETALLICS

The development and use of novel iridium complexes as catalysts for ortho-directed hydrogen isotope exchange reactions

(2010) Göran N. Nilsson et al.   JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS

Ligand-Accelerated C−H Activation Reactions: Evidence for a Switch of Mechanism

(2010) Keary M. Engle et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Reactivity of an Iridium(I) Acetonyl PNP Complex. Experimental and Computational Study of Metal−Ligand Cooperation in H−H and C−H Bond Activation via Reversible Ligand Dearomatization

(2010) Leonid Schwartsburd et al.   ORGANOMETALLICS

Surprising isomer preference on IrIII, favoring facile H–C(sp3) bond cleavage

(2009) Nikolai P. Tsvetkov et al.   CHEMICAL COMMUNICATIONS

Imidazol-2-yl Complexes of Cp*Ir as Bifunctional Ambident Reactants

(2008) Valentín Miranda-Soto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY