Journal
CHEMSUSCHEM
Volume 14, Issue 15, Pages 3047-3053Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.202100813
Keywords
aromatics; biomass; Diels-Alder reaction; oxygen heterocycles; renewable
Funding
- Fundacao para a Ciencia e a Tecnologia [SFRH/BD/120829/2016, PTDC/QUI-QOR/32008/2017, UIDB/04138/2020, UIDP/04138/2020]
- COMPETE Program [SAICTPAC/0019/2015]
- European Union's Horizon 2020 research and innovation program [951996]
- Fundação para a Ciência e a Tecnologia [SFRH/BD/120829/2016, PTDC/QUI-QOR/32008/2017] Funding Source: FCT
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The bio-based furan DA strategy is a key method to transform renewable resources into high value-added chemicals, involving a series of aromatization reactions starting from furan platform chemicals. The focus of the research is on different utilization and activation strategies of furfurals, as well as direct Diels-Alder reactions of biomass-derived furans.
The preparation of high value-added chemicals from renewable resources is a crucial approach towards a sustainable economy. One prominent alternative to the production of petroleum-based chemicals from fossil resources is through the sequential Diels-Alder/aromatization reactions of biomass-derived furan platforms. This Concept is focused on the recent boom in bio-based furan DA strategies for aromatization of bio-based platform chemicals, particularly that of furfurals, ranging from indirect use and activation strategies to recent examples of direct DA reaction of these electron-withdrawing biomass-derived furans.
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