Bipyridinium and Phenanthrolinium Dications for Metal‐Free Hydrodefluorination: Distinctive Carbon‐Based Reactivity

Silylium‐Ion‐Promoted (5+1) Cycloaddition of Aryl‐Substituted Vinylcyclopropanes and Hydrosilanes Involving Aryl Migration

(2020) Tao He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Extensive Set of Accurate Fluoride Ion Affinities for p ‐Block Element Lewis Acids and Basic Design Principles for Strong Fluoride Ion Acceptors

(2020) Philipp Erdmann et al.   CHEMPHYSCHEM

Isolable Silicon‐Based Polycations with Lewis Superacidity

(2020) André Hermannsdorfer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Accessing Difluoromethylated and Trifluoromethylated cis -Cycloalkanes and Saturated Heterocycles: Preferential Hydrogen Addition to the Substitution Sites for Dearomatization

(2019) Xue Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition Metal-Mediated and -Catalyzed C-F Bond Activation via Fluorine Elimination

(2018) Takeshi Fujita et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Hydrodefluorination of C−F Bonds by an Air-Stable PIII Lewis Acid

(2018) Saurabh S. Chitnis et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hydrogenation of fluoroarenes: Direct access to all-cis-(multi)fluorinated cycloalkanes

(2017) Mario P. Wiesenfeldt et al.   SCIENCE

C−C Coupling of Benzyl Fluorides Catalyzed by an Electrophilic Phosphonium Cation

(2016) Jiangtao Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Single C−F Bond Cleavage of Trifluoromethylarenes with an ortho -Silyl Group

(2016) Suguru Yoshida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic activation of a single C–F bond in trifluoromethyl arenes

(2016) Hester Dang et al.   Chemical Science

The Carbocation: A Forgotten Lewis Acid Catalyst

(2015) Veluru Ramesh Naidu et al.   ChemCatChem

N-Methylacridinium Salts: Carbon Lewis Acids in Frustrated Lewis Pairs for σ-Bond Activation and Catalytic Reductions

(2014) Ewan R. Clark et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Hydrodefluorination of Fluoromethanes at Room Temperature by Silylium-ion-like Surface Species

(2013) Mike Ahrens et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Hydride-Ion Affinity of Borenium Cations and Their Propensity to Activate H2in Frustrated Lewis Pairs

(2013) Ewan R. Clark et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Ru−η6-Arene Complex as a C-Based Lewis Acid in the Activation of Hydrogen and Hydrogenation Catalysis

(2013) Michael P. Boone et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

[(acridine)BCl2]+: A Borenium Cation That Is a Strong Boron- and Carbon-Based Lewis Acid

(2013) Ewan R. Clark et al.   ORGANOMETALLICS

Lewis Acidity of Organofluorophosphonium Salts: Hydrodefluorination by a Saturated Acceptor

(2013) C. B. Caputo et al.   SCIENCE

Fullerenes as Neutral Carbon-Based Lewis Acids

(2012) Javier Iglesias-Sigüenza et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

“Tamed” Silylium Ions: Versatile in Catalysis

(2012) Axel Schulz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and reactivity of electron poor allenes: formation of completely organic frustrated Lewis pairs

(2012) David Palomas et al.   DALTON TRANSACTIONS

Decisive Steps of the Hydrodefluorination of Fluoroaromatics using [Ni(NHC)2]

(2012) Peter Fischer et al.   ORGANOMETALLICS

Fullerene–Carbene Lewis Acid–Base Adducts

(2011) Huaping Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Proton-Catalyzed, Silane-Fueled Friedel-Crafts Coupling of Fluoroarenes

(2011) O. Allemann et al.   SCIENCE

Ruthenium-catalyzed arylation of fluorinated aromatic ketones via ortho-selective carbon–fluorine bond cleavage

(2011) Keisuke Kawamoto et al.   TETRAHEDRON LETTERS

Heterolytic SS Bond Cleavage by a Purely Carbogenic Frustrated Lewis Pair

(2010) Blanca Inés et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Titanium-Catalyzed C-F Activation of Fluoroalkenes

(2010) Moritz F. Kühnel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CF Activation of Fluorobenzene by Silylium Carboranes: Evidence for Incipient Phenyl Cation Reactivity

(2010) Simon Duttwyler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Calculated Hydride and Fluoride Affinities of a Series of Carbenium and Silylium Cations in the Gas Phase and in C6H5Cl Solution

(2010) Dmitry G. Gusev et al.   CHEMISTRY-A EUROPEAN JOURNAL

Borohydrides from Organic Hydrides: Reactions of Hantzsch’s Esters with B(C6F5)3

(2010) Jonathan D. Webb et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hydrodefluorination and Other Hydrodehalogenation of Aliphatic Carbon−Halogen Bonds Using Silylium Catalysis

(2010) Christos Douvris et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic CF Activation and Hydrodefluorination of Fluoroalkyl Groups

(2009) Gregor Meier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis Acidities and Hydride, Fluoride, and X−Affinities of the BH3−nXnCompounds for (X = F, Cl, Br, I, NH2, OH, and SH) from Coupled Cluster Theory

(2009) Daniel J. Grant et al.   INORGANIC CHEMISTRY

Revisiting the IspH Catalytic System in the Deoxyxylulose Phosphate Pathway: Achieving High Activity

(2009) Youli Xiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Hydrodefluorination of Aromatic Fluorocarbons by Ruthenium N-Heterocyclic Carbene Complexes

(2009) Steven P. Reade et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrodefluorination of Perfluoroalkyl Groups Using Silylium-Carborane Catalysts

(2008) C. Douvris et al.   SCIENCE