Evolution of Earth‐Abundant 3 d‐Metallaelectro‐Catalyzed C−H Activation: From Chelation‐Assistance to C−H Functionalization without Directing Groups

Electrochemical Oxidation of Organic Molecules at Lower Overpotential: Accessing Broader Functional Group Compatibility with Electron−Proton Transfer Mediators

(2020) Fei Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Site-Selective C–H Functionalization via Synergistic Use of Electrochemistry and Transition Metal Catalysis

(2020) Ke-Jin Jiao et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalyzing Electrosynthesis: A Homogeneous Electrocatalytic Approach to Reaction Discovery

(2020) Juno C. Siu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Aza-Ruthena(II)-Bicyclo-[3.2.0]-Heptadiene: Key Intermediate for Ruthenaelectro(II/III/I)-Catalyzed Alkyne Annulations

(2020) Long Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bidentate Directing Groups: An Efficient Tool in C–H Bond Functionalization Chemistry for the Expedient Construction of C–C Bonds

(2020) Supriya Rej et al.   CHEMICAL REVIEWS

Cobalta‐Electrocatalyzed C−H Activation in Biomass‐Derived Glycerol: Powered by Renewable Wind and Solar Energy

(2020) Tjark H. Meyer et al.   ChemSusChem

Multiple Catalytic C-H Bond Functionalization for Natural Product Synthesis

(2020) Olivier Baudoin   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickelaelectro‐Catalyzed Mild C–H Alkylations at Room Temperature

(2020) Ramesh C. Samanta et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Insights into Cobalta(III/IV/II)‐Electrocatalysis: Oxidation‐Induced Reductive Elimination for Twofold C−H Activation

(2020) Tjark H. Meyer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Palladaelectro‐Catalyzed C–H Activations by Transient Directing Groups: Expedient Access to Helicenes

(2020) Uttam Dhawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Evolution of High‐Valent Nickelaelectro‐Catalyzed C–H Activation: From Cross(‐Electrophile)‐Couplings to Electrooxidative C–H Transformations

(2020) Shou-Kun Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cobalt-catalysed C–H methylation for late-stage drug diversification

(2020) Stig D. Friis et al.   Nature Chemistry

Cobalta-Electrocatalyzed C–H Allylation with Unactivated Alkenes

(2020) Uttam Dhawa et al.   ACS Catalysis

Manganese-Catalyzed Oxidative Azidation of C(sp3)–H Bonds under Electrophotocatalytic Conditions

(2020) Linbin Niu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Powering the Future: How Can Electrochemistry Make a Difference in Organic Synthesis?

(2020) Tjark H. Meyer et al.   Chem

Ruthenaelectro‐Catalyzed Domino Three‐Component Alkyne Annulation Expedient Isoquinoline Assembly

(2020) Xuefeng Tan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobaltaelectro‐Catalyzed C–H Acyloxylation

(2019) Cong Tian et al.   CHINESE JOURNAL OF CHEMISTRY

Cobaltaelectro‐Catalyzed C–H Activation with Carbon Monoxide or Isocyanides

(2019) Samaresh Chandra Sau et al.   ChemSusChem

Nickel-Catalyzed Thiolation of Aryl Halides and Heteroaryl Halides through Electrochemistry

(2019) Dong Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodaelectrocatalysis for Annulative C-H Activation: Polycyclic Aromatic Hydrocarbons by Versatile Double Electrocatalysis

(2019) Wei-Jun Kong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light for Ruthenium-Catalyzed meta-C-H Alkylation at Room Temperature

(2019) Parthasarathy Gandeepan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective C-H Activation with Earth-Abundant 3d Transition Metals

(2019) Joachim Loup et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electrons and Holes as Catalysts in Organic Electrosynthesis

(2019) Robert Francke et al.   ChemElectroChem

Cobaltaelectro-Catalyzed Oxidative C–H/N–H Activation with 1,3-Diynes by Electro-Removable Hydrazides

(2019) Ruhuai Mei et al.   ORGANIC LETTERS

Cupraelectro-Catalyzed Alkyne Annulation: Evidence for Distinct C–H Alkynylation and Decarboxylative C–H/C–C Manifolds

(2019) Cong Tian et al.   ACS Catalysis

Flow Rhodaelectro-Catalyzed Alkyne Annulations by Versatile C−H Activation: Mechanistic Support for Rhodium(III/IV)

(2019) Wei-Jun Kong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electroorganic Synthesis under Flow Conditions

(2019) Mohamed Elsherbini et al.   ACCOUNTS OF CHEMICAL RESEARCH

Chemistry with Electrochemically Generated N-Centered Radicals

(2019) Peng Xiong et al.   ACCOUNTS OF CHEMICAL RESEARCH

Scalable Rhodium(III)-Catalyzed Aryl C−H Phosphorylation Enabled by Anodic Oxidation Induced Reductive Elimination

(2019) Zheng-Jian Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electro-Catalyzed Hypervalent Iodine Orchestrated for Ruthenaelectro-Catalyzed C-H Oxygenation­­

(2019) Leonardo Massignan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickellaelectro-Catalyzed C-H Alkoxylation with Secondary Alcohols: Oxidation-Induced Reductive Elimination at Nickel(III)

(2019) Shou-Kun Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Breadth and Depth of C–H Functionalization

(2019) Jonathan A. Ellman et al.   JOURNAL OF ORGANIC CHEMISTRY

Electrochemistry-Enabled Ir-Catalyzed Vinylic C–H Functionalization

(2019) Qi-Liang Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metalla-electrocatalyzed C–H Activation by Earth-Abundant 3d Metals and Beyond

(2019) Lutz Ackermann   ACCOUNTS OF CHEMICAL RESEARCH

A Survival Guide for the “Electro-curious”

(2019) Cian Kingston et al.   ACCOUNTS OF CHEMICAL RESEARCH

Electrochemical Access to Aza-Polycyclic Aromatic Hydrocarbons: Rhoda-Electrocatalyzed Domino Alkyne Annulations

(2019) Wei-Jun Kong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron‐Electrocatalyzed C−H Arylations: Mechanistic Insights into Oxidation‐Induced Reductive Elimination for Ferraelectrocatalysis

(2019) Cuiju Zhu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Electrochemically Enabled Double C–H Activation of Amides: Chemoselective Synthesis of Polycyclic Isoquinolinones

(2019) Zi-Qiang Wang et al.   ORGANIC LETTERS

Increasing Catalyst Efficiency in C−H Activation Catalysis

(2018) Tobias Gensch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electrochemical C−H/N−H Activation by Water-Tolerant Cobalt Catalysis at Room Temperature

(2018) Cong Tian et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light Photocatalysis: Does It Make a Difference in Organic Synthesis?

(2018) Leyre Marzo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Late-Stage Peptide Diversification by Position-Selective C-H Activation

(2018) Wei Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electrooxidative Rhodium-Catalyzed C−H/C−H Activation: Electricity as Oxidant for Cross-Dehydrogenative Alkenylation

(2018) Youai Qiu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electrooxidative Ruthenium-Catalyzed C−H/O−H Annulation by Weak O -Coordination

(2018) Youai Qiu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electrochemical C−H Amination by Cobalt Catalysis in a Renewable Solvent

(2018) Nicolas Sauermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electrifying Organic Synthesis

(2018) Anton Wiebe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tetramethylpiperidine N-Oxyl (TEMPO), Phthalimide N-Oxyl (PINO), and Related N-Oxyl Species: Electrochemical Properties and Their Use in Electrocatalytic Reactions

(2018) Jordan E. Nutting et al.   CHEMICAL REVIEWS

Using Physical Organic Chemistry To Shape the Course of Electrochemical Reactions

(2018) Kevin D. Moeller   CHEMICAL REVIEWS

Electrochemical strategies for C–H functionalization and C–N bond formation

(2018) Markus D. Kärkäs   CHEMICAL SOCIETY REVIEWS

Electrochemical Cobalt-Catalyzed C-H Activation

(2018) Nicolas Sauermann et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cobalt(II)-Catalyzed Electrooxidative C–H Amination of Arenes with Alkylamines

(2018) Xinlong Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electroremovable Traceless Hydrazides for Cobalt-Catalyzed Electro-Oxidative C–H/N–H Activation with Internal Alkynes

(2018) Ruhuai Mei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

sp3 C–H activation via exo-type directing groups

(2018) Yan Xu et al.   Chemical Science

Cobalt-catalyzed electrooxidative C-H/N-H [4+2] annulation with ethylene or ethyne

(2018) Shan Tang et al.   Nature Communications

Ruthenium-Catalyzed Electrochemical Dehydrogenative Alkyne Annulation

(2018) Fan Xu et al.   ACS Catalysis

An Electrocatalytic Approach to the Radical Difunctionalization of Alkenes

(2018) Gregory S. Sauer et al.   ACS Catalysis

Cobalt-Catalyzed Electrochemical Oxidative C–H/N–H Carbonylation with Hydrogen Evolution

(2018) Li Zeng et al.   ACS Catalysis

Recent Advances in C–H Functionalization Using Electrochemical Transition Metal Catalysis

(2018) Cong Ma et al.   ACS Catalysis

Transient Directing Groups for Transformative C–H Activation by Synergistic Metal Catalysis

(2018) Parthasarathy Gandeepan et al.   Chem

Iridium-Catalyzed Electrooxidative C-H Activation by Chemo-Selective Redox-Catalyst Cooperation

(2018) Youai Qiu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

(2018) Carlo Sambiagio et al.   CHEMICAL SOCIETY REVIEWS

Copper-Catalyzed Electrochemical C–H Amination of Arenes with Secondary Amines

(2018) Qi-Liang Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrooxidative Allene Annulations by Mild Cobalt-Catalyzed C–H Activation

(2018) Tjark H. Meyer et al.   ACS Catalysis

3d Transition Metals for C–H Activation

(2018) Parthasarathy Gandeepan et al.   CHEMICAL REVIEWS

Nickel-Catalyzed Electrooxidative C−H Amination: Support for Nickel(IV)

(2018) Shou-Kun Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Electrochemical Cobalt-Catalyzed C–H Oxygenation at Room Temperature

(2017) Nicolas Sauermann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed C(sp3)—H Oxygenation via Electrochemical Oxidation

(2017) Qi-Liang Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium catalyzed CH functionalization with electrochemical oxidation

(2017) Ke-Jin Jiao et al.   TETRAHEDRON LETTERS

Recent Advances in Catalytic C(sp2)–H Allylation Reactions

(2017) Neeraj Kumar Mishra et al.   ACS Catalysis

Collective Approach to Advancing C–H Functionalization

(2017) Huw M. L. Davies et al.   ACS Central Science

The merger of transition metal and photocatalysis

(2017) Jack Twilton et al.   Nature Reviews Chemistry

Merging Visible Light Photoredox Catalysis with Metal Catalyzed C–H Activations: On the Role of Oxygen and Superoxide Ions as Oxidants

(2016) David C. Fabry et al.   ACCOUNTS OF CHEMICAL RESEARCH

Direct (Hetero)arylation Polymerization: Simplicity for Conjugated Polymer Synthesis

(2016) Jean-Rémi Pouliot et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Transformations of Alkyl C–H Bonds

(2016) Jian He et al.   CHEMICAL REVIEWS

Transition-Metal-Catalyzed C–H Bond Addition to Carbonyls, Imines, and Related Polarized π Bonds

(2016) Joshua R. Hummel et al.   CHEMICAL REVIEWS

Mild metal-catalyzed C–H activation: examples and concepts

(2016) T. Gensch et al.   CHEMICAL SOCIETY REVIEWS

Ag-catalyzed C–H/C–C bond functionalization

(2016) Qing-Zhong Zheng et al.   CHEMICAL SOCIETY REVIEWS

Manganese-Catalyzed C–H Activation

(2016) Weiping Liu et al.   ACS Catalysis

Synthetic Organic Electrochemistry: An Enabling and Innately Sustainable Method

(2016) Evan J. Horn et al.   ACS Central Science

Bidentate, Monoanionic Auxiliary-Directed Functionalization of Carbon–Hydrogen Bonds

(2015) Olafs Daugulis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Chiral Cyclopentadienyls: Enabling Ligands for Asymmetric Rh(III)-Catalyzed C–H Functionalizations

(2015) Baihua Ye et al.   ACCOUNTS OF CHEMICAL RESEARCH

Ruthenium(II)-Catalyzed CH Activation/Alkyne Annulation by Weak Coordination with O2as the Sole Oxidant

(2015) Svenja Warratz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel Catalysts/N,N′-Bidentate Directing Groups: An Excellent Partnership in Directed C–H Activation Reactions

(2015) Luis C. Misal Castro et al.   CHEMISTRY LETTERS

Dual catalysis at the flick of a switch

(2015) James J. Devery et al.   NATURE

Robust Ruthenium(II)-Catalyzed C–H Arylations: Carboxylate Assistance for the Efficient Synthesis of Angiotensin-II-Receptor Blockers

(2015) Lutz Ackermann   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Synthesis of Extended π-Systems through C-H Activation

(2014) Yasutomo Segawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–H Functionalization in the Synthesis of Amino Acids and Peptides

(2014) Anaïs F. M. Noisier et al.   CHEMICAL REVIEWS

Redox catalysis in organic electrosynthesis: basic principles and recent developments

(2014) Robert Francke et al.   CHEMICAL SOCIETY REVIEWS

Experimental Limiting Oxygen Concentrations for Nine Organic Solvents at Temperatures and Pressures Relevant to Aerobic Oxidations in the Pharmaceutical Industry

(2014) Paul M. Osterberg et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Carboxylate-Assisted Ruthenium-Catalyzed Alkyne Annulations by C–H/Het–H Bond Functionalizations

(2013) Lutz Ackermann   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-Catalyzed Cross-Coupling: A Historical Contextual Perspective to the 2010 Nobel Prize

(2012) Carin C. C. Johansson Seechurn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

(2011) Charles S. Yeung et al.   CHEMICAL REVIEWS

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Transition metal-catalyzed arylation of unactivated C(sp3)–H bonds

(2011) Olivier Baudoin   CHEMICAL SOCIETY REVIEWS

Direct Arylation as a Synthetic Tool for the Synthesis of Thiophene-Based Organic Electronic Materials

(2011) Derek J. Schipper et al.   CHEMISTRY OF MATERIALS

Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage

(2009) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Green Chemistry: Principles and Practice

(2009) Paul Anastas et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Aromatic C−H Halogenation with Hydrogen Halides by Means of Electrochemical Oxidation

(2009) Fumitoshi Kakiuchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Oxidation of Organic Substrates by Molecular Oxygen and Hydrogen Peroxide by Multistep Electron Transfer—A Biomimetic Approach

(2008) Julio Piera et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Contribution of Electrochemistry to Organometallic Catalysis

(2008) Anny Jutand   CHEMICAL REVIEWS