Electrifying Organic Synthesis

Electrocatalytic C–H/N–H Coupling of 2′-Aminoacetophenones for the Synthesis of Isatins

(2017) Peng Qian et al.   JOURNAL OF ORGANIC CHEMISTRY

Metal- and Reagent-Free Intramolecular Oxidative Amination of Tri- and Tetrasubstituted Alkenes

(2017) Peng Xiong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Insights into the Mechanism of Anodic N–N Bond Formation by Dehydrogenative Coupling

(2017) Tile Gieshoff et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Scalable, Electrochemical Oxidation of Unactivated C–H Bonds

(2017) Yu Kawamata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cathodic Aromatic C,C Cross-Coupling Reaction via Single Electron Transfer Pathway

(2017) Yang Qu et al.   MOLECULES

Electrochemical amination. Selective introduction of two amino groups into an aromatic ring

(2017) Yu. A. Lisitsyn et al.   RUSSIAN JOURNAL OF GENERAL CHEMISTRY

Metal-catalyzed electrochemical diazidation of alkenes

(2017) Niankai Fu et al.   SCIENCE

Combining theory and experiment in electrocatalysis: Insights into materials design

(2017) Zhi Wei Seh et al.   SCIENCE

TEMPO-Catalyzed Electrochemical C–H Thiolation: Synthesis of Benzothiazoles and Thiazolopyridines from Thioamides

(2017) Xiang-Yang Qian et al.   ACS Catalysis

Twofold Electrochemical Amination of Naphthalene and Related Arenes

(2017) Sabine Möhle et al.   ChemElectroChem

Unexpected high robustness of electrochemical cross-coupling for a broad range of current density

(2017) Anton Wiebe et al.   Science Advances

Hexafluoroisopropanol as a highly versatile solvent

(2017) Ignacio Colomer et al.   Nature Reviews Chemistry

Electrochemical Allylic Oxidation of Olefins: Sustainable and Safe

(2016) Siegfried R. Waldvogel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electrochemical C−H/N−H Functionalization for the Synthesis of Highly Functionalized (Aza)indoles

(2016) Zhong-Wei Hou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electrocatalytic Generation of Amidyl Radicals for Olefin Hydroamidation: Use of Solvent Effects to Enable Anilide Oxidation

(2016) Lin Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of meta -Terphenyl-2,2′′-diols by Anodic C−C Cross-Coupling Reactions

(2016) Sebastian Lips et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Synthesis of Partially Protected Nonsymmetric Biphenols by Reagent- and Metal-Free Anodic Cross-Coupling Reaction

(2016) Anton Wiebe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Access to Pyrazolidin-3,5-diones through Anodic N-N Bond Formation

(2016) Tile Gieshoff et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Amidinyl Radical Formation through Anodic N−H Bond Cleavage and Its Application in Aromatic C−H Bond Functionalization

(2016) Huai-Bo Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild metal-catalyzed C–H activation: examples and concepts

(2016) T. Gensch et al.   CHEMICAL SOCIETY REVIEWS

Electrochemical Synthesis of Benzazoles from Alcohols and o -Substituted Anilines with a Catalytic Amount of CoII Salt

(2016) Yin-Long Lai et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metal-Free Benzylic C−H Amination via Electrochemically Generated Benzylaminosulfonium Ions

(2016) Ryutaro Hayashi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Beneficial Effects of Electrochemistry in Cross-Coupling Reactions: Electroreductive Synthesis of 4-Aryl- or 4-Heteroaryl-6-pyrrolylpyrimidines

(2016) Stéphane Sengmany et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Electrochemical Amination of Less-Activated Alkylated Arenes Using Boron-Doped Diamond Anodes

(2016) Sebastian Herold et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Electrochemical synthesis of benzoxazoles mediated by 2,3-dichloro-5,6-dicyano- p -hydroquinone (DDH) as a redox catalyst

(2016) Li-Shuo Kang et al.   JOURNAL OF ELECTROANALYTICAL CHEMISTRY

Paired Electrolysis in the Simultaneous Production of Synthetic Intermediates and Substrates

(2016) Mark J. Llorente et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Stabilized Cation Pool Method: Metal- and Oxidant-Free Benzylic C–H/Aromatic C–H Cross-Coupling

(2016) Ryutaro Hayashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Scalable and sustainable electrochemical allylic C–H oxidation

(2016) Evan J. Horn et al.   NATURE

Electro-organic Synthesis as a Sustainable Alternative for Dehydrogenative Cross-Coupling of Phenols and Naphthols

(2016) Siegfried Waldvogel et al.   SYNTHESIS-STUTTGART

Synthetic Organic Electrochemistry: An Enabling and Innately Sustainable Method

(2016) Evan J. Horn et al.   ACS Central Science

Electrolytic Macrocyclizations: Scalable Synthesis of a Diazonamide-Based Drug Development Candidate

(2015) Hui Ding et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Practical Electrochemical Anodic Oxidation of Polycyclic Lactams for Late Stage Functionalization

(2015) Kevin J. Frankowski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Over-Oxidation as the Key Step in the Mechanism of the MoCl5 -Mediated Dehydrogenative Coupling of Arenes

(2015) Moritz Schubert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Versatile Electrochemical CH Amination via Zincke Intermediates

(2015) Siegfried R. Waldvogel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly selective generation of vanillin by anodic degradation of lignin: a combined approach of electrochemistry and product isolation by adsorption

(2015) Dominik Schmitt et al.   Beilstein Journal of Organic Chemistry

Reaction Integration Using Electrogenerated Cationic Intermediates

(2015) Jun-ichi Yoshida et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

An anodic aromatic C,C cross-coupling reaction using parallel laminar flow mode in a flow microreactor

(2015) Toshihiro Arai et al.   CHEMICAL COMMUNICATIONS

Electrochemical Intramolecular CH Amination: Synthesis of Benzoxazoles and Benzothiazoles

(2015) Tatsuya Morofuji et al.   CHEMISTRY-A EUROPEAN JOURNAL

Source of Selectivity in Oxidative Cross-Coupling of Aryls by Solvent Effect of 1,1,1,3,3,3-Hexafluoropropan-2-ol

(2015) Bernd Elsler et al.   CHEMISTRY-A EUROPEAN JOURNAL

Electrochemistry for Biofuel Generation: Transformation of Fatty Acids and Triglycerides to Diesel-Like Olefin/Ether Mixtures and Olefins

(2015) Tatiane R. dos Santos et al.   ChemSusChem

The Dilemma of Supporting Electrolytes for Electroorganic Synthesis: A Case Study on Kolbe Electrolysis

(2015) Carolin Stang et al.   ChemSusChem

Heterocyclization Approach for Electrooxidative Coupling of Functional Primary Alkylamines with Aromatics

(2015) Tatsuya Morofuji et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrochemical Oxidative Decarboxylation of Malonic Acid Derivatives: A Method for the Synthesis of Ketals and Ketones

(2015) Xiaofeng Ma et al.   ORGANIC LETTERS

Electrochemical Screening for Electroorganic Synthesis

(2015) Christoph Gütz et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Selective synthesis of benzene-1,3-diamines by amination of anilines containing ortho/para-orienting substituents in the para position

(2015) Yu. A. Lisitsyn et al.   RUSSIAN JOURNAL OF ORGANIC CHEMISTRY

Recent advances in the electrochemical construction of heterocycles

(2015) Robert Francke   Beilstein Journal of Organic Chemistry

Electrochemical Intramolecular Aminooxygenation of Unactivated Alkenes

(2014) Fan Xu et al.   CHEMISTRY-A EUROPEAN JOURNAL

The mechanism of mediated oxidation of carboxylates with ferrocene as redox catalyst in absence of grafting effects. An experimental and theoretical approach

(2014) Lindsay S. Hernández-Muñoz et al.   ELECTROCHIMICA ACTA

Electrochemically Initiated Oxidative Amination of Benzoxazoles Using Tetraalkylammonium Halides As Redox Catalysts

(2014) Wei-Jing Gao et al.   JOURNAL OF ORGANIC CHEMISTRY

Total Synthesis of Dixiamycin B by Electrochemical Oxidation

(2014) Brandon R. Rosen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct C–N Coupling of Imidazoles with Aromatic and Benzylic Compounds via Electrooxidative C–H Functionalization

(2014) Tatsuya Morofuji et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Regioselective Homocoupling of Arenes Using Anodic Oxidation: Formal Electrolysis of Aromatic Carbon–Hydrogen Bonds

(2014) Fumito Saito et al.   ORGANOMETALLICS

A palladium-catalyzed facile and general method for the stereoselective synthesis of (E)-3-arylidene-3,4-dihydro-2H-1,4-benzoxazines and their naphthoxazine analogues

(2014) Kaushik Brahma et al.   TETRAHEDRON

Efficient Indirect Electrochemical Synthesis of 2-Substituted Benzoxazoles using Sodium Iodide as Mediator

(2013) Wei-Cui Li et al.   ADVANCED SYNTHESIS & CATALYSIS

Synthesis of Vicinal Aminoalcohols by Stereoselective Aza-Wacker Cyclizations: Access to (−)-Acosamine by Redox Relay

(2013) Adam B. Weinstein et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidative Cyclization Reactions: Controlling the Course of a Radical Cation-Derived Reaction with the Use of a Second Nucleophile

(2013) Alison Redden et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Polyurethanes: Versatile Materials and Sustainable Problem Solvers for Today’s Challenges

(2013) Hans-Wilhelm Engels et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electro-reductive Homo-Coupling Reaction of Aryl Bromides in PdCl2(PPh3)2/Pyridinium Salt Double Mediatory Systems

(2013) Hideo TANAKA et al.   ELECTROCHEMISTRY

Cyclization Reactions of Anode-Generated Amidyl Radicals

(2013) Hai-Chao Xu et al.   JOURNAL OF ORGANIC CHEMISTRY

Electrochemical C–H Amination: Synthesis of Aromatic Primary Amines via N-Arylpyridinium Ions

(2013) Tatsuya Morofuji et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H Arylation Reaction: Atom Efficient and Greener Syntheses of π-Conjugated Small Molecules and Macromolecules for Organic Electronic Materials

(2013) Ken Okamoto et al.   MACROMOLECULES

Electrochemical amination of anisole in 4–6 M solutions of H2SO4 and acetonitrile

(2013) Yu. A. Lisitsyn et al.   RUSSIAN JOURNAL OF ELECTROCHEMISTRY

Selectivity of electrochemical amination of anisole in water solutions of H2SO4

(2013) Yu. A. Lisitsyn et al.   RUSSIAN JOURNAL OF GENERAL CHEMISTRY

Viologen as catalytic organic reductant: electro-reductive dimerization of aryl bromides in a Pd/viologen double mediatory system

(2013) Manabu Kuroboshi et al.   TETRAHEDRON LETTERS

Anodic Oxidation on a Boron-Doped Diamond Electrode Mediated by Methoxy Radicals

(2012) Takenori Sumi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electrochemical Fluorination Using Alkali-Metal Fluorides

(2012) Takahiro Sawamura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal- and Chemical-Oxidant-Free CH/CH Cross-Coupling of Aromatic Compounds: The Use of Radical-Cation Pools

(2012) Tatsuya Morofuji et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient electroorganic synthesis of 2,3,6,7,10,11-hexahydroxytriphenylene derivatives

(2012) Carolin Regenbrecht et al.   Beilstein Journal of Organic Chemistry

Applied Hydroformylation

(2012) Robert Franke et al.   CHEMICAL REVIEWS

Electrochemical Synthesis of Adiponitrile from the Renewable Raw Material Glutamic Acid

(2012) Jian-Jun Dai et al.   ChemSusChem

The effect of substituents on the anodic oxidation of aliphatic carboxylates and the passage towards a pseudo-Kolbe reaction

(2012) Mónica Galicia et al.   JOURNAL OF ELECTROANALYTICAL CHEMISTRY

An Electrochemical Nickel-Catalyzed Arylation of 3-Amino-6-Chloropyridazines

(2012) Stéphane Sengmany et al.   JOURNAL OF ORGANIC CHEMISTRY

Investigating the Reactivity of Radical Cations: Experimental and Computational Insights into the Reactions of Radical Cations with Alcohol and p-Toluene Sulfonamide Nucleophiles

(2012) John M. Campbell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Anodic and Direct Phenol-Arene C,C Cross-Coupling: The Benign Role of Water or Methanol

(2012) Axel Kirste et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Opportunities and challenges for a sustainable energy future

(2012) Steven Chu et al.   NATURE

Electrocatalyst approaches and challenges for automotive fuel cells

(2012) Mark K. Debe   NATURE

Efficient and Stereodivergent Electrochemical Synthesis of Optically Pure Menthylamines

(2011) Jörn Kulisch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective electrochemical fluorination of organic molecules and macromolecules in ionic liquids

(2011) Toshio Fuchigami et al.   CHEMICAL COMMUNICATIONS

Contributions of organic electrosynthesis to green chemistry

(2011) Hans J. Schäfer   COMPTES RENDUS CHIMIE

Bubble dynamics during Kolbe electrolysis of trifluoroacetic acid at Pt electrodes

(2011) D. Koutsaftis et al.   ELECTROCHIMICA ACTA

Electrochemical conversion of fatty acids

(2011) Hans J. Schäfer   EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY

Electrochemical Synthesis of 1,2-Disilylethanes from α-Silylacetic Acids

(2011) Alex V. Shtelman et al.   JOURNAL OF ORGANIC CHEMISTRY

An Electrochemical Synthesis of Functionalized Arylpyrimidines from 4-Amino-6-Chloropyrimidines and Aryl Halides

(2011) Stéphane Sengmany et al.   MOLECULES

Electrochemical amination. Functionalization of anisole in solutions of 4.0–6.0 M H2SO4 and acetic acid

(2011) Yu. A. Lisitsyn et al.   RUSSIAN JOURNAL OF ELECTROCHEMISTRY

Porphyrin-Sensitized Solar Cells with Cobalt (II/III)-Based Redox Electrolyte Exceed 12 Percent Efficiency

(2011) A. Yella et al.   SCIENCE

Recyclable Polymer-Supported Iodobenzene-Mediated Electrocatalytic Fluorination in Ionic Liquid

(2010) Takahiro Sawamura et al.   ADVANCED SYNTHESIS & CATALYSIS

Intramolecular Anodic Olefin Coupling Reactions: Use of the Reaction Rate To Control Substrate/Product Selectivity

(2010) Hai-Chao Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organic electrosynthesis: a promising green methodology in organic chemistry

(2010) Bernardo A. Frontana-Uribe et al.   GREEN CHEMISTRY

Anodic Coupling Reactions and the Synthesis of C-Glycosides

(2010) Guoxi Xu et al.   ORGANIC LETTERS

Use of Task-Specific Ionic Liquid for Selective Electrocatalytic Fluorination

(2010) Takahiro Sawamura et al.   ORGANIC LETTERS

Electrochemical amination. Ti(IV)/Ti(III) mediator system in aqueous solutions of sulfuric acid

(2010) Yu. A. Lisitsyn et al.   RUSSIAN JOURNAL OF ELECTROCHEMISTRY

Electrosynthesis of anisidines in aqueous sulfuric and acetic acids

(2010) Yu. A. Lisitsyn et al.   Russian Journal of Physical Chemistry A

Electrochemical construction of the diaryl ethers: a synthetic approach to o-methylthalibrine

(2010) Yu Naito et al.   TETRAHEDRON LETTERS

Anodic Phenol-Arene Cross-Coupling Reaction on Boron-Doped Diamond Electrodes

(2009) Axel Kirste et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly efficient and selective electrochemical fluorination of organosulfur compounds in Et3N·3HF ionic liquid under ultrasonication

(2009) Takeshi Sunaga et al.   CHEMICAL COMMUNICATIONS

Kinase Domain Mutations in Cancer: Implications for Small Molecule Drug Design Strategies

(2009) Jack A. Bikker et al.   JOURNAL OF MEDICINAL CHEMISTRY

Electrochemical amination. Dilute aqueous organic solutions of sulfuric acid

(2009) Yu. A. Lisitsyn et al.   RUSSIAN JOURNAL OF ELECTROCHEMISTRY

Pd/TEMPO-catalyzed electrooxidative synthesis of biaryls from arylboronic acids or arylboronic esters

(2009) Koichi Mitsudo et al.   TETRAHEDRON

Enantioselective Organocatalytic Epoxidation Driven by Electrochemically Generated Percarbonate and Persulfate

(2008) Philip C. Bulman Page et al.   ADVANCED SYNTHESIS & CATALYSIS

A Study in Mauve: Unveiling Perkin's Dye in Historic Samples

(2008) Micaela M. Sousa et al.   CHEMISTRY-A EUROPEAN JOURNAL

Effects of additives on anodic fluorination in ionic liquid hydrogen fluoride salts

(2008) Shinsuke Inagi et al.   ELECTROCHEMISTRY COMMUNICATIONS

Pd(OAc)2/p-Benzoquinone-Catalyzed Anaerobic Electrooxidative Homocoupling of Arylboronic Acids, Arylboronates and Aryltrifluoroborates in DMF and/or Water

(2008) Christian Amatore et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Kolbe Carbon−Carbon Coupling Electrosynthesis Using Solid-Supported Bases

(2008) Hitoshi Kurihara et al.   JOURNAL OF ORGANIC CHEMISTRY

Anodic Fluorination and Fluorodesulfurization in Ionic Liquid Hydrogen Fluoride Salts with Polyether Additives

(2008) Takahiro Sawamura et al.   JOURNAL OF THE ELECTROCHEMICAL SOCIETY

Synthesis of a spiroacetal moiety of antitumor antibiotic ossamycin by anodic oxidation

(2008) Eriko Honjo et al.   TETRAHEDRON

Anodic cyclization reactions and the synthesis of (−)-crobarbatic acid

(2008) Hai-Chao Xu et al.   TETRAHEDRON LETTERS

Electrooxidative homo-coupling of arylboronic acids catalyzed by electrogenerated cationic palladium catalysts

(2008) Koichi Mitsudo et al.   TETRAHEDRON LETTERS

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS