Review
Public, Environmental & Occupational Health
Kym Roberts, Ogilvie Thom, Susan Devine, Peter A. Leggat, Amy E. Peden, Richard C. Franklin
Summary: This scoping review focused on exploring adult female unintentional drowning in high-income countries, revealing differences in risk factors for female drowning and a lack of research on clinical treatment and outcomes specifically for females.
Article
Chemistry, Medicinal
Tony Ge, Jean-Christophe Cintrat
Summary: Heterocyclic amino derivatives have proven to be potent bioactive compounds, with novel heterocycles showing promise as building blocks in drug discovery. Pyrrolotriazinones, in particular, have attracted attention for their potential biological activities.
Review
Plant Sciences
Martijn van Zanten, Haiyue Ai, Marcel Quint
Summary: Plants have evolved various strategies to adjust organ positions in response to temperature, with thermotropism and thermonastic movements being classic concepts in botany. While thermonastic movements are relatively well-studied, the ecological function and mechanisms underlying thermotropism remain poorly understood.
JOURNAL OF EXPERIMENTAL BOTANY
(2021)
Review
Food Science & Technology
Marlene Machado, Helena Ferreira, M. Beatriz P. P. Oliveira, Rita C. Alves
Summary: Consumers' demand for nutritious and healthy foods has driven the development of prebiotic foods. In the coffee industry, the waste/by-products generated from the transformation of cherries into roasted beans can be used as sources of prebiotic ingredients. Coffee by-products contain dietary fiber and other components that can improve gut health and stimulate beneficial bacteria, making them potential prebiotic ingredients. However, further in vivo studies are needed to validate these findings obtained in vitro. This review highlights the potential of coffee by-products in the development of functional foods, contributing to sustainability, circular economy, food security, and health.
CRITICAL REVIEWS IN FOOD SCIENCE AND NUTRITION
(2023)
Article
Plant Sciences
Mitja M. Zdouc, Marianna Iorio, Sonia Maffioli, Max Cruesemann, Stefano Donadio, Margherita Sosio
Summary: Despite a strong track record, microbial drug discovery faces challenges with high rates of rediscovery and the lack of systematic characterization of less explored strains. A metabolomic study of Planomonospora isolates revealed a correlation between chemical diversity and strain phylogeny, identifying previously reported metabolites and gene clusters connected to biosynthetic capabilities. This study highlights the value of metabolomic studies in exploring poorly understood taxa and provides insights into the biosynthetic potential of the genus Planomonospora.
JOURNAL OF NATURAL PRODUCTS
(2021)
Article
Engineering, Environmental
Noah Linder, Matteo Giusti, Karl Samuelsson, Stephan Barthel
Summary: This article argues for the importance of pro-environmental habits in sustainability research and highlights the potential of habit theory in driving pro-environmental behaviors. It emphasizes the impact of habits on automatic processes of behavior, how the environmental context shapes habits, and how habits influence our values and self-identity. Studying sustainable behaviors through a habit lens can lead to a more comprehensive understanding and complement current approaches that focus on reasoned decisions and intrinsic motivations.
Review
Oncology
Yaiza Senent, Daniel Ajona, Antonio Gonzalez-Martin, Ruben Pio, Beatriz Tavira
Summary: Ovarian cancer is a deadly gynecological cancer where the immune system, particularly the complement system, plays a crucial role. Current therapeutic strategies can only temporarily control the disease, with many patients developing resistance to treatment. Immunotherapy has shown limited success in ovarian cancer, highlighting the need for further research into immune components for more effective treatment options.
Review
Immunology
Lucinda Baatjies, Andre G. Loxton, Monique J. Williams
Summary: Mycobacterium tuberculosis manipulates the host immune response and expresses specific genes during infection. Current immunodiagnostics lack the ability to detect progression from latent infection to active disease, highlighting the need for new tuberculosis biomarkers that can accurately diagnose TB infection and monitor treatment efficacy. Iron regulation by the host plays a crucial role in the susceptibility and outcome of Mtb infection, with certain genes being induced during iron limitation and intracellular growth of Mtb.
FRONTIERS IN IMMUNOLOGY
(2021)
Article
Environmental Sciences
Bradley A. Weymer, Mark E. Everett, Amir Haroon, Marion Jegen-Kulcsar, Aaron Micallef, Christian Berndt, Holly A. Michael, Rob L. Evans, Vincent Post
Summary: This article highlights the lack of research on marine geological structures, especially regarding the topography and geology below the coastline. Studying this area is significant for understanding geological processes, hazards, and coastal aquifers.
COMMUNICATIONS EARTH & ENVIRONMENT
(2022)
Review
Biochemistry & Molecular Biology
Jared T. Seale, Owen M. McDougal
Summary: This review consolidates the botanical and phytochemical information regarding V. parviflorum, exploring its potential medicinal value, particularly as potential Hh pathway inhibitors using its extract's steroidal alkaloids.
Article
Oncology
Luigi Grassi, Martino Belvederi Murri, Michelle Riba, Silvia de Padova, Tatiana Bertelli, Silvana Sabato, Maria Giulia Nanni, Rosangela Caruso, Heifa Ounalli, Luigi Zerbinati
Summary: The study found that approximately 25% of patients had moderate hostility and 11% had high levels of hostility, with about 20% being BSI-HOS cases. Hostility was higher in patients with a formal ICD-10 psychiatric diagnosis (mainly major depression, other depressive disorders, anxiety disorders). Hostility was associated with hopelessness, anxious preoccupation, poorer quality of life, worries (mainly interpersonal relationship problems), and inability to openly discuss these problems within the family.
Review
Chemistry, Medicinal
Rocio Diaz-Puertas, Mikolaj Adamek, Ricardo Mallavia, Alberto Falco
Summary: The antimicrobial molecules found in fish skin mucus, including peptides, proteins, and other metabolites, have been shown to have antimicrobial capacity against bacteria, fungi, and viruses. This review highlights the different methods of mucus extraction and emphasizes the importance of omic techniques in identifying and isolating new antimicrobial compounds. Overall, fish skin mucus is a promising source for the discovery of new antimicrobial agents.
Article
Immunology
McKinlee M. Salazar, Monica T. Pupo, Amanda M. V. Brown
Summary: The interactions between insect symbionts and plant pathogens are complex and dynamic, involving various species and organisms. Through shotgun metagenomic sequencing, this study identified a diverse range of potential plant pathogens and insect symbionts in treehoppers, suggesting that treehoppers offer a rich palette for future research on symbiont-plant pathogen interactions.
FRONTIERS IN CELLULAR AND INFECTION MICROBIOLOGY
(2021)
Article
Microbiology
Fabian Abiusi, Egbert Trompetter, Antonino Pollio, Rene H. Wijffels, Marcel Janssen
Summary: This study investigated six microalgal strains capable of growing at low pH conditions and compared their biomass productivity with other commercially relevant microalgae. The results showed that five strains had autotrophic biomass productivities comparable to other microalgae, indicating their potential for large-scale autotrophic biomass production under acidic conditions. Additionally, two strains demonstrated the ability to grow mixotrophically and heterotrophically.
FRONTIERS IN MICROBIOLOGY
(2022)
Article
Green & Sustainable Science & Technology
H. Feng, Y. N. Liang, X. Hu
Summary: Natural organic matter (NOM) has been widely studied due to its unique compositions and configurations. Despite the negative environmental impacts, NOM has shown great potential in environmental conservation and remediation. This review focuses on the applications of NOM in soil remediation, water treatment, phytoremediation, soil erosion control, and photocatalysis, discussing their working principles and recent developments. The review also addresses the challenges and prospects of synthetic humic-like acid (SHLA) in environmental remediation.
MATERIALS TODAY SUSTAINABILITY
(2022)
Article
Energy & Fuels
Detlef Bahnemann, Peter Robertson, Chuanyi Wang, Wonyong Choi, Helen Daly, Mohtaram Danish, Hugo de Lasa, Salvador Escobedo, Christopher Hardacre, Tae Hwa Jeon, Bupmo Kim, Horst Kisch, Wei Li, Mingce Long, M. Muneer, Nathan Skillen, Jingzheng Zhang
Summary: As nations transition towards low or net zero carbon economies due to global climate change, the need for practical alternative fuels is urgent. Hydrogen gas is considered one of the most desirable substitutes for traditional hydrocarbons, but obtaining "green" hydrogen from low or zero carbon footprint sources presents challenges. Research focuses on practical techniques for producing "green" hydrogen through photocatalytic or photoelectrocatalytic processes. However, the capability of this technology to produce hydrogen at scale has faced significant issues. This road map article explores various aspects of photocatalytic and photoelectrocatalytic hydrogen generation, including processes, materials science, reactor engineering, and biomass reforming applications.
JOURNAL OF PHYSICS-ENERGY
(2023)
Article
Nanoscience & Nanotechnology
Reshalaiti Hailili, Xiaokaiti Reyimu, Zelong Li, Xu Lu, Detlef W. Bahnemann
Summary: Effective removal of dilute nitrogen oxide (NO, ppb) without NO2 emission is still challenging in environmental pollution control. The construction of photocatalysts with diversified microstructures and atomic arrangements has been found to promote NO adsorption, activation, and complete removal without secondary pollution. In this study, the microstructure of ZnO photocatalysts was regulated by altering the reaction temperature and alkalinity, resulting in enhanced NO removal and reduced NO2 yields through defect-related surface-interface aspects. Mechanistic exploitations revealed that regulated microstructures, defect-related charge carrier separation, and strengthened surface interactions contributed to improved NO removal and simultaneous avoidance of NO2 formation. This investigation sheds light on the facile regulation of microstructures and the roles of surface chemistry in the oxidation of low concentration NO in the ppb level upon light illumination.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Physical
Muhammad Kamran, Tarek A. Kandiel, Safwat Abdel-Azeim, Mohamed A. Morsy, Detlef W. Bahnemann
Summary: This article explores TiO2 nanomaterials as promising photocatalysts for NOx depollution from air under sunlight irradiation. Experimental results show that brookite TiO2 exhibits comparable photocatalytic activity to benchmark TiO2 P25 and higher selectivity towards the conversion of NOx into nitrate ions. The enhanced selectivity is attributed to the higher density of defects on brookite TiO2 surfaces, which facilitates the adsorption of NO2 while favoring the dissociative adsorption of water.
JOURNAL OF PHYSICAL CHEMISTRY C
(2023)
Article
Chemistry, Physical
Jing Ma, Yang Tang, Gui Lu, Yu Wang, Wenke Niu, Dong Fu, Kai Zhang, Detlef W. Bahnemann, Jia Hong Pan
Summary: A PVDF/CB/TiO2 conductive membrane was fabricated through the hybridization of PVDF, mesoporous TiO2 spheres (MTS), and carbon black (CB). The membrane showed a highly porous structure and excellent photoelectrocatalytic (PEC) properties, achieving a high decolorization rate of methylene blue (MB) in a continuous cross-flow filtration process.
JOURNAL OF PHYSICAL CHEMISTRY C
(2023)
Article
Nanoscience & Nanotechnology
Haoran Wang, Reshalaiti Hailili, Xiaoyu Jiang, Guoliang Yuan, Detlef W. Bahnemann, Xiong Wang
Summary: The successful construction of heterojunction facilitates the improvement of solar light utilization efficiency. In this study, visible-light-driven AgBr was deposited on the surface of lamellar BiVO4 to enhance charge carrier separation and photocatalytic effectiveness. The catalyst with an optimal AgBr/BiVO4 ratio exhibited significantly enhanced decolorization ability and high stability. The S-scheme carrier migration mechanism was investigated, revealing the effective charge carrier separation/transfer and the excellent photocatalytic performance.
Article
Chemistry, Multidisciplinary
Jakob Schlenkrich, Franziska Luebkemann-Warwas, Rebecca T. Graf, Christoph Wesemann, Larissa Schoske, Marina Rosebrock, Karen D. J. Hindricks, Peter Behrens, Detlef W. Bahnemann, Dirk Dorfs, Nadja C. Bigall
Summary: Destabilizing ligand-stabilized semiconductor nanocrystal solutions results in the formation of macroporous self-supporting nanocrystal networks called hydrogels, which have high surface accessibility. The delocalization of charge carriers in these gels extends their mobility and enhances photocatalytic reactions. Recent advances in colloid chemistry enable the synthesis of nanocrystals with specific physicochemical properties, which, when combined with nanocrystal-based hydrogels, can lead to novel materials with optimized photocatalytic properties. This study demonstrates that CdSe quantum dots, CdS nanorods, and CdSe/CdS dot-in-rod-shaped nanorods as nanocrystal-based hydrogels show significantly higher hydrogen production rates compared to their ligand-stabilized nanocrystal solutions. The gel synthesis through controlled destabilization by ligand oxidation ensures high surface-to-volume ratio, facilitates photocatalytic hydrogen production without a co-catalyst, and overcomes colloidal instability issues in photocatalysis. X-ray photoelectron spectroscopy and photoelectrochemical measurements confirm the advantageous properties of these 3D networks for photocatalytic hydrogen production.
Article
Acoustics
Peter Delaney, Varaha P. Sarvothaman, Sanjay Nagarajan, David Rooney, Peter K. J. Robertson, Vivek V. Ranade
Summary: Hydrodynamic Cavitation (HC) is a promising method for enhancing oxidative desulphurization of fuels. This study investigated the oxidation of single ring thiophene in a model fuel over a wide range of volume fraction of organic phase. The influence of HC device type and scale on the desulphurization performance was also examined.
ULTRASONICS SONOCHEMISTRY
(2023)
Article
Chemistry, Physical
Lan Lan, Helen Daly, Rehana Sung, Floriana Tuna, Nathan Skillen, Peter K. J. Robertson, Christopher Hardacre, Xiaolei Fan
Summary: This study investigated the mechanistic details of glucose photoreforming over TiO2 and Pt/m-TiO2 catalysts. The alpha-scission mechanism of glucose oxidation was confirmed by the formation of arabinose and formic acid in the initial oxidation step. The selectivity to sugar products and formic acid differed over Pt/TiO2 and TiO2, with Pt/TiO2 showing lower selectivity to formic acid due to enhanced adsorption/conversion. In situ ATR-IR spectroscopy revealed the presence of molecular formic acid and formate on the surface of both catalysts, suggesting the dominance of formic acid oxidation in glucose photoreforming.
Article
Chemistry, Physical
Jia Hong Pan, Peter K. J. Robertson, Michael Wark
Summary: In honor of Prof. Dr. Detlef W. Bahnemann's 70th birthday and his distinguished contributions in semiconductor photocatalysis and nanotechnology, a Special Issue (SI) has been organized, consisting of 5 review articles and 34 research articles contributed by colleagues, collaborators, friends, and former group members from over 30 countries on five continents. The SI covers heterogeneous semiconductor photo(electro)catalysis, including novel photocatalysts and photo(electro)catalytic processes, mechanism study, activity evaluation method, and applications in environmental remediation, disinfection, solar fuel generation, and CO2 reduction. The SI presents the research frontiers in semiconductor photo(electro)catalysis and provides an overview of Prof. Bahnemann's education, career experiences, and research achievements in this Editorial.
APPLIED CATALYSIS A-GENERAL
(2023)
Editorial Material
Chemistry, Physical
Kangwoo Cho, Wonyong Choi, Detlef Bahnemann
JOURNAL OF PHYSICAL CHEMISTRY A
(2023)
Editorial Material
Chemistry, Physical
Kangwoo Cho, Wonyong Choi, Detlef Bahnemann
JOURNAL OF PHYSICAL CHEMISTRY A
(2023)
Article
Chemistry, Multidisciplinary
Wesley J. McCormick, Peter K. J. Robertson, Nathan Skillen, Denis McCrudden
Summary: This study introduces a novel voltammetric method for determining emamectin benzoate (EB) using a cathodically pretreated boron-doped diamond electrode (CTP-BDDE) for the first time. The CPT-BDDE electrode showed a well-defined irreversible signal at -1.35 V (vs. Ag/AgCl) using cyclic voltammetry. Square wave voltammetry was used to quantify EB concentrations in real sea water samples, and the method was found to be unaffected by other insecticides and inorganic ions present in seawater.
RESULTS IN CHEMISTRY
(2023)
Article
Green & Sustainable Science & Technology
Xinzhu Pang, Nathan Skillen, Jiaman Wu, Varaha P. Sarvothaman, David W. Rooney, Peter K. J. Robertson
Summary: Semiconductor photocatalysis is a versatile process that has been widely used in various applications. Controlled Periodic Illumination (CPI) can be used to control the intensity of photons entering the system and identify the limiting factors in a reaction. This paper evaluates the limiting factors in the photocatalytic generation of H2O2 and H2 using CPI, and highlights the different effects of CPI on different catalysts.
SUSTAINABLE MATERIALS AND TECHNOLOGIES
(2023)
Article
Engineering, Environmental
Haitao Ren, Fan Qi, Abdelkader Labidi, Ahmed A. Allam, Jamaan S. Ajarem, Detlef W. Bahnemann, Chuanyi Wang
Summary: In this study, carbon quantum dots (CQDs) with excellent fluorescence properties were prepared from apple leaf waste and used as a fluorescent probe for the detection of Fe3+ in aqueous environments. The CQDs exhibited high fluorescence stability, specific recognition ability for Fe3+, and recyclability.
ACS ES&T ENGINEERING
(2023)