Strategies to break linear scaling relationships

Dynamics of Subnanometer Pt Clusters Can Break the Scaling Relationships in Catalysis

(2019) Borna Zandkarimi et al.   Journal of Physical Chemistry Letters

Selective Electrochemical Nitrogen Reduction Driven by Hydrogen Bond Interactions at Metal–Ionic Liquid Interfaces

(2019) Manuel A. Ortuño et al.   Journal of Physical Chemistry Letters

Disentangling the size-dependent geometric and electronic effects of palladium nanocatalysts beyond selectivity

(2019) Hengwei Wang et al.   Science Advances

Atom-by-Atom Resolution of Structure-Function Relations over Low-Nuclearity Metal Catalysts

(2019) Evgeniya Vorobyeva et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Principles of Dynamic Heterogeneous Catalysis: Surface Resonance and Turnover Frequency Response

(2019) Matthew Alexander Ardagh et al.   ACS Catalysis

Synthetic applications of light, electricity, mechanical force and flow

(2019) Johnathon C. Robertson et al.   Nature Reviews Chemistry

The Carboxylate Ligand as an Oxide Relay in Catalytic Water Oxidation

(2019) Shaoqi Zhan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Atomic-scale engineering of indium oxide promotion by palladium for methanol production via CO2 hydrogenation

(2019) Matthias S. Frei et al.   Nature Communications

Brønsted Acid Scaling Relationships Enable Control Over Product Selectivity from O2 Reduction with a Mononuclear Cobalt Porphyrin Catalyst

(2019) Yu-Heng Wang et al.   ACS Central Science

Direct magnetic enhancement of electrocatalytic water oxidation in alkaline media

(2019) Felipe A. Garcés-Pineda et al.   Nature Energy

Dynamic charge and oxidation state of Pt/CeO2 single-atom catalysts

(2019) Nathan Daelman et al.   NATURE MATERIALS

Breaking Linear Scaling Relationships with Secondary Interactions in Confined Space: A Case Study of Methane Oxidation by Fe/ZSM-5 Zeolite

(2019) Ágnes Szécsényi et al.   ACS Catalysis

Pt/Cu single-atom alloys as coke-resistant catalysts for efficient C–H activation

(2018) Matthew D. Marcinkowski et al.   Nature Chemistry

Selective ensembles in supported palladium sulfide nanoparticles for alkyne semi-hydrogenation

(2018) Davide Albani et al.   Nature Communications

Understanding and Breaking Scaling Relations in Single-Site Catalysis: Methane to Methanol Conversion by FeIV═O

(2018) Terry Z. H. Gani et al.   ACS Catalysis

Creating Cavities at Palladium–Phosphine Interfaces for Enhanced Selectivity in Heterogeneous Biomass Conversion

(2018) Manuel A. Ortuño et al.   ACS Catalysis

Electrostatic Origins of Linear Scaling Relationships at Bifunctional Metal/Oxide Interfaces: A Case Study of Au Nanoparticles on Doped MgO Substrates

(2018) Tej Choksi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lonely Atoms with Special Gifts: Breaking Linear Scaling Relationships in Heterogeneous Catalysis with Single-Atom Alloys

(2018) Matthew T. Darby et al.   Journal of Physical Chemistry Letters

Mechanistic Insights into the Synthesis of Higher Alcohols from Syngas on CuCo-alloys

(2018) Ang Cao et al.   ACS Catalysis

Enhanced Electrochemical Water Splitting with Chiral Molecule-Coated Fe3O4 Nanoparticles

(2018) Wenyan Zhang et al.   ACS Energy Letters

Origin of the Selective Electroreduction of Carbon Dioxide to Formate by Chalcogen Modified Copper

(2018) Rodrigo García-Muelas et al.   Journal of Physical Chemistry Letters

Breaking the scaling relationship via thermally stable Pt/Cu single atom alloys for catalytic dehydrogenation

(2018) Guodong Sun et al.   Nature Communications

Interfacial acidity in ligand-modified ruthenium nanoparticles boosts the hydrogenation of levulinic acid to gamma-valerolactone

(2017) Davide Albani et al.   GREEN CHEMISTRY

Synthesis of Pt3Y and Other Early–Late Intermetallic Nanoparticles by Way of a Molten Reducing Agent

(2017) Jacob S. Kanady et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Concerted Chemoselective Hydrogenation of Acrolein on Secondary Phosphine Oxide Decorated Gold Nanoparticles

(2017) Neyvis Almora-Barrios et al.   ACS Catalysis

Gold–Ligand-Catalyzed Selective Hydrogenation of Alkynes into cis-Alkenes via H2 Heterolytic Activation by Frustrated Lewis Pairs

(2017) Jhonatan L. Fiorio et al.   ACS Catalysis

Reproducibility in density functional theory calculations of solids

(2016) K. Lejaeghere et al.   SCIENCE

Homogeneously dispersed multimetal oxygen-evolving catalysts

(2016) B. Zhang et al.   SCIENCE

Recent Advances in Breaking Scaling Relations for Effective Electrochemical Conversion of CO2

(2016) Yawei Li et al.   Advanced Energy Materials

Beyond the top of the volcano? – A unified approach to electrocatalytic oxygen reduction and oxygen evolution

(2016) Michael Busch et al.   Nano Energy

A Stable Single-Site Palladium Catalyst for Hydrogenations

(2015) Gianvito Vilé et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From the Sabatier principle to a predictive theory of transition-metal heterogeneous catalysis

(2015) Andrew J. Medford et al.   JOURNAL OF CATALYSIS

Introducing structural sensitivity into adsorption–energy scaling relations by means of coordination numbers

(2015) Federico Calle-Vallejo et al.   Nature Chemistry

Linear scaling relationships and volcano plots in homogeneous catalysis – revisiting the Suzuki reaction

(2015) Michael Busch et al.   Chemical Science

New design paradigm for heterogeneous catalysts

(2015) Aleksandra Vojvodic et al.   National Science Review

The Virtue of Defects: Stable Bromine Production by Catalytic Oxidation of Hydrogen Bromide on Titanium Oxide

(2014) Maximilian Moser et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From the Lindlar Catalyst to Supported Ligand-Modified Palladium Nanoparticles: Selectivity Patterns and Accessibility Constraints in the Continuous-Flow Three-Phase Hydrogenation of Acetylenic Compounds

(2014) Gianvito Vilé et al.   CHEMISTRY-A EUROPEAN JOURNAL

Homolytic Products from Heterolytic Paths in H2 Dissociation on Metal Oxides: The Example of CeO2

(2014) Max García-Melchor et al.   Journal of Physical Chemistry C

Beyond the volcano limitations in electrocatalysis – oxygen evolution reaction

(2014) Niels Bendtsen Halck et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Silver Nanoparticles for Olefin Production: New Insights into the Mechanistic Description of Propyne Hydrogenation

(2013) Gianvito Vilé et al.   ChemCatChem

Activity and Selectivity Trends in Synthesis Gas Conversion to Higher Alcohols

(2013) Andrew J. Medford et al.   TOPICS IN CATALYSIS

Isolated Metal Atom Geometries as a Strategy for Selective Heterogeneous Hydrogenations

(2012) Georgios Kyriakou et al.   SCIENCE

Mechanochemistry: opportunities for new and cleaner synthesis

(2011) Stuart L. James et al.   CHEMICAL SOCIETY REVIEWS

Selectivity enhancement in acetylene hydrogenation over diphenyl sulphide-modified Pd/TiO2 catalysts

(2011) Fiona-Mairead McKenna et al.   JOURNAL OF CATALYSIS

Plasmonic-metal nanostructures for efficient conversion of solar to chemical energy

(2011) Suljo Linic et al.   NATURE MATERIALS

Volcano Relation for the Deacon Process over Transition-Metal Oxides

(2009) Felix Studt et al.   ChemCatChem

Towards the computational design of solid catalysts

(2009) J. K. Nørskov et al.   Nature Chemistry

Subnanometre platinum clusters as highly active and selective catalysts for the oxidative dehydrogenation of propane

(2009) Stefan Vajda et al.   NATURE MATERIALS