The Effect of Symmetric and Asymmetric NHCs on the Structure and Catalytic Properties of Dialkylgallium Alkoxides in the Ring-Opening Polymerization of rac-Lactide—Linking the Structure, Activity, and Stereoselectivity

N-heterocyclic carbene complexes in ring opening polymerization

(2021) Isha Jain et al.   EUROPEAN POLYMER JOURNAL

Alkaline Earth Metal‐Mediated Highly Iso‐selective Ring‐Opening Polymerization of rac ‐Lactide

(2020) Jayeeta Bhattacharjee et al.   Chemistry-An Asian Journal

Mechanism of Initiation Stereocontrol in Polymerization of rac-Lactide by Aluminum Complexes Supported by Indolide–Imine Ligands

(2020) Anna M. Luke et al.   MACROMOLECULES

N-Heterocyclic carbene/Lewis acid-mediated ring-opening polymerization of propylene oxide. Part 1: Triisobutylaluminum as an efficient controlling agent

(2020) Qilei Song et al.   EUROPEAN POLYMER JOURNAL

The Dual-Stereocontrol Mechanism: Heteroselective Polymerization of rac-Lactide and Syndioselective Polymerization of meso-Lactide by Chiral Aluminum Salan Catalysts

(2019) Rami Hador et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tuning the Thiolen: Al(III) and Fe(III) Thiolen Complexes for the Isoselective ROP of rac-Lactide

(2019) Jack A. Stewart et al.   MACROMOLECULES

Coordination Ring-Opening Polymerization of Cyclic Esters: A Critical Overview of DFT Modeling and Visualization of the Reaction Mechanisms

(2019) Ilya Nifant’ev et al.   MOLECULES

Recent Advances in Metal‐Mediated Stereoselective Ring‐Opening Polymerization of Functional Cyclic Esters towards Well‐Defined Poly(hydroxy acid)s: From Stereoselectivity to Sequence‐Control

(2019) Hui Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

NHCs in Main Group Chemistry

(2018) Vitaly Nesterov et al.   CHEMICAL REVIEWS

Electronic Properties of N-Heterocyclic Carbenes and Their Experimental Determination

(2018) Han Vinh Huynh   CHEMICAL REVIEWS

On the alcoholysis of alkyl-aluminum(iii) alkoxy-NHC derivatives: reactivity of the Al-carbene Lewis pair versus Al-alkyl

(2018) Vincent Dardun et al.   DALTON TRANSACTIONS

Probing the M–CNHC Bond and Its Effect on the Synthesis, Structure, and Reactivity of R2MOR(NHC) (M = Al, Ga, In) Complexes

(2018) Rafał Zaremba et al.   ORGANOMETALLICS

Dinuclear catalysts for the ring opening polymerization of lactide

(2018) Alexandre B. Kremer et al.   COORDINATION CHEMISTRY REVIEWS

Towards NHC stabilized alkylgallium alkoxide/aryloxide cations – The advances, the limitations and the challenges

(2017) Anna Maria Dąbrowska et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Highly Robust Yttrium Bis(phenolate) Ether Catalysts for Excellent Isoselective Ring-Opening Polymerization of Racemic Lactide

(2017) Tie-Qi Xu et al.   MACROMOLECULES

Synthesis and structural characterization of NHC-stabilized Al(III) and Ga(III) alkyl cations and use in the ring-opening polymerization of lactide

(2016) Gilles Schnee et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Effect of In–CNHC Bonds on the Synthesis, Structure, and Reactivity of Dialkylindium Alkoxides: How Indium Compares to Gallium

(2016) Martyna Cybularczyk et al.   ORGANOMETALLICS

Simple sodium and potassium phenolates as catalysts for highly isoselective polymerization of rac-lactide

(2016) Zhongran Dai et al.   Catalysis Science & Technology

Discrete Cationic Complexes for Ring-Opening Polymerization Catalysis of Cyclic Esters and Epoxides

(2015) Yann Sarazin et al.   CHEMICAL REVIEWS

Switchable Polymerization Catalysts

(2015) Aaron J. Teator et al.   CHEMICAL REVIEWS

Beyond Stereoselectivity, Switchable Catalysis: Some of the Last Frontier Challenges in Ring-Opening Polymerization of Cyclic Esters

(2015) Sophie M. Guillaume et al.   CHEMISTRY-A EUROPEAN JOURNAL

Scandium and Yttrium Phosphasalen Complexes as Initiators for Ring-Opening Polymerization of Cyclic Esters

(2015) Clare Bakewell et al.   INORGANIC CHEMISTRY

Intramolecular and intermolecular bromine⋯polyfluoroarene interactions: The crystal structure of bis{κC-1-(2,3,5,6-tetrafluoropyridyl)-3-benzylimidazolin-2-ylidene}tetrabromodimercury

(2015) Joseph R. Lane et al.   JOURNAL OF FLUORINE CHEMISTRY

Dialkylgallium Alkoxides Stabilized with N-Heterocyclic Carbenes: Opportunities and Limitations for the Controlled and Stereoselective Polymerization of rac-Lactide

(2015) Paweł Horeglad et al.   ORGANOMETALLICS

Overcoming aggregation in indium salen catalysts for isoselective lactide polymerization

(2015) D. C. Aluthge et al.   Chemical Science

SHELXT– Integrated space-group and crystal-structure determination

(2015) George M. Sheldrick   Acta Crystallographica A-Foundation and Advances

PLATONSQUEEZE: a tool for the calculation of the disordered solvent contribution to the calculated structure factors

(2015) Anthony L. Spek   Acta Crystallographica Section C-Structural Chemistry

Crystal structure refinement withSHELXL

(2015) George M. Sheldrick   Acta Crystallographica Section C-Structural Chemistry

Controlled ring-opening polymerization of trimethylene carbonate and access to PTMC-PLA block copolymers mediated by well-definedN-heterocyclic carbene zinc alkoxides

(2014) Christophe Fliedel et al.   APPLIED ORGANOMETALLIC CHEMISTRY

Dinuclear Zinc-N-Heterocyclic Carbene Complexes for Either the Controlled Ring-Opening Polymerization of Lactide or the Controlled Degradation of Polylactide Under Mild Conditions

(2014) Christophe Fliedel et al.   ChemCatChem

Group 1 and 2 and Early Transition Metal Complexes Bearing N-Heterocyclic Carbene Ligands: Coordination Chemistry, Reactivity, and Applications

(2014) Stéphane Bellemin-Laponnaz et al.   CHEMICAL REVIEWS

Group 13 metal (Al, Ga, In, Tl) complexes supported by heteroatom-bonded carbene ligands

(2014) Christophe Fliedel et al.   COORDINATION CHEMISTRY REVIEWS

NHC Bis-Phenolate Aluminum Chelates: Synthesis, Structure, and Use in Lactide and Trimethylene Carbonate Polymerization

(2014) Charles Romain et al.   ORGANOMETALLICS

Polylactides-an overview

(2014) Stanislaw Slomkowski et al.   POLYMERS FOR ADVANCED TECHNOLOGIES

Zinc-Catalyzed Highly Isoselective Ring Opening Polymerization of rac-Lactide

(2014) Srinivas Abbina et al.   ACS Macro Letters

Unusual Tilted Carbene Coordination in Carbene Complexes of Gallium(I) and Indium(I)

(2013) Alexander Higelin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The influence of organosuperbases on the structure and activity of dialkylgallium alkoxides in the polymerization ofrac-lactide: the road to stereo diblock PLA copolymers

(2013) Paweł Horeglad et al.   APPLIED ORGANOMETALLIC CHEMISTRY

Abnormal N-heterocyclic carbene main group organometallic chemistry: a debut to the homogeneous catalysis

(2013) Tamal K. Sen et al.   DALTON TRANSACTIONS

Dialkylgallium Complexes with Alkoxide and Aryloxide Ligands Possessing N-Heterocyclic Carbene Functionalities: Synthesis and Structure

(2013) Paweł Horeglad et al.   ORGANOMETALLICS

{Phenoxy-imine}aluminum versus -indium Complexes for the Immortal ROP of Lactide: Different Stereocontrol, Different Mechanisms

(2013) Mickael Normand et al.   ORGANOMETALLICS

Protic compound mediated living cross-chain-transfer polymerization of rac-lactide: synthesis of isotactic (crystalline)–heterotactic (amorphous) stereomultiblock polylactide

(2012) Wei Zhao et al.   CHEMICAL COMMUNICATIONS

Mechanism of Living Lactide Polymerization by Dinuclear Indium Catalysts and Its Impact on Isoselectivity

(2012) Insun Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Yttrium Phosphasalen Initiators for rac-Lactide Polymerization: Excellent Rates and High Iso-Selectivities

(2012) Clare Bakewell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ring-Opening Polymerization of Lactide with Zr Complexes of {ONSO} Ligands: From Heterotactically Inclined to Isotactically Inclined Poly(lactic acid)

(2012) Ayellet Stopper et al.   MACROMOLECULES

Bis(1-benzyl-3-methylimidazolium-κC2)mercury(II) bis(hexafluoridophosphate)

(2011) Rosenani A. Haque et al.   ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

The first facile stereoselectivity switch in the polymerization of rac-lactide—from heteroselective to isoselective dialkylgallium alkoxides with the help of N-heterocyclic carbenes

(2011) Paweł Horeglad et al.   CHEMICAL COMMUNICATIONS

The Measure of All Rings-N-Heterocyclic Carbenes

(2010) Thomas Dröge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Poly(lactide)s with Modified Thermal and Mechanical Properties

(2010) Jan M. Becker et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Heteroselective Polymerization ofrac-Lactide in the Presence of Dialkylgallium Alkoxides: The Effect of Lewis Base on Polymerization Stereoselectivity

(2010) Paweł Horeglad et al.   ORGANOMETALLICS

Single site catalysts for stereoselective ring-opening polymerization of lactides

(2010) Pieter Jelle Dijkstra et al.   Polymer Chemistry

Stereocontrolled ring-opening polymerisation of lactide

(2009) Matthew J. Stanford et al.   CHEMICAL SOCIETY REVIEWS

Stereocontrolled ring-opening polymerization of cyclic esters: synthesis of new polyester microstructures

(2009) Christophe M. Thomas   CHEMICAL SOCIETY REVIEWS

Magnesium and zinc complexes of functionalised, saturated N-heterocyclic carbene ligands: carbene lability and functionalisation, and lactide polymerisation catalysis

(2009) Polly L. Arnold et al.   DALTON TRANSACTIONS

SambVca: A Web Application for the Calculation of the Buried Volume of N-Heterocyclic Carbene Ligands

(2009) Albert Poater et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

OLEX2: a complete structure solution, refinement and analysis program

(2009) Oleg V. Dolomanov et al.   JOURNAL OF APPLIED CRYSTALLOGRAPHY

Stereogenic-at-Metal Zn- and Al-Based N-Heterocyclic Carbene (NHC) Complexes as Bifunctional Catalysts in Cu-Free Enantioselective Allylic Alkylations

(2009) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Structure of an Amino-Linked N-Heterocyclic Carbene and the Reactivity of its Aluminum Adduct

(2009) Wei-Chih Shih et al.   ORGANOMETALLICS

C3-Symmetric Lanthanide Tris(alkoxide) Complexes Formed by Preferential Complexation and Their Stereoselective Polymerization ofrac-Lactide

(2008) Polly L. Arnold et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

New N-heterocyclic carbene mercury(II) and silver(I) complexes

(2007) Qing-Xiang Liu et al.   POLYHEDRON