Controlled ring-opening polymerization of trimethylene carbonate and access to PTMC-PLA block copolymers mediated by well-definedN-heterocyclic carbene zinc alkoxides

Molecular Zinc Dihydride Stabilized by N-Heterocyclic Carbenes

(2013) Arnab Rit et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Al–H σ-bond coordination: expanded ring carbene adducts of AlH3 as neutral bi- and tri-functional donor ligands

(2013) Joseph A. B. Abdalla et al.   CHEMICAL COMMUNICATIONS

Discrete Divalent Rare-Earth Cationic ROP Catalysts: Ligand-Dependent Redox Behavior and Discrepancies with Alkaline-Earth Analogues in a Ligand-Assisted Activated Monomer Mechanism

(2013) Bo Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Gallium and indium complexes for ring-opening polymerization of cyclic ethers, esters and carbonates

(2013) Samuel Dagorne et al.   COORDINATION CHEMISTRY REVIEWS

Zinc complexes supported by methyl salicylato ligands: synthesis, structure, and application in ring-opening polymerization of l-lactide

(2013) Rafał Petrus et al.   DALTON TRANSACTIONS

Magnesium complexes supported by salan-like ligands: Synthesis, characterization and their application in the ring-opening polymerization of rac-lactide

(2013) Shaodi Song et al.   DALTON TRANSACTIONS

Abnormal N-heterocyclic carbene main group organometallic chemistry: a debut to the homogeneous catalysis

(2013) Tamal K. Sen et al.   DALTON TRANSACTIONS

Synthesis and structures of calcium and strontium 2,4-di-tert-butylphenolates and their reactivity towards the amine co-initiated ring-opening polymerisation of rac-lactide

(2013) Lawrence Clark et al.   DALTON TRANSACTIONS

Synthesis and structures of tridentate ketoiminate zinc complexes bearing trifluoromethyl substituents that act as l-lactide ring opening polymerization initiators

(2013) Nomaan M. Rezayee et al.   DALTON TRANSACTIONS

Potassium, zinc, and magnesium complexes of a bulky OOO-tridentate bis(phenolate) ligand: synthesis, structures, and studies of cyclic ester polymerisation

(2013) Yong Huang et al.   DALTON TRANSACTIONS

Structurally well-defined group 4 metal complexes as initiators for the ring-opening polymerization of lactide monomers

(2013) Andreas Sauer et al.   DALTON TRANSACTIONS

Neutral and Cationic N-Heterocyclic Carbene Zinc Adducts and the BnOH/Zn(C6F5)2Binary Mixture - Characterization and Use in the Ring-Opening Polymerization of β-Butyrolactone, Lactide, and Trimethylene Carbonate

(2013) Gilles Schnee et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Recent advances in S-functionalized N-heterocyclic carbene ligands: From the synthesis of azolium salts and metal complexes to applications

(2013) Christophe Fliedel et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Group 12 Metal Complexes of N-Heterocyclic Ditopic Carbanionic Carbenes

(2013) Jordan B. Waters et al.   ORGANOMETALLICS

Synthesis and Structural Characterization of Various N,O,N-Chelated Aluminum and Gallium Complexes for the Efficient ROP of Cyclic Esters and Carbonates: How Do Aluminum and Gallium Derivatives Compare ?

(2013) Frédéric Hild et al.   ORGANOMETALLICS

Alkali-metal-mediated zincation (AMMZn) meets N-heterocyclic carbene (NHC) chemistry: Zn–H exchange reactions and structural authentication of a dinuclear Au(i) complex with a NHC anion

(2013) David R. Armstrong et al.   Chemical Science

A robust zirconium N-heterocyclic carbene complex for the living and highly stereoselective ring-opening polymerization of rac-lactide

(2012) Charles Romain et al.   CHEMICAL COMMUNICATIONS

Metal-only Lewis pairs featuring unsupported Pt→M (M = Zn or Cd) dative bonds

(2012) Mengtao Ma et al.   CHEMICAL COMMUNICATIONS

Titanium pyridonates and amidates: novel catalysts for the synthesis of random copolymers

(2012) Ruth L. Webster et al.   CHEMICAL COMMUNICATIONS

Synthetic and Mechanistic Aspects of the Immortal Ring-Opening Polymerization of Lactide and Trimethylene Carbonate with New Homo- and Heteroleptic Tin(II)-Phenolate Catalysts

(2012) Valentin Poirier et al.   CHEMISTRY-A EUROPEAN JOURNAL

Abnormal, mesoionic and remote N-heterocyclic carbene complexes

(2012) Robert H. Crabtree   COORDINATION CHEMISTRY REVIEWS

Ring-opening polymerisation of rac-lactide mediated by cationic zinc complexes featuring P-stereogenic bisphosphinimine ligands

(2012) Hongsui Sun et al.   DALTON TRANSACTIONS

Dimethylaluminium aldiminophenolates: synthesis, characterization and ring-opening polymerization behavior towards lactides

(2012) Wenjuan Zhang et al.   DALTON TRANSACTIONS

Highly active zinc alkyl cations for the controlled and immortal ring-opening polymerization of ε-caprolactone

(2012) Charles Romain et al.   DALTON TRANSACTIONS

Synthesis and structural characterization of novel cyclam-based zirconium complexes and their use in the controlled ROP of rac-lactide: access to cyclam-functionalized polylactide materials

(2012) Luis G. Alves et al.   DALTON TRANSACTIONS

Zinc complexes supported by claw-type aminophenolate ligands: synthesis, characterization and catalysis in the ring-opening polymerization of rac-lactide

(2012) Shaodi Song et al.   DALTON TRANSACTIONS

Calcium complexes containing oxalamidinate ligands as catalysts for ε-caprolactone polymerization

(2012) Tzu-Lun Huang et al.   DALTON TRANSACTIONS

Synthesis and rac-lactide ring-opening polymerisation studies of new alkaline earth tetrahydroborate complexes

(2012) Richard A. Collins et al.   DALTON TRANSACTIONS

Synthesis, Characterization, and Lactide Polymerization Activity of Group 4 Metal Complexes Containing Two Bis(phenolate) Ligands

(2012) Andreas Sauer et al.   INORGANIC CHEMISTRY

Stereoselective Synthesis of Biphenolate/Binaphtolate Titanate and Zirconate Alkoxide Species: Structural Characterization and Use in the Controlled ROP of Lactide

(2012) Laurine Azor et al.   INORGANIC CHEMISTRY

Ring-opening polymerization of lactides catalyzed by magnesium complexes coordinated with NNO-tridentate pyrazolonate ligands

(2012) Hui-Ju Chuang et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Yttrium Phosphasalen Initiators for rac-Lactide Polymerization: Excellent Rates and High Iso-Selectivities

(2012) Clare Bakewell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Magnesium and Zinc Complexes Supported by N,O-Bidentate Pyridyl Functionalized Alkoxy Ligands: Synthesis and Immortal ROP of ε-CL and l-LA

(2012) Yang Wang et al.   ORGANOMETALLICS

Synthesis and Structures of Tridentate Ketoiminate Zinc Complexes That Act As l-Lactide Ring-Opening Polymerization Catalysts

(2012) Courtney C. Roberts et al.   ORGANOMETALLICS

Chiral N,N,O-Scorpionate Zinc Alkyls as Effective and Stereoselective Initiators for the Living ROP of Lactides

(2012) Antonio Otero et al.   ORGANOMETALLICS

A dual organic/organometallic approach for catalytic ring-opening polymerization

(2011) Estefanía Piedra-Arroni et al.   CHEMICAL COMMUNICATIONS

Heteroscorpionate Rare-Earth Metal Zwitterionic Complexes: Syntheses, Characterization, and Heteroselective Catalysis on the Ring-Opening Polymerization of rac-Lactide

(2011) Zhichao Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Exploring Electronic versus Steric Effects in Stereoselective Ring-Opening Polymerization of Lactide and β-Butyrolactone with Amino-alkoxy-bis(phenolate)-Yttrium Complexes

(2011) Miloud Bouyahyi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Zinc and magnesium complexes incorporated by bis(amine) benzotriazole phenoxide ligand: Synthesis, characterization, photoluminescent properties and catalysis for ring-opening polymerization of lactide

(2011) Chang-Yu Sung et al.   DALTON TRANSACTIONS

Toward Stereoselective Lactide Polymerization Catalysts: Cationic Zinc Complexes Supported by a Chiral Phosphinimine Scaffold

(2011) Hongsui Sun et al.   INORGANIC CHEMISTRY

Bis(phosphinic)diamido Yttrium Amide, Alkoxide, and Aryloxide Complexes: An Evaluation of Lactide Ring-Opening Polymerization Initiator Efficiency

(2011) Rachel H. Platel et al.   INORGANIC CHEMISTRY

Discrete, Solvent-Free Alkaline-Earth Metal Cations: Metal···Fluorine Interactions and ROP Catalytic Activity

(2011) Yann Sarazin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Production of Poly(rac-lactide) by ROP with Highly Efficient Bulky Heteroscorpionate Alkylmagnesium Initiators

(2011) Luis F. Sánchez-Barba et al.   ORGANOMETALLICS

Novel N,O,N-Supported Tetracoordinate Aluminum Complexes for the Highly Controlled and Immortal ROP of Trimethylene Carbonate (TMC) under Mild Conditions: Access to Narrowly Disperse poly-TMC and Derived Copolymers

(2011) Frédéric Hild et al.   ORGANOMETALLICS

Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes

(2010) Mohand Melaimi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cationic zinc complexes: a new class of catalyst for living lactide polymerization at ambient temperature

(2010) Craig A. Wheaton et al.   CHEMICAL COMMUNICATIONS

Unusual reactivity in organoaluminium and NHC chemistry: deprotonation of AlMe3 by an NHC moiety involving the formation of a sterically bulky NHC–AlMe3 Lewis adduct

(2010) Anne-Laure Schmitt et al.   CHEMICAL COMMUNICATIONS

Iron(III) and Zinc(II) Calixarene Complexes: Synthesis, Structural Studies, and Use as Procatalysts for ε-Caprolactone Polymerization

(2010) Abdessamad Arbaoui et al.   Chemistry-An Asian Journal

Synthesis and characterisation of alkylaluminium benzimidazolates and their use in the ring-opening polymerisation of ε-caprolactone

(2010) Miao Shen et al.   DALTON TRANSACTIONS

Zinc and magnesium complexes supported by bulky multidentate amino-ether phenolate ligands: potent pre-catalysts for the immortalring-opening polymerisation of cyclic esters

(2010) Valentin Poirier et al.   DALTON TRANSACTIONS

Discrete, Base-Free, Cationic Alkaline-Earth Complexes - Access and Catalytic Activity in the Polymerization of Lactide

(2010) Yann Sarazin et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Ring-Opening Polymerization of Lactides Catalyzed by Natural Amino-Acid Based Zinc Catalysts

(2010) Donald J. Darensbourg et al.   INORGANIC CHEMISTRY

Hybrid Scorpionate/Cyclopentadienyl Magnesium and Zinc Complexes: Synthesis, Coordination Chemistry, and Ring-Opening Polymerization Studies on Cyclic Esters

(2010) Andrés Garcés et al.   INORGANIC CHEMISTRY

Magnesium, zinc, and calcium complexes based on tridentate nitrogen ligands: Syntheses, structures, and catalytic activities to the ring opening polymerization of rac-lactide

(2010) Xin Xu et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Random Copolymerization of ε-Caprolactone with Lactide Using a Homosalen−Al Complex

(2010) Nobuyoshi Nomura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Polymerization ofmeso-Lactide: Syndiotactic Polylactide by Heteroselective Initiators Based on Trivalent Metals

(2010) Jean-Charles Buffet et al.   MACROMOLECULES

Highly Active Magnesium Initiators for Ring-Opening Polymerization ofrac-Lactide

(2010) Liying Wang et al.   MACROMOLECULES

Ring-Opening Polymerization of Trimethylene Carbonate Catalyzed by Methanesulfonic Acid: Activated Monomer versus Active Chain End Mechanisms

(2010) Damien Delcroix et al.   MACROMOLECULES

Synthesis of a stable adduct of dialane(4) (Al2H4) via hydrogenation of a magnesium(I) dimer

(2010) Simon J. Bonyhady et al.   Nature Chemistry

Thioether-Functionalized N-Heterocyclic Carbenes: Mono- and Bis-(S,CNHC) Palladium Complexes, Catalytic C−C Coupling, and Characterization of a Unique Ag4I4(S,CNHC)2Planar Cluster†

(2010) Christophe Fliedel et al.   ORGANOMETALLICS

Ring-Opening Polymerization ofrac-Lactide by Bis(phenolate)amine-Supported Samarium Borohydride Complexes: An Experimental and DFT Study

(2010) Hellen E. Dyer et al.   ORGANOMETALLICS

Lactide Polymerization with Chiral β-Diketiminate Zinc Complexes

(2010) Frédéric Drouin et al.   ORGANOMETALLICS

Metal catalysts for ε-caprolactone polymerisation

(2010) Abdessamad Arbaoui et al.   Polymer Chemistry

Dicationic and zwitterionic catalysts for the amine-initiated, immortal ring-opening polymerisation of rac-lactide: facile synthesis of amine-terminated, highly heterotactic PLA

(2009) Lawrence Clark et al.   CHEMICAL COMMUNICATIONS

Lactide Polymerisation with Air-Stable and Highly Active Zinc Complexes with Guanidine-Pyridine Hybrid Ligands

(2009) Janna Börner et al.   CHEMISTRY-A EUROPEAN JOURNAL

Versatile coordination modes of novel hemilabile S-NHC ligands

(2009) Christophe Fliedel et al.   DALTON TRANSACTIONS

Complexes of Mg, Ca and Zn as homogeneous catalysts for lactide polymerization

(2009) Craig A. Wheaton et al.   DALTON TRANSACTIONS

Versatile catalytic systems based on complexes of zinc, magnesium and calcium supported by a bulky bis(morpholinomethyl)phenoxy ligand for the large-scale immortal ring-opening polymerisation of cyclic esters

(2009) Valentin Poirier et al.   DALTON TRANSACTIONS

Chemistry of BDI*M(2+) complexes (M = Mg, Zn) and their role in lactide polymerization where BDI* is the anion derived from methylenebis(C-tBu, N-2,6-diisopropylphenyl)imine BDI*H

(2009) Carla N. Ayala et al.   DALTON TRANSACTIONS

Magnesium and zinc complexes of functionalised, saturated N-heterocyclic carbene ligands: carbene lability and functionalisation, and lactide polymerisation catalysis

(2009) Polly L. Arnold et al.   DALTON TRANSACTIONS

Synthesis and structural characterization of well-defined anionic aluminium alkoxide complexes supported by NON-type diamido ether tridentate ligands and their use for the controlled ROP of lactide

(2009) Frédéric Hild et al.   DALTON TRANSACTIONS

Zinc(II) Homogeneous and Heterogeneous Species and Their Application for the Ring-Opening Polymerisation ofrac-Lactide

(2009) Matthew D. Jones et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

CO2, Magnesium, Aluminum, and Zinc Adducts of N-Heterocyclic Carbenes as (Latent) Catalysts for Polyurethane Synthesis

(2009) Bhasker Bantu et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Monomeric, Dimeric, and Trimeric Calcium Compounds Containing Substituted Pyrrolyl and Ketiminate Ligands: Synthesis and Structural Characterization

(2009) Shih-Mao Ho et al.   INORGANIC CHEMISTRY

Ring-opening polymerization of lactides initiated by magnesium and zinc complexes based on NNO-tridentate ketiminate ligands: Activity and stereoselectivity studies

(2009) Yong Huang et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Tridentate anilido-aldimine magnesium and zinc complexes as efficient catalysts for ring-opening polymerization of ε-caprolactone and L-lactide

(2009) Yueh-Hsuan Tsai et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Stereogenic-at-Metal Zn- and Al-Based N-Heterocyclic Carbene (NHC) Complexes as Bifunctional Catalysts in Cu-Free Enantioselective Allylic Alkylations

(2009) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activated Zinc Complexes Supported by a Neutral, Phosphinimine-Containing Ligand: Synthesis and Efficacy for the Polymerization of Lactide

(2009) Craig A. Wheaton et al.   ORGANOMETALLICS

Unusually Stable Chiral Ethyl Zinc Complexes: Reactivity and Polymerization of Lactide

(2009) Guillaume Labourdette et al.   ORGANOMETALLICS

Heterocyclic Carbenes: Synthesis and Coordination Chemistry

(2008) F. Ekkehardt Hahn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbenes: Synthesis, properties, and organometallic chemistry

(2008) Pierre de Frémont et al.   COORDINATION CHEMISTRY REVIEWS

Homo- and heteroleptic zinc aminophenolates as initiators for lactide polymerization

(2008) Jolanta Ejfler et al.   DALTON TRANSACTIONS

Bimetallic anilido-aldimine Al or Zn complexes for efficient ring-opening polymerization of ε-caprolactone

(2008) Wei Yao et al.   DALTON TRANSACTIONS

Dinuclear Zinc Complexes Using Pentadentate Phenolate Ligands

(2008) Paul D. Knight et al.   INORGANIC CHEMISTRY

Preparation, Characterization, and Catalytic Studies of Magnesium Complexes Supported by NNO-Tridentate Schiff-Base Ligands

(2008) Wen-Chou Hung et al.   INORGANIC CHEMISTRY

Aluminum and zinc complexes supported by functionalized phenolate ligands: Synthesis, characterization and catalysis in the ring-opening polymerization of ε-caprolactone and rac-lactide

(2008) Cheng Zhang et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Ring-Opening Polymerization of Cyclic Monomers by Complexes Derived from Biocompatible Metals. Production of Poly(lactide), Poly(trimethylene carbonate), and Their Copolymers

(2008) Donald J. Darensbourg et al.   MACROMOLECULES

Biocompatible Initiators for Lactide Polymerization

(2008) Rachel Platel et al.   Polymer Reviews